利用AFM对单晶硅表面加工化学反应理论分析

以原子力显微镜为工具,在空气条件下对单晶硅片表面加工得到下凹的三维微结构。给出了AFM金刚石针尖在对单晶硅的微加工中的化学反应和加工模型。对加工条件下发生的化学反应及其原理进行了理论分析。用化学热力学定律、化学动力学原理和相关的热力学数据自由能、生成热、化学键能、活化能等分析加工过程中发生的反应是空气中O2与单晶硅Si反应生成二氧化硅的过程;金刚石针尖磨损发生的反应主要是空气中O2与金刚石针尖C反应生成CO2的过程。     

光电探测器薄膜生长条件及机理分析

将苝四甲酸二酐（3,4,9,10-perlenetetracrboxylic dianhydride,PTCDA）真空蒸发到无机半导体p-Si衬底上,研制的p-Si/PTCDA异质结光电探测器,对光照非常敏感,是一种响应度很高的宽带光电子元器件。讨论分析了不同的衬底制备条件制备p-Si/PTCDA异质结薄膜的情况,实验结果表明,制备过程中细微的环境变化,显著影响了器件质量,通过分析成膜质量与器件内部微观机制、能带结构、载流子输运之间的关系,确定制备异质结有机薄膜的硅晶面选择,以及衬底的温度最佳的选择范围。     

探针对原子力显微镜成像的影响

原子力显微镜（Atomic Force Microscope,AFM）的一个重要应用就是对样品表面的微纳米级尺寸特征进行成像,但在扫描成像的过程中,由于针尖的影响作用,使得扫描所获图像是原子力探针和样品共同作用的结果,而不是样品形貌的真实描述。本文通过用具有不同形状、尺寸针尖的探针对同一样品进行成像,将所得图像进行分析、对比,模拟和实验结果表明,为获得更准确的特征尺寸成像,对有不同特征尺寸的样品,需要选择适合的探针对其实施成像。     

Surface morphology of sputtered NiTi-based shape memory alloy thin films

The effect of substrate condition and annealing treatment on the surface morphology of sputter-deposited NiTi-based thin films was studied by means of atomic force microscope. It is found that the surface of the film deposited at 450 °C on a (100) Si wafer is composed of large island groups, consisting of islands of 150–300 nm in diameter. Annealing treatment at 400 °C results in a more homogeneous distribution of the island size. However, for the film deposited at 450 °C on a (111) Si wafer, its surface consists of more homogeneous islands, being about 200–250 nm in diameter. For the film deposited at 450 °C on a SiO₂ buffer layer on top of the Si-substrate, the surface islands have ideal spherical shape. After annealed at 650 °C, the islands have grown to about 300 nm in width and 550 nm in length. The surface roughness of the deposited film is related not only to the island sizes but also to the island distributions.     

交变电场下不锈钢的电化学行为

主要研究了交变电场下SS304不锈钢在2.5 mol/L硫酸 溶液中的表面成膜情况.运用电位阶跃研究了不锈钢在交变电场高电位、低电位下的电化学 反应；用AFM准现场地观察了不锈钢在交变电场下各个阶段的成膜状况；用XPS分析了膜层的 纵向组成结构.结果表明：交变电场下不锈钢表面钝化膜的生长机制不同于直流钝化.最后 分析了不锈钢在交变电场下的电化学反应和成膜机理.     

The influence of sulphate-reducing bacteria biofilm on the corrosion of stainless steel AISI 316

This work investigates microbially-influenced corrosion (MIC) of stainless steel AISI 316 by two sulphate-reducing bacteria, Desulfovibrio desulfuricans and a local marine isolate. The biofilm and pit morphology that developed with time were analyzed using atomic force microscopy (AFM). Electrochemical impedance spectroscopy (EIS) results were interpreted with an equivalent circuit to model the physicoelectric characteristics of the electrode/biofilm/solution interface. D. desulfuricans formed one biofilm layer on the metal surface, while the marine isolate formed two layers: a biofilm layer and a ferrous sulfide deposit layer. AFM images corroborated results from the EIS modeling which showed biofilm attachment and subsequent detachment over time.     

Preparation of epitaxial and polycrystalline bismuth titanate thin films on single crystal (100) MgO by chemical solution deposition

Epitaxial and polycrystalline Bi₄Ti₃O₁₂ thin films were prepared on single crystal (100) MgO substrates by a chemical solution deposition process using metal naphthenates as starting materials. Pyrolyzed films (at 500°C) were annealed for 30 min in air at 650, 700, 750 and 800°C, respectively. The effects of annealing temperature on the crystallinity, epitaxy and surface morphology of the films were investigated by X-ray diffraction θ-2θ scans, pole-figure analysis, and atomic force microscopy (AFM). Epitaxially grown films annealed at 700 and 750°C, respectively, showed growth of three-dimensional needle-shaped grains. During annealing at 800°C, grain growth of Bi₄Ti₃O₁₂ may be suppressed by the formation of a titanium-rich phase such as Bi₂Ti₂O₇ owing to Bi volatilization, resulting in lower root mean square roughness than that of film annealed at 750°C.     

基于AFM的纳米测试技术在机械领域中的应用

简要介绍了AFM的基本原理及操作模式。系统地阐述了AFM在国内外机械领域的发展现状，并进行了展望。     

基于CAM的STM和AFM的一种新型偏心升降装置研究

根据STM和AFM的扫描原理，通过CAM设计了一种新型偏心升降装置，使STM和AFM测试样品的高度大为增加，形成柔性测试系统。根据对实际工况的仿真研究，对装置进行了修改。     

CRYSTALLOGRAPHIC ANALYSIS OF THE LATH MARTENSITE TRANSFORMATION IN Fe-Ni-Mn ALLOY

1.IntroductionBased on the concept of an invariant plane strain (IPS), phenomenological theory of martensite transformation (PTMT) is established[1-3]. In this case, an invariant plane is obtained by self-accommoda-tion effect between different martensitic variants, and the formula which reveals this self-accommoda-tion effect can be written as …