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991.
单元系T—p相图的数学结构 总被引:1,自引:0,他引:1
作者以化学元素的稳定单质为基准,推演出了任意物质M_i(相态Ω)的热力学生成活度{相态Ω)的函数形式:?D_Ω数值的大小体现着相态Ω的热力学相对稳定性.根据集合论原理沿D(稳定性)座标取极大值的方法把物理性质互不连续的各个异相态连结在一起,建立了单元系在T-p面上的优势分布方程(PSDE):■作者以H_2O为实例,计算了T-p相图,与实验相图基本一致. 相似文献
992.
Immobilization was carried out of the lactate dehydrogenase (LDH) from rabbit muscle (EC 1.1.1.27), cross-linked through the bifunctional reactive glutar-aldehyde on to nylon tubing (1 m long, 53cm2 internal surface area). Immobilized LDH inactivation kinetics are of first order (t1/2 = 3·6 years, k = 5·4,e?4 day?1 to 5°C). The smaller effect of pH on activity than in the case of LDH in solution can be explained on the basis of limitation to proton diffusion towards the support. A limiting effect to free external diffusion of the substrate towards and products from the support was also observed, an effect which seems to determine the effective kinetic behaviour of immobilized LDH. The apparent optimum temperature is centred around 40°C, observing a clear inactivation (thermal denaturation) above this temperature. In the temperature range studied (10–40°C), the co-existence was seen of a kinetic control accompanied by another control, involving diffusional transport of substrates and products, on the global activity of the immobilized enzyme. This makes the Arrhenius profiles curvilinear. Both graphic and statistical non-linear regression analysis of the kinetic data—rate, v, versus substrate concentration [S]—carried out under conditions in which the diffusional limitations can be considered negligible (high recirculation flow rate), permitted investigation of the intrinsic kinetic behaviour of immobilized LDH. In this sense, it can be deduced that the rate equation to which these data seem to be fitted is of the polynomial quotient type in [S] of minimum degree 2:2. Although the diffusional limitations have a marked effect on the type of global kinetics shown by immobilized LDH, temperature was not found to affect its v[S] behaviour. The experimental evidence obtained thus indicates that the rate equation in the 10-40°C temperature range continues to be a rational equation of at least degree 2:2 in [S]. 相似文献
993.
王纪鑫 《材料科学技术学报》1992,8(1):44-50
The general relationship between binary phase diagrams and the thermodynamic properties was system-atically derived without any assumption.A procedure was presented to estimate the thermodynamic proper-ties from the binary phase diagrams. 相似文献
994.
HPVC/PP共混改性研究:Ⅲ低分子量反应性化合物作相容剂 总被引:3,自引:0,他引:3
采用低分子量反应性化合物作相容剂,即化学交联体系来改善HPVC/PP共混物的相容性。考察了在不同共混比下,不同化学交联体系对共混物力学性能的影响,并观察了共混物的微观形态。结果表明,采用低分子量反应性化合物作相容剂,共混物的拉伸强度提高,但冲击强度无改善。分散相尺寸减小,相间粘接得到改善。并比较了3种增容方法的效果,发现CPE是HPVC/PP共混物的最佳相容剂。 相似文献
995.
I. W. Hall 《Materials Characterization》1997,39(2-5):419-434
The effects of ion implantation and subsequent annealing on the microstructure of molybdenum have been investigated by transmission electron microscopy. The ions investigated were carbon, nitrogen, and tellurium. The ion-induced damage was found to give rise to grain boundary migration phenomena both during implantation and during subsequent annealing. Precipitation or ordering was found to occur for each ion on annealing. 相似文献
996.
利用短周期地脉动推断深层地基S波速度 总被引:3,自引:0,他引:3
从二维随机波场的相关理论出发,提出了如何从短周期地脉动(频率>0.5Hz)时域信号中计算Rayleigh波弥散曲线,进而反演深层地基剪切波(S波)速度的理论方法和分析技术,并结合实测信号的分析结果,探讨了该方法的可行性和实用性。 相似文献
997.
聚苯硫醚酰胺的合成与表征 总被引:7,自引:1,他引:6
用4-氯苯甲酰4′-氯苯胺和硫化钠为原料在常压下合成了聚苯硫醚酰胺,并对其进行了表征。结果表明所合成的产物为结晶性聚合物,并且有较高的热稳定性。 相似文献
998.
The modified direct observation method is employed for the determination of the liquidus lines in the (Hg1_xZnx)1_yTey, ternary system. The liquidus temperatures of the ternary samples of various compositions withx from 0.05 to 0.30 andy from 0.5 to 0.9 are measured. The temperature-composition phase diagrams and some liquidus isotherms are established for
this system. 相似文献
999.
用层次分析法(AHP)确定煤和瓦斯突出中的有关参数 总被引:1,自引:0,他引:1
介绍了井下瓦斯突出的原因 ,详细阐述了瓦斯突出的有关参数的确定方法。 相似文献
1000.
S. Anastasova M. Milanova I. Manolov T. Czeppe D. Todorovsky 《Bulletin of Materials Science》2007,30(5):511-520
The results from DSC and thermogravimetric analysis of gels produced from a mixture of tetraethoxysilane (TEOS) and octyltriethoxysilane
(OtEOS) both with and without immobilized Ru(II) tris(4,7-diphenyl-1,10-phenanthroline) dichloride as well as DSC and TG data for films deposited by deep-or spin-coating from
the same gels, are reported. The initial products are characterized by elemental analysis, IR, solid state NMR and mass spectroscopy.
Elemental analysis and IR spectroscopy are applied for identification of some of the intermediates obtained after heating
at different temperatures. The final products are characterized by X-ray diffractometry. A hypothesis for the thermodecomposition
processes taking place is proposed. The results reported contribute to elucidation of the properties as well as the temperature
intervals in which the studied microcomposites could be used as sensing components of oxygen sensors. 相似文献