基于外部压力的我国上市公司环境信息披露

以我国沪市A股制造业上市公司为研究样本,从外部压力角度,分析合法性压力和投资者关注度对企业环境信息披露行为的影响。研究发现：合法性压力越大,上市公司越有可能进行环境信息披露;投资者关注度对上市公司环境信息披露呈现微弱正相关关系,但在统计上不显著。     

曲线箱梁桥的空间传递矩阵

为了分析曲线箱梁桥的受力情况,将传递矩阵法用于曲线箱梁桥的受力分析,以变化固定端的悬臂梁作为单元基本计算体系,利用平衡方程、卡式定理及虚功原理推导了弹性曲线箱梁的显式空间传递矩阵,并考虑了截面剪切中心与形心不重合的影响。为验证公式的正确性,分别采用传递矩阵法与有限元法对某一单跨曲线箱梁桥进行空间受力分析,结果显示2种方法计算结果基本吻合,而传递矩阵法划分较少单元却可达到很高的精度,计算效率大大提高。表明该公式正确,推导方法可行,可推广应用于其他结构在不同荷载情况下传递矩阵的推导。     

Pt-Sn工业重整催化剂失活过程金属分散性的原子尺度表征

重整催化剂活性铂原子的表面分散特性与催化剂的活性密切相关。借助球差校正扫描透射电子显微镜(Cs-STEM),针对金属Pt、Sn质量分数均为0.3%左右的低负载量的工业Pt-Sn/γ-Al₂O₃重整催化剂,采用STEM方法研究了不同工业状态下Pt原子在催化剂载体表面的分散特性。结果表明：新鲜催化剂中活性元素Pt以单原子或小原子簇形式分散,催化剂失活的过程是活性Pt原子不断聚集的过程;当Pt-Sn金属聚集体尺寸大到不能再生分散时,则催化剂活性无法恢复。本研究从工业剂角度给出了金属原子分散性与催化剂性能的构效关系。     

Thermal,mechanical and γ-ray shielding properties of micro- and nano-Ta2O5 loaded DGEBA epoxy resin composites

In this work, we have investigated the synergistic effect of micro- and nano-Ta₂O₅ fillers in the epoxy matrix on the thermal, mechanical, and radioprotective properties of the composites. Morphological analysis revealed uniform dispersion of fillers in the matrix. Both the thermal stability and tensile properties of matrices have enhanced in the presence of fillers. Although the nanocomposites showed significantly higher tensile strength and Youngs modulus compared to micro-composites, the enhancement in these properties was predominant at low loadings. Dynamic mechanical analysis indicated good interfacial adhesion and positive reinforcing effect on the matrix even at higher loading (30 wt%) of nano-Ta₂O₅. γ-Ray attenuation studies performed in the energy range of 0.356–1.332 MeV revealed better γ-ray shielding ability of nanocomposites compared to microcomposites at same weight fraction of fillers. In particular, γ-ray attenuation at 0.356 MeV for 30 wt% nano-Ta₂O₅ loaded epoxy composite was enhanced by around 13% compared to the microcomposite at the same loading. Increased surface-to-volume ratio of nanofillers and consequent increase in matrix-filler adhesion and radiation-matter interaction have manifested in an overall enhancement in the thermal, mechanical, dynamic mechanical, and radiation shielding characteristics of nano-Ta₂O₅/epoxy composites, proving them as promising γ-ray shields.     

Study on the preparation and microstructure of a single-crystal hollow turbine blade

This paper studied the structural design of a ceramic core and a blade, ceramic core localization, shell preparation, casting process, core leaching technology, and the heat treatment process of a single-crystal hollow turbine blade. The results show that the single-crystal structure solidification sequence of the blade platform is consistent with the cooling sequence and the pulling-out direction of the blade. The primary dendrites were obviously enlarged with the increase of the blade thickness owing to the change in the local cooling rate. Besides, the γ′ phase had a high uniform size distribution ranging from 0.40 to 0.60?µm after heat treatment, and the cubic degree was more homogeneous in comparison with the as-cast microstructure, which are favorable for the superalloy structure. Moreover, γ′ phase size gradually increased and its quantity gradually reduced owing to the increase of the wall thickness in the growth direction.     

多孔氮化硅表面γ-Y_2Si_2O_7陶瓷涂层的制备及抗热震性能

采用浆料喷涂与高温熔渗结合的方法,以γ-Y_2Si_2O_7和Y_2O_3-Al_2O_3-SiO_2三元氧化物粉体为原料,在多孔Si_3N_4表面制备致密γ-Y_2Si_2O_7陶瓷涂层,采用XRD和SEM测试方法系统研究原料配比及烧结温度对涂层结构、组织和抗热震性能的影响。结果表明:SiO2与Al2O3物质的量之比较高时,涂层为致密γ-Y_2Si_2O_7层和过渡层的双层结构;SiO_2与Al_2O_3物质的量之比较低时,只能形成单层结构;双层结构涂层的抗热震性能优于单层结构涂层。     

5-5′型木质素二聚体高温热解微观化学反应机理研究

选用5-5′键型连接的木质素二聚体为研究对象,基于B3LYP/6-31g基组和密度泛函理论(DFT)对其进行了高温热解微观化学反应机理研究,设计了5-5′型木质素二聚体高温热解反应的5条初反应路径,并在分析初反应结果的基础上设计了7条次反应路径,对每条路径的反应物及其产物进行了结构优化,计算了1500K温度下每条反应路径的热力学及动力学参数。结果表明,5-5′型木质素苯环位上的甲氧基具有很强的活性,甲氧基中O-CH3键以及Caromatic-OCH3键较易断裂;通过计算得出初反应的R3、R4反应焓变较小,分别为192.7kJ/mol和270.5kJ/mol,认为该热解反应的主反应路径以R3及R4为主;该热解反应得到的最终产物有3-4,二羟基甲苯、对羟基甲苯、2-乙烯-4-甲基-3,5-二烯环己酮、甲烷、甲醇及甲醛。     

冷拉减面率对C形环用Inconel X-750丝材组织性能的影响

文章通过冷拉拔加工制备减面率为0%、30%、60%的Inconel X-750丝材,分别在650℃、730℃、810℃下时效处理16h,研究冷拉减面率对X-750合金组织性能的影响,特别是减面率对γ′相形状、分布、数量及尺寸的影响。经定量分析,增大冷拉减面率除了有细化晶粒的作用外,还能一定程度地增加γ′相析出的颗粒数量及体积分数,减小γ′相尺寸,进一步加强沉淀强化的作用。时效温度对X-750丝材的晶粒尺寸没有明显影响,对γ′相的数量、尺寸及形状影响较大。采用730℃时效处理16h的标准工艺制备的X-750丝材,经加工为弹簧后制造成金属C形密封环,其回弹量及泄漏率均满足要求,实验条件下密封性能良好。     

关于Smarandache可求和因数对问题

对任意正整数n,设d（n）表示n的Dirichlet除数函数,即就是n的所有不同正因数的个数.著名的Smarandache可求和因数对问题是指：是否存在无穷多个正整数m及n,使得d（m）＋d（n）=d（m＋n）,其中（m,n）=1.利用初等方法以及著名的陈景润定理研究这一问题,即证明存在无穷多个正整数m及n且（m,n）≤2,使得d（m）＋d（n）=d（m＋n）,其中（m,n）表示m和n的最大公约数.从而将AmarnathMurthy及Charles Ashbacher提出的一个猜想做出了实质性进展.     

Research on Comparison and Evaluation Studies of Several Smoothing Denoising Method Based on γ-ray Spectrum Detector

The extraction of spectral parameters is very difficult because of the limited energy resolution for NaI(TI)[JP] gamma-ray detectors. For statistical fluctuation of radioactivity under complex environment, some smoothing filtering methods are proposed to solve the problem. These methods include adopting method of arithmetic moving average, center of gravity, least squares of polynomial, slide converter of discrete funcion convolution etc. The process of spectrum data is realized, and the results are assessed in H/FWHM(Peak High/Full Width at Half Maximum) and peak area based on the Matlab programming. The results indicate that different methods smoothed spectrum have respective superiority in different ergoregion, but the Gaussian function theory in discrete function convolution slide method is used to filter the complex γ-spectrum on Embedded system platform, and the statistical fluctuation of γ-spectrum is filtered well.