四叔丁基萘酞菁氧钒非线性及光限幅特性

为提高酞菁化合物的非线性光学性能,以1,8-二氮杂双环[5.4.0]十一碳烯-7(DBU)为催化剂,采用液相法合成了四叔丁基萘酞菁氧钒((t-Bu)4NcVO)化合物.利用元素分析、红外光谱、核磁共振氢谱方法,验证了化合物的分子结构.应用调Q倍频ns/ps Nd∶YAG脉冲激光系统,在波长为532nm下,研究了化合物的非线性和光限幅特性.测得化合物的非线性折射率n2和三阶非线性极化率χ(3)分别为2.51×10-11esu和8.54×10-12esu,通过计算得到分子极化率γ’为3.7×10-29esu.在透过率69%时限幅阈值为1608mJ/cm2,箝位值为585mJ/cm2,有效激发态与基态吸收截面比为3.66.     

Simulation and optimization of SOFC-BCHP system

As the prime motor of dispersed energy system, the high-temperature solid oxide fuel cells (SOFC) are high efficient with large heat recovery. This study presents a simulation of SOFC building-based cooling, heat and power (BCHP) system, which can meet basic requirements in power and heating (cooling) of the designated customers. The peak power load can be met by power grid, while the peak heating (cooling) load requirement can be met by backup equipments. In order to solve the economic dispatch problem of the energy system, a restricted nonlinear optimization model has been developed. The production costs can be minimized via both the equality constraints of customer’s heat and power demands, and other inequality constrains of equipments’ capacities. The sequential quadratic programming method has been used to search the solution. The study indicates that the model can be used to optimize the system’s capacities and run strategy. An office building case has been computed, and it is indicated that the model can be served in design and optimization of SOFC-BCHP system.     

HP nonlinear guidance law design based on smooth sliding mode control

To eliminate the perturbation of interceptor detection induced by aerodynamic heating,the head pursuit (HP) guidance law for three-dimensional interception was presented. The guidance law positioned the interceptor ahead of the target on its flight trajectory,and the speed of interceptor was required to be lower than that of the target. On the basis of a novel head pursuit three-dimensional guidance model,a nonlinear guidance law was developed based on smooth sliding mode control theory. At the same time,a special observer was designed to estimate the target acceleration,and a numerical example on maneuvering ballistic target interception verified the effectiveness of the presented guidance law.     

专家介绍

惠静教授,博士,2004年7月毕业于中国科学院数学与系统科学研究院,获理学博士学位,专业为非线性动力系统;2004年9月至2006年9月在华东师范大学数学系博士后流动站进行研究;     

基于扰动力矩观测器的电子节气门控制

通过介绍汽车电子节气门控制系统的工作原理及其组成,以及对系统的非线性因素分析,建立其数学模型,设计出数字PID控制器和扰动力矩补偿器,并在matlab/simulink中进行了仿真,对仿真结果分析得出:基于数字PID控制器的控制精度较差,并且容易产生超调;基于扰动力矩观测器的PID控制器具有较好的跟踪性,可以较好地满足控制要求.     

全非线性深水波的Green-Naghdi理论研究

全非线性深水波的数值模拟对于深海工程有着重要意义.应用二维深水G-N理论的控制方程,得到深水LevelⅢ G-N理论和Level Ⅳ G-N理论的线性解析解.采用深水Level Ⅲ和Level Ⅳ G-N理论对单色波进行数值模拟.提出适用于G-N理论的非线性造波边界条件,使用线性造波边界条件的结果与使用非线性边界条件的结果基本一致,因此可以使用线性造波边界叠加的方法来模拟不规则波.采用深水LevelⅢG-N理论模拟全非线性双色波和不规则波,并与线性解析解进行比较,结果表明使用深水LevelⅢG-N理论并配合线性造波边界条件来模拟全非线性深水不规则波是可行的.     

无机纳米-聚酰亚胺复合薄膜介电性研究

测试了纳米Al2O3-聚酰亚胺(PI)复合薄膜和纳米SiO2-聚酰亚胺复合薄膜的介电常数、介质损耗角正切和电导电流特性.结果表明,随着无机物含量的增加,两种复合薄膜的相对介电常数和介质损耗角正切增大,电老化阈值减小;无机物含量相同时,Al2O3-聚酰亚胺复合薄膜的相对介电常数和介质损耗角正切比SiO2-聚酰亚胺复合薄膜大,电导电流大,电老化阈值小.     

介质阻挡放电反应器降解邻二甲苯的特性研究

采用介质阻挡放电(DBD)降解常压下流动态的邻二甲苯模拟废气,系统地考察了放电极值电压,气体的初始质量浓度、停留时间以及相对湿度等工艺参数对邻二甲苯降解的影响,并初步探讨了邻二甲苯的降解产物.实验研究结果表明:在7.0kV的放电极间电压下,邻二甲苯的初始质量浓度为1 500mg/m3,停留时间为9s,其去除率可达到80%以上.降解产物主要为CO2、H2O以及苯甲酸、苯乙酸、苯乙醛等有机物,并且经降解后产物的生物可生化性得到提高,因而为后续的等离子-生物法联合处理VOCs提供了依据.     

水溶性有机合成淬火介质在石油钻采机械热处理中的应用

石油钻采机械及其配件多系大截面、重负荷。采用优质合金锻钢或铸钢制造,要求通过热处理达到高强度和优良的综合机械性能。长期以来,热处理以水和油作为淬火剂、由于水的冷却性能不理想,主要限于水-油,水-空