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71.
AC and DC electrochemical experiments were performed as a function of humidity and contaminant concentration in an effort to identify the range of atmospheric environments where corrosion processes could be detected and possibly quantified. AC measurements exhibited two time constants at 25% relative humidity (RH), possibly indicating the ability to resolve both electrolyte resistance and interfacial impedance. Galvanic current measurements were sensitive to the presence of Cl2(g) at 30% RH and electrochemical transients were detected at both 30% and 50% RH levels, also indicating sensitivity to interfacial processes. Higher humidity levels allowed better quantification due to decreasing electrolyte and interfacial impedances. 相似文献
72.
以载重车用大型双鼓形铝轮毂精密模锻为应用对象,开发了分体组合式锻模工装,突破了普通模锻以单一最大水平投影面分模的限制,解除了双鼓形外形对模锻成形工艺的制约,并采用80000kN电动螺旋压力机进行精密模锻,保证了产品成形精度。 相似文献
73.
Xu-hui Zhao Yu Zuo Jing-mao Zhao Jin-ping Xiong Yu-ming Tang 《Surface & coatings technology》2006,200(24):6846-6853
The electrochemical behaviors of anodized aluminum in neutral NaCl and Na2SO4 solutions were studied using electrochemical impedance spectroscopy (EIS). The results reveal that there is a self-sealing process for unsealed anodic film in neutral NaCl and Na2SO4 solutions. The resistance of the porous layer (Rp) and the capacitance of the barrier layer (CPEb) increase and the capacitance of the porous layer (CPEp) decreases with immersion time in the initial stage. Corrosion resistance provided by the anodic film is improved by the self-sealing process of the porous layer. However, chloride ions have an opposite effect. The improving effect of the self-sealing process on film resistance is decreased with the increase of chloride concentration of the solution. 相似文献
74.
Andres Amador García-Granada Giovanni Gomez-Gras Ramón Jerez-Mesa Guillermo Reyes 《Materials and Manufacturing Processes》2017,32(11):1279-1289
Ball-burnishing induces compressive residual stresses on treated materials by the effect of plastic deformation. The result is an increase in the fatigue life of the treated part, retarding the initiation of cracks on the surface. Compressive residual stresses have been previously measured by X-ray diffraction near the surface, revealing considerably high values at the maximum analyzed depth, in relation to other finishing processes such as shot peening. However, the maximum analyzed depth is very limited by using this technique. In this paper, the incremental hole drilling (IHD) technique is tested to measure residual stresses, being able to reach a 2-mm measuring depth. To that objective, a commercial strain gage is used and calibrated using finite element model simulations. A second Finite Element Model based on material removal rate is developed to obtain the equations to calculate the strain release through IHD. Finally, residual stresses are measured experimentally with that technique on two different materials, confirming that ball-burnishing increases the compressive residual stresses in layers up to 0.5?mm deep for the testing conditions, which is a good response to industrial needs. The method proves to be suitable, simple and inexpensive way to measure the value of these tensions. 相似文献
75.
In this study, the very high cycle fatigue (VHCF) properties of 7050-T7451 aluminum alloy and its friction stir welding (FSW) butt welds have been investigated. The results show that the failure of FSW joints still occurs at 7.0 × 108 cycles. The fatigue properties of the FSW joints are superior to those of the base material, especially in the super long life regime. Most fatigue cracks initiate at the thermo-mechanically affected zone and heat affected zone on the advancing side of the FSW joints, and the susceptibility of these zones to fatigue is attributed to the metallurgical heterogeneity. 相似文献
76.
Duyao Zhang Shoujin Sun Dong Qiu Mark A. Gibson Matthew S. Dargusch Milan Brandt Ma Qian Mark Easton 《Advanced Engineering Materials》2018,20(5)
77.
First-principles calculations of binary Al compounds: Enthalpies of formation and elastic properties
Jiong Wang Shun-Li ShangYi Wang Zhi-Gang MeiYong-Feng Liang Yong Du Zi-Kui Liu 《Calphad》2011,35(4):562-573
Systematic first-principles calculations of energy vs. volume (E-V) and single crystal elastic stiffness constants (cij’s) have been performed for 50 Al binary compounds in the Al-X (X = Co, Cu, Hf, Mg, Mn, Ni, Sr, V, Ti, Y, and Zr) systems. The E-V equations of state are fitted by a four-parameter Birch-Murnaghan equation, and the cij’s are determined by an efficient strain-stress method. The calculated lattice parameters, enthalpies of formation, and cij’s of these binary compounds are compared with the available experimental data in the literature. In addition, elastic properties of polycrystalline aggregates including bulk modulus (B), shear modulus (G), Young’s modulus (E), B/G (bulk/shear) ratio, and anisotropy ratio are calculated and compared with the experimental and theoretical results available in the literature. The systematic predictions of elastic properties and enthalpies of formation for Al-X compounds provide an insight into the understanding and design of Al-based alloys. 相似文献
78.
The Al-Li-Zn system was critically assessed using the CALPHAD technique. The solution phases (liquid, bcc, fcc and hcp) were described by the substitutional solution model. The compounds Al2Li3 and Al4Li9 in the Al-Li system had homogeneity ranges of Zn and were treated as (Al,Zn)2Li3 and (Al,Zn)4Li9 in the Al-Li-Zn system, respectively. The compounds αLi2Zn3, βLi2Zn3, αLi2Zn5, βLi2Zn5 and αLiZn4 in the Li-Zn system had no solubility of the third component Al in the Al-Li-Zn system. A two-sublattice model (Al,Li,Zn)0.2(Al,Li,Zn)0.8 was applied to describe the compound βLiZn4 in the Al-Li-Zn system in order to cope with the order-disorder transition between hexagonal close-packed solution (hcp-A3) and βLiZn4 with the Mg-type structure. The ternary compound τ2 with a NaTl-type structure (B32) had the same structure with the compounds AlLi in the binary Al-Li system and LiZn in the binary Li-Zn system. In the present work, the three compounds AlLi, LiZn and τ2 were treated as one phase by a two-sublattice model (Al,Li,Zn)0.5(Al,Li,Zn)0.5 in order to cope with the order-disorder transition between B32(AlLi, LiZn and τ2) and body-centered cubic solid solution (bcc-A2). The ternary intermetallic compounds τ1 and τ3 in the Al-Li-Zn system were treated as the formula Li(Al,Zn)2 and (AlLi,Zn)Zn3, respectively. A set of self-consistent thermodynamic parameters describing the Gibbs energy of each individual phase as a function of composition and temperature in the Al-Li-Zn system was obtained. 相似文献
79.
针对铝电解槽温度高、腐蚀性强、温度难以直接连续测量的问题,引用BP神经网络技术,选择铝电解槽的输入电流、电压和下料速度作为辅助变量,建立BP神经网络模型,并利用matlab对数据样本进行了标准化处理,实现了BP神经网络的建立、训练和仿真。在预焙阳极铝电解槽进行实验,通过预算温度与实际温度进行对比,结果证明了该方法的有效性。 相似文献
80.
Potentiometric cell, Au/LiCoO2 5 m/o Co3O4/Li2.88PO3.73N0.14/Li2CO3/Au, has been fabricated and investigated for monitoring CO2 gas. A LiCoO2–Co3O4 mixture was used as the solid-state reference electrode instead of a reference gas. The idea is to keep the lithium activity constant on the reference side using thermodynamic equilibrium at a given temperature. The thermodynamic stability of the reference electrode was studied from the phase stability diagram of Li–Co–C–O system. The Gibb’s free energy of formation of LiCoO2 was estimated at 500°C from the measured value of the cell emf. The sensors showed good reversibility and fast response toward changing CO2 concentrations from 200 to 3000 ppm. The emf values were found to follow a logarithmic Nernstian behavior in the 400–500°C temperature range. CH4 gas did not show any interference effect. Humidity and CO gas decreased the emf values of the sensor slightly. NO and NO2 gases affect this sensor significantly at low temperatures. However, increased operating temperature seems to reduce the interference. 相似文献