红外研究丁羟二异氰酸酯的固化反应动力学

用红外分光光度计研究了端羟基聚丁二烯(HTPBD)与二异氰酸酯的反应动力学,结果表明,NCO与OH的反应为二级动力学反应,由于位阻效应和共轭效应,MDI比TDI的反应活性大得多,前者的反应速率常数大约是后者的10～20倍。反应速率常数及活化能随NCO的过量而有所变化。在NCO过量体系中。TDI-HTPBD体系中有次级反应发生,由于氢键的作用,次级反应为对于氨基甲酸酯基为二级、NCO为一级的三级反应动力学.由于位阻效应,MDI体系很难发生次级反应。     

辐射照度测量与色修正系数

本文首次明确提出了辐射照度测量中的色修正系数问题，在理论上给出了它的计算公式。在一定情况下它可能是暗藏的不确定度的最大来源。本文还针对一些实际测量的典型情况，计算了色修正系数值，从而揭示了色修正问题可能给辐射照度计示值带来巨大的系统偏差，得出了一些有用的结论。     

张应变,长波长In1—xGaxAsyP2—y／InP量子阱材料的光荧光谱实验室

给出了具有二三个量是的Ｉｎ１－ｘＧａｘＡｓｙＰ１－ｙ／ＩｎＰ张应变量子阱材料的光荧光谱及ｘ射线双晶衍射摇摆曲线，指出了荧光峰为量子阱中导带子带和阶带子带间本征复合机构所致。理论上分析了光荧光谱中双峰强度比随温度变化的关系，理论计算和实测结果基本一致。     

红外探测器光谱响应自动测试系统的探讨

本文对红外探测器光谱响应自动测试系统中存在的问题进行了探讨和分析，特别是对人们一般不太重视的个别问题作了较详细的实验分析，并根据调试中出现的异常情况做了多种不同的试验，分别找到了解决办法，使系统调试成功，实现了红外探测器光谱响应自动测试。     

岩石光谱在遥感解译中的应用

为配合地质解译，提供地面遥感图象、航空遥感图象信息来源和影象特征，对位于河北省阳原县石匣里Ⅰ坝址地段的几类主要岩石进行了光谱测定，重点研究了光谱信息特征与岩石成分、结构和构造间的相互关系，为库坝地区的遥感地质解译确立了典型的地质解译标志。1坝址地质概况石匣     

Structural Description of Polyaromatic Nucleus in Residue

The proton nuclear magnetic resonance spectroscopy （1H-NMR）, the synchronous fluorescence spectrometry （SFS） and the ruthenium ions catalyzed oxidation （RICO） method were used to determine the chemical structure of polyaromatic nucleus in Oman residue fractions. The results of 1H-NMR analyses showed that the average numbers of aromatic rings in the aromatics, resins and asphaltenes units were 3.2, 5.6 and 8.2, respectively. SFS was used to investigate the distribution of aromatic rings in residue fractions, the main distribution range of aromatic rings in aromatics, resins and asphaltenes were 3 4 rings, 3--5 rings and more than 5 rings, respectively. The aromatic network in residue fractions was oxidized to produce numerous carboxylic acids. The types and content of benzenepolycarboxylic acids, such as phthalic acid, benzenetricarboxylic acids, benzenetetracarboxylic acids, benzenepentacarboxylic acid and benzenehexacarboxylic acid disclosed the condensed types of aromatic nuclei in the core. The biphenyl fraction （BIPH）, the cata-condensed fraction （CATA）, the peri-condensed fraction （PERI） and the condensed index （BCI） were calculated based on the benzenepolycarboxylic acids formed. The results implied that there was less biphenyl type structures in all residue fractions. The aromatics fraction was almost composed of the cata-condensed type system, and the asphaltenes fraction was wholly composed of the peri-condensed type system, while in the resins fraction co-existed the two types, herein the peri-con- densed type was predominant over the cata-condensed type. Based on the analytical results obtained in the study, the components --aromatics, resins and asphaltenes -- were given the likely structural models.