Thermodynamic Study on the Rare Earth Vapour Complex PrAl_3Cl_(12)

ＴｈｅｒｍｏｄｙｎａｍｉｃＳｔｕｄｙｏｎｔｈｅＲａｒｅＥａｒｔｈＶａｐｏｕｒＣｏｍｐｌｅｘＰｒＡｌ３Ｃｌ１２ＷａｎｇＬｉｎｓｈａｎ（王林山），ＧａｏＲｏｎｇｊｉｅ（高荣杰），ＳｕＹｉ（苏轶），ＷａｎｇＺｈｉｃｈａｎｇ（王之昌）（Ｄｅｐａｒｔｍｅｎｔ...     

辐射和热同时作用对膨润土物理化学性质和微观结构影响的初步研究北大核心CSCD

为了研究γ辐射和热同时作用对膨润土的影响,以高庙子改性钠基膨润土为研究对象,开展了90℃热作用下、不同剂量率和不同累积剂量的γ辐射老化试验。结果表明:γ辐射和90℃热同时作用引起了膨润土物理化学性质和微观结构的变化。在老化作用后,膨润土的吸水率、pH值、阳离子交换容量、层荷以及蒙脱石001晶面方向的微晶尺寸均减小,比参考样分别降低了(最大减幅)18.4%、7.8%、3.4%、2.9%和15.6%,且表现出剂量率效应;老化作用对膨润土的矿物成分及含量影响较小。在高放废物地质处置的工程屏障设计和安全评价中,应考虑膨润土性质变化的影响因素。     

二维三氧化钨纳米结构的合成及其在光电探测器中的应用

三氧化钨（WO₃）是制造晶体管和光电探测器的理想材料,虽然在WO₃纳米结构的生长方面已经完成了一些工作,但是制造足够长的理想型纳米线仍然是一个挑战。在众多的合成方法中,作者选择了化学气相沉积（CVD）方法合成WO₃纳米线,并对其在光电传感器中的应用进行了研究。影响WO₃纳米线成品率的主要因素是前体材料温度、基片位置、载气流速和生长持续时间。在合适的生长条件下生长的纳米线长度最长约为100 μm。这些WO₃纳米线可用来制造高性能的光电探测器,WO₃光电探测器具有灵敏度高、响应速度快、模块微型化等优良的器件性能,表明二维WO₃纳米线在光电探测器的制造中具有很大的优势。      

三维虚拟建模技术和仿真技术在虚拟矿井生产中的应用

三维虚拟建模技术和仿真技术是虚拟矿井生产漫游系统构建的基础工作.本文介绍三维虚拟建模软件3DS Max的优点及常用建模方法,根据流程的重点分析三维虚拟矿井的实体模型构建和优化等关键技术.     

并行设备总线嵌入式控制系统设计

采用ARM7内核芯片S3C4510的高性能网络控制器结合使用CPLD设计VME总线控制器逻辑时序,研制出了类似3UVME的并行设备总线控制器。开发嵌入式系统uClinux的网络通讯软件,实现提供设备之间高速网络连接通道,把后台计算机数据库和前端设备紧密地连接起来,实现数据的快速获取与给定。     

Photoluminescence and doping mechanism of theranostic Eu3+/Fe3+ dual-doped hydroxyapatite nanoparticles

Theranostic nanoparticles currently have been regarded as an emerging concept of ‘personalized medicine’ with diagnostic and therapeutic dual-functions. Eu³⁺ doped hydroxyapatite (HAp) has been regarded as a promising fluorescent probe for in vivo imaging applications. Additionally, substitution of Ca²⁺ with Fe³⁺ in HAp crystal may endow the capability of producing heat upon exposure to a magnetic field. Here we report a preliminary study of doping mechanism and photoluminescence of Eu³⁺ and Fe³⁺ doped HAp nanoparticles (Eu/Fe:HAp). HAp with varied concentration of Eu³⁺ and Fe³⁺ doping are presented as Eu(10 mol%):HAp, Eu(7 mol%)-Fe(3 mol%):HAp, Eu(5 mol%)-Fe(5 mol%):HAp, Eu(3 mol%)-Fe(7 mol%):HAp, and Fe(10 mol%):HAp in the study. The results showed that the HAp particles, in nano-size with rod-like morphology, were successfully doped with Eu³⁺ and Fe³⁺, and the particles can be well suspended in cell culture medium. Photoluminescence analysis revealed that particles have prominent emissions at 536 nm, 590 nm, 615 nm, 650 nm and 695 nm upon excitation at a wavelength of 397 nm. Moreover, these Eu/Fe:HAp nanoparticles belonged to B-type carbonated HAp, which has been considered an effective biodegradable and biocompatible drug/gene carrier in biological applications.     

纳米WO3材料的制备、应用及研究趋势

结合近年来国内外相关文献，综述了纳米WO3材料的研究现状与进展，重点概述了超细WO3粉体和纳米WO3薄膜的各种制备方法及各自优缺点，并介绍了纳米WO3薄膜的稀有金属掺杂研究等；分析了纳米WO3材料的研究意义，介绍了纳米WO3材料在变色及催化等方面的应用。最后分析了纳米WO3材料应用的发展趋势。     

一种新型的激光—等离子体辅助化学气相沉积装置的研究

为探索用激光离子体共同辅助化学气相沉积过程以实现室温沉积的可能性，设计并制造了一种新型的ＣＶＤ装置，实际了ＳｉＨ４－ＮＨ３－Ｎ２体系制取Ｓｉ３Ｎ４膜的试验。结果表明，激光和等离子体是可以相互促进，共同辅助ＣＶＤ过程的，且两者均处于较代的能量水平。     

Phase formation mechanism and kinetics in solid-state synthesis of undoped and calcium-doped lanthanum manganite

LaMnO_3+δ and La_0.7Ca_0.3MnO₃ were synthesized from La₂O₃(La(OH)₃), CaCO₃ and MnO₂ powder mixture with solid-state reaction technique. X-ray diffraction and thermal analysis were employed in the present study on the process of synthesizing of the two compound powders. The kinetic study on solid-state reaction between La₂O₃ and MnO₂ in the powder mixture was isothermally carried out for LaMnO_3+δ formation. The result showed that the reaction process was controlled by three-dimensional solid-ionic diffusion. Both Jander and Ginstling-Brounstein model can be used to describe the reaction kinetics satisfactorily. The relevant apparent activation energy values obtained were as great as 205 ± 11 and 189 ± 8 kJ/mol. The reaction process of La_0.7Ca_0.3MnO₃ preparation from La₂O₃, SrCO₃ and MnO₂ powder mixture was also studied using X-ray diffraction and thermal analysis. The result indicated that the following steps composed the overall reaction: the decomposition of the reactant; the formation of La_1−xCa_xMnO_3+δ; La₂O₃ and Mn₃O₄ reacted with La_1−xCa_xMnO₃ to form final La_0.7Ca_0.3MnO₃ phase. The latest step was the most time-consuming one among others in the overall reaction.     

Direct Digital Manufacturing Industry Ascendant

The paper introduces the origin of the word of Direct Digital Manufacturing and other forms of address, and the working principles of Direct Digital Manufacturing technology and major types of the technology, hard- ware and software development, use of materials, applications, market growth and its development prospects. Focused presentations of Direct Digital Manufacturing （additive manufacturing） compared to traditional mechani- cal manufacturing industry in the use of prices, processing speed, reliability and cost advantages and characteris- tics. Particularly the significant challenges and competitiveness of Direct Digital Manufacturing technology in the processing of any complexity created directly the number of objects, internal structure and channel function, as well as the shape of the chassis components and structure of the matching and optimization.