树枝状荧光探针设计制备及荧光特性初步研究

树枝状荧光探针是将荧光染料引入树枝状化合物（dendrimer）端基的一类化合物,具有良好的稳定性及光谱特性．笔者以2,2-二甲氧基乙胺为核,采用发散合成法合成了一端含活性氨基的扇形树枝状化合物,并将羧基噻唑橙染料（TO—COOH）引入树枝状化合物的端基,制备出树枝状荧光分子．初步研究了其荧光特性,讨论了反应温度、反应时间等条件对反应收率的影响．     

Development of Zr/ZrO<Subscript>2</Subscript> high temperature and high pressure sensors for <Emphasis Type="Italic">in-situ</Emphasis> measuring chemical parameters of deep-sea water

In order to in situ measure chemical parameters of deep-sea water and hydrothermal fluids at midocean ridge(MOR), it is necessary to use high temperature and high pressure chemical sensors.Developing new sensors is essential to measure in-situ pH and other chemical parameters(dissolved H2, dissolved H2S) of deep-sea water and hydrothermal fluids in a wide temperature range(2℃―400℃) at MOR vents.The YSZ(Yttria Stabilized Zirconia, 9%Y2O3) ceramic-based(HgO/Hg) chemical sensors possess excellent electrochemic...     

Investigation on the electrocatalytic characteristics of SnO_2 electrodes with nanocoating prepared by electrodeposition method

SnO2 electrodes have many advantages in the degradation of toxic or bio-refractory organic wastewater,and SnO2 is a kind of anode material which has the potential to be widely used.Electrocatalytic effi-ciency and service life of Ti\SnO2 electrodes are key factors that can influence its applications.In order to enhance the electrocatalytic characteristics of Ti\SnO2 electrodes,a type of electrocatalytic electrode with nanocoating was prepared by direct current(DC)electrodeposition method and thermal oxidati...     

Experiments and reaction characteristics of liquid phase simultaneous removal of SO<Subscript>2</Subscript> and NO

Experiments of simultaneous removal of SO₂ and NO from simulated flue gas, using NaClO₂ solution as the absorbent, were carried out in a self-designed bubble reactor, and high simultaneous removal efficiencies of SO₂ and NO were obtained under the optimal experimental conditions. The mechanism of simultaneous removal based on NaClO₂ acid solutions was proposed by analyzing the removal products. Possibility and limitation of the desulfurization and denitrification using NaClO₂ acid solutions were calculated by thermodynamic methods. Experimental results of reaction kinetics for simultaneous desulfurization and denitrification indicated that the oxidation-absorption processes of SO₂ and NO were divided into two zones, namely the fast and slow reaction zones. In the slow reaction zones both were zero order reactions, and in the fast reaction zones, the reaction order, rate constant and activation energy of SO₂ reaction with absorbent were 1.4, 1.22 (mol·L⁻¹)^−0.4·s⁻¹ and 66.25 kJ·mol⁻¹, respectively, and 2, 3.15×10³ (mol·L⁻¹) ⁻¹·s⁻¹, and 42.50 kJ·mol⁻¹ for NO reaction, respectively. Supported by the National High-Tech Research and Development Program of China (“863” Project) (Grant No. 2007AA061803)     

CuO-NiO/Al_20_2催化剂上N-甲基哌嗪合成研究

以共沉淀法制备铜、铝系复合氧化物作为催化剂,二乙醇胺和甲胺为原料,合成了N-甲基哌嗪.利用高压反应釜对其进行活性评价,发现CuO-NiO/Al2O3活性最高.并对铜、铝、镍摩尔比、沉淀剂种类、沉淀方式,焙烧温度等条件进行了优化.结果表明:催化剂中理想的Cu、Al、Ni摩尔比为1:1:3.2,沉淀剂为氢氧化钠,沉淀方式为并流,焙烧温度为500℃.该条件下N-甲基哌嗪的选择性为27.7%,二乙醇胺的转化率达89.8%.另外通过对使用前后催化剂进行表征分析发现催化剂失活原因为表面高聚物的附着和对孔道的堵塞.     

金属离子掺杂TiO2光催化材料的光催化性能研究

用溶胶-凝胶法制备金属离子掺杂的TiO2光催化剂,以紫外灯和太阳光为光源,用罗丹明B溶液为模拟废水,研究TiO2掺杂金属离子催化剂光催化性能,探讨金属离子的半径、价态及电子构型等因素对掺杂TiO2催化活性的影响.     

P2P网络环境下的推荐信任模型方案

P2P网络的匿名性和动态性带来了许多安全问题,传统的信任管理模型并不能很好的适应对等网络环境。提出了一种基于推荐的P2P网络信任模型,将节点提供服务和推荐的能力进行区分,用信誉值表示节点的推荐能力,根据节点的直接信任值、其它节点的推荐信任值和相应的惩罚值来计算节点的信任度,节点依据信任度选择交易对象。仿真实验表明,基于推荐的信任模型能有效的评估节点的信任度,在交易成功率上要优于传统的信任管理模型。     

基于并行预测控制的Turbo码译码结构

提出一种基于并行预测控制的Turbo码译码结构. 通过建立预测控制模块(PCA)来预测分量译码器第n+1次的译码外部信息值. 相比于传统的并行译码方案,基于PCA模块的PPC-Turbo结构可以降低译码算法的复杂度,并减少译码时延. 通过对单次外部信息值预测（6～9次）及复次外部信息值预测（6+8、7+9次）,对比了外部信息预测的变化趋势及不同帧长（1?024、512、256、128、64帧）情况下的译码时延,验证了译码时延的减少. 在帧长为1?024、信噪比为0～2?dB时,对译码器2第6～8次的外部信息进行了单次预测,比较了PPC-Turbo与Turbo的误比特率(BER)性能,结果表明,两者的BER非常接近,预测控制模块可以代替分量译码器的一次译码迭代.     

无循环前缀SFBC-OFDM系统的Turbo均衡

为了提高传输效率,对无循环前缀(CP)的空频分组码正交频分复用(SFBC-OFDM)系统进行了研究,提出一种基于软信息反馈的Turbo均衡算法. 同时提出了符号间干扰删除、软循环重构、对角化SFBC译码以及MMSE频域均衡器,通过多次迭代抑制系统中出现的各种干扰. 仿真结果表明,该算法可有效改善无CP的SFBC-OFDM的误码性能.     

Prospects of N2O emission regulations in the European fertilizer industry

European authorities consider that N₂O emissions from nitric acid plants can be reduced to a large extent at a relatively low cost. Two regulation approaches can have major implications for the fertilizer industry in Europe. The EU integrated pollution prevention and control (IPPC) directive will be effective from October 2007 for existing plants. In this, emission permits will be based on best available techniques (BAT). Additionally, the EU commission will shortly consider whether the emission trading directive should be applicable to cover other greenhouse gases besides CO₂. This paper discusses advantages and drawbacks of these approaches, with emphasis on how emission trading with N₂O can be turned into a win–win situation both for European governments and for the fertilizer industry.