Energy Band-gap Calculation of d-Ta2O5 Using sX-LDA and B3LYP Methods

The energy band-gap and related factors of tantalum pentoxide with hexagonal phase were investigated using hybrid functional B3 LYP and s X-LDA methods. The results showed that both s X-LDA and B3 LYP techniques reveal the indirect semiconductor nature of δ-Ta2O5, whereas the obtained value of energy band-gap is much higher than previous theoretical reports but closer to the experimental data. The optical bandgap of δ-Ta2O5 is expected to originate from the O 2p→Ta 5d transition which may benefit from the d-s-p hybridization.     

面向大学生心理问题分析的数据挖掘应用

当前已经进入大数据时代,数据挖掘是在大量的数据中提取有用的有价值的知识。本文结合高校学生心理测试产生的数据,采用ID3算法构造决策树分析预测大学生心理健康状况,为学校的心理辅导工作提供参考依据。     

500 kV 开关弹簧机构支架螺栓断裂的原因分析及处理

HPL500B2型弹簧机构支架(BA)螺栓断裂可能导致开关分合闸失败,对其原因进行分析,发现BA螺栓由于预紧固力矩过大,接近其扭断力矩,使得作用在BA螺栓上的力偏高,BA螺栓安全系数仅为12%,安全系数较低。列出BA螺栓更换步骤及注意事项,并详细介绍分闸、合闸弹簧调整步骤,为类似事件的处理提供参考。     

不同晶相结构ZrO2负载铜基催化剂用于二乙醇胺脱氢反应

通过制备不同晶相结构〔单斜相(m-ZrO_2)、四方相(t-ZrO_2)和无定型(a-ZrO_2)〕ZrO_2载体,再通过沉积沉淀法制得Cu/m-ZrO_2、Cu/t-ZrO_2和Cu/a-ZrO_2催化剂,分别用于催化二乙醇胺脱氢合成亚氨基二乙酸反应。采用XRD、氮气物理吸附脱附、XPS、H_2-TPR、CO_2-TPD对催化剂的结构进行了表征。结果表明,Cu/m-ZrO_2催化剂界面更加有利于Cu~+/Cu~0稳定存在,具有更多的碱性位点,且抗氧化性较好。在二乙醇胺脱氢反应中,Cu/m-ZrO_2催化剂性能最好,反应时间为2.5 h,亚氨基二乙酸收率为97.64%。     

Room Temperature Ferromagnetism in Co-doped CuAlO2 Nanofibers Fabricated by Electrospinning

One-dimensional, diluted magnetic semiconductor nanofibers have attracted increasing attention for their unique magnetic properties, large specific surface area, and high porosity. These qualities lead to excellent performance in magneto-optical devices, magnetic resonance imaging, ferrofluids and magnetic separation. The purpose of this study is to fabricate P-type one dimensional CuAlO2-based diluted magnetic semiconductor nanofibers. First, we fabricated Cu Al0.95Co0.05O2 nanofibers with an average diameter of 1 μm with the electrospinning method. The annealed nanofibers were thermally treated at a temperature of 1 100 ℃ and then shrunk to a diameter of about 650 nm. We used X-ray diffraction measurements and Raman spectra to confirm that the Cu Al0.95Co0.05O2 nanofibers had a single impurity free delafossite phase. The X-ray photoelectron spectroscopy analysis indicates that Co was present in the +2 oxidation state, resulting in an room temperature ferromagnetism in the Cu Al0.95Co0.05O2 fiber. This contrasts with nonmagnetism in pristine CuAlO2 fiber. The coercivity(Hc) value of 65.26 Oe and approximate saturation magnetization(Ms) of 0.012 emu/g demonstrate good evidence of ferromagnetism at room temperature for Cu Al0.95Co0.05O2 nanofibers.     

《高校化学工程学报》简介

<正>《高校化学工程学报》于1986年创刊,1989年经报请原国家教委和国家科委批复后向国内外公开发行。20多年来,该刊的主办院校已扩大到20所,同时聘请了六位外籍著名学者和六位国内著名院士担任"编委会顾问委员",使该刊"编委会国际化"迈出了可喜的一步。该刊一直受国内外学术界的重视。     

初馏塔建设过程中对CS3000网络功能与系统构成

针对初馏塔建设过程中常减压蒸馏装置工艺流程的改造,采用集散控制系统来满足初馏塔建设改造后提出的工艺条件和控制操作要求。本次设计重点放在基本控制系统和基本控制回路的阐述,选用了先进的DCS控制系统,采用多种控制方案,选择比较先进的国内外仪表,使整个系统能够正常的运行,并注重理论联系实际,使之具有先进性和实用性。     

基于LabVIEW的CRDM噪声录波试验台设计

控制棒驱动机构(CRDM)是控制棒的驱动装置,它是核反应堆压力容器内惟一的可动部件,也是关键部件之一。为了提高大亚湾核电站在大修期间CRDM噪声录波试验的效率、简化试验的过程,通过对CRDM噪声录波试验进行分析研究,合理设计CRDM噪声录波试验台结构,并采用Lab VIEW软件编程实现信息采集、数据记录、分析等多种功能,设计一种新的CRDM噪声录波试验台。该试验台解决了试验数据分析困难等问题,简便易行,对大亚湾核电站大修期间的CRDM试验具有重要意义。