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41.
42.
探讨了磷酸体系下不同因素对废旧锂电池正极材料中有价金属浸出效率的影响,结果表明:在浸出时间60min,反应温度60℃,磷酸浓度2mol/L,液固比20mL/g,还原剂(H2O2)体积分数为4%时,可得最佳浸出效果,Co、Li、Mn、Ni浸出效率分别可达96.3%、100%、98.8%和99.5%;浸出液添加相应比例金属离子,采用草酸共沉淀法制备前体材料(Ni1/3Co1/3Mn1/3)C2O4,并得到相应再生磷酸溶液。再生磷酸进行循环浸出实验,实验研究结果表明:循环浸出5次之后Li的浸出率仍可保持在90.1%,而Co、Mn和Ni的浸出率在75.0%以上。前体添加锂源Li2CO3煅烧合成Li(Ni1/3Co1/3Mn1/3)O2材料,考察了不同温度对Li(Ni1/3Co1/3Mn1/3)O2材料合成的影响,结果显示,当合成温度为800℃时,得到的材料性能最优良,初次放电容量可达136.4mA·h/g。在0.2C下经过50圈循环后容量保持率为97.2%。 相似文献
43.
Changes in soil pH, exchangeable aluminium (Al), calcium (Ca), magnesium (Mg), and potassium (K) and extractable manganese (Mn) were investigated after urea fertigation of a sandy loam soil in an apple orchard in New Zealand. Urea at three rates (0, 25, 50 kg N ha–1 yr–1 or 0, 16.9, 33.8 g N emitter–1 yr–1) was applied in 4 equal fertigations. Soil cores at 4 profile depths (0–10, 10–20, 20–40 and 40–60 cm) directly below and 20 cm from the emitter were sampled approximately 4 weeks after each fertigation and in the following winter. Results obtained showed that the largest changes in soil pH and cations occurred in soils directly below the emitter in the 50 kg N ha–1 yr–1 treatment where the soil pH decreased by 1.6 pH units at all soil depths. The lowest pH of 4.3 was observed at a depth of 27 cm. Exchangeable Al and extractable Mn levels increased to 11 meq kg–1 and 78µg g–1 respectively. Estimated losses of Ca, Mg and K from the upper soil profile depth (0–10 cm) represented 23, 63 and 27% of their respective total exchangeable levels. At lower profile depths (>20 cm), accumulation of displaced K was evident. Variable, and generally non-significant, chemical changes recorded in soils 20 cm from the emitter were attributed to restricted lateral water movement, and therefore urea movement, down the profile.The present study showed that one season of urea fertigation by trickle emitters, applied to a sandy loam, at half the rate conventionally applied to apple orchards (50 kg N ha–1 yr–1) resulted in pH and mineral element imbalances which were potentially and sufficiently severe to inhibit tree growth. 相似文献
44.
纳米铜锰复合氧化物固相反应法的制备与表征 总被引:1,自引:0,他引:1
以乙酸铜、乙酸锰与草酸为原料,采用固相化学反应法制备了纳米铜锰复合氧化物前驱物,利用均匀设计考察了微波功率与加热时间、热分解温度及时间对产物粒径的影响。研究表明热分解温度对产品粒径的影响最大。最小粒径产物的制备条件是:微波功率540 W,微波加热时间15 min;热分解温度370℃,热分解时间2 h。XRD和TEM分析结果表明,此产品主要物相为Cu1.5Mn1.5O4,结构属立方晶系,空间群为Fd3m,平均粒径16.9-19.0 nm。应用TG-DTG和DSC技术研究了纳米铜锰复合氧化物的热分解过程以及热分解动力学,采用Ozawa积分法和Coats-Redfern积分法得前驱体的热分解机理函数均为G(α)=[-ln(1-α)]^2/3。 相似文献
45.
46.
Effects of coralline lime on nutrient uptake and yield of field-grown sweet corn and peanuts in Oxidic soils of Western Samoa 总被引:1,自引:0,他引:1
Effects of coralline lime on yield and nutrient uptake by sweet corn (Zea mays saccharata Sturt.) and peanut (Arachis hypogea) were studied at three locations in Western Samoa. Coarse (0-10 mm) coralline material containing 31.1% Ca and 1.67% Mg was used as lime. There were two modes of application: band and broadcast, and three rates: 6, 12 and 18 ton ha–1. In the highest rainfall location, marketable yields were increased by 250% for peanut and 160% for sweet corn by liming at 6 ton ha–1, relative to the unamended control. Peanut yield increases were associated with reduced Mn toxicity and/or with Ca and Mg deficiency. Sweet corn was less susceptible to Mn toxicity, but more responsive to exchangeable Ca. The critical level of exchangeable Ca was found to be about 2.0 cmol(+)kg–1. Applying lime to a band of 0.25-m wide did not reduce yield relative to broadcast. Soil cultivation caused the lime to spread over a wider band, diluting the applied calcium with a larger soil volume, suggesting that less than 6 ton ha–1 broadcast coarse coralline lime could still be adequate for most Samoan soils. 相似文献
47.
隔膜电解制备Mn^3+的研究 总被引:1,自引:0,他引:1
对电解媒质MnSO4在有隔膜条件下电解制备Mn3+过程进行了研究。结果表明,无论均相还是非均相隔膜电解,在常温20℃、40%H2SO4介质中,当电流密度、MnSO4浓度、电解时间在很宽的范围变动时,电流效率保持很高,至少在85%以上。 相似文献
48.
49.
The spinel LiMn2O4 cathode material was synthesized with the solid-state reaction method. Four manganese compounds including electrolytic manganese dioxide (EMD), MnCO3, Mn3O4 and nano-EMD were used as Mn sources while LiOH·H2O was used as the uniform Li source. The crystal structure characteristics of these samples produced were investigated by means of XRD, SEM, particle size distribution analysis and specific surface area testing. Their electrochemical properties were also studied by comparing their specific capacity, charge and discharge efficiency and cycle performance. 相似文献
50.
Immobilization of new Mn(salen) complex over MCM-41 and its activity in asymmetric epoxidation of styrene 总被引:3,自引:0,他引:3
New tetradentate chelates of bis-Schiff bases were synthesized and then these chiral salen ligands were immobilized over mesoporous
MCM-41 by using the ion-exchange method. The efficiency of the chiral catalyst was examined in the asymmetric epoxidation
of styrene. Chiral Mn(salen) complexes immobilized onto mesoporous MCM-41 were stable during the reaction without any leaching
and exhibited relatively high enantioselectivity for epoxidation as compared with homogeneous complexes.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献