Q235B 热轧H型钢拉伸试验分层断口的显微分析

Q2 35B热轧H型钢拉伸试验后出现分层断口。用扫描电镜进行了显微观察 ,发现分层现象与试样中超长的带状组织密切相关。用能谱仪对断口分层处和超长铁素体带上的夹杂物进行了成分分析 ,证实都是硫化物。试样拉伸时在铁素体带上密集分布的硫化物处产生大量微裂纹 ,同时超长铁素体带的变形又受到阻碍 ,导致该处在试样拉断之前裂纹已经贯通 ,最终在断口上形成分层。因此 ,拉伸试验断口出现分层的原因是试样中存在密集分布的硫化物和超长的带状组织。     

Thermal spray vitrification process for the removal of lead-based paint from steel structures: An applications note

Lead-based paints and primers have long been used to protect steel structures from corrosion, but are now recognized as environmental hazards. During lead-based paint removal via abrasive blasting, federal, state and local environmental requirements mandate the use of containment structures to prevent contamination of air, soil, or water. The thermal spray vitrification (TSV) process was developed and optimized in laboratory experiments to remove hazardous lead-based paint. TSV consists of thermal spraying a molten glass onto the painted surface. As the glass strikes the substrate, it reacts with the paint, and organic components are pyrolyzed, while lead ions are trapped on the glass surface. Quenching stresses in the glass cause it to crack and spall off the substrate. The resulting glass fragments are collected, and further remelted to completely immobilize lead (Pb) ions in the glassy iron (Fe) silicate matrix. The glass waste is thus rendered non-hazardous, as determined by the Toxicity Characteristic Leaching Procedure (TCLP). The TSV process was field tested on a fire hydrant, using minimal personal protective equipment and without using a containment structure. The lead-containing paint was removed, without producing hazardous waste, leaving de-painted surfaces suitable for repainting.     

Influence of chromium on the local structure and morphology of ferric oxyhydroxides

The extended X-ray absorption fine structure (EXAFS) method and transmission electron microscopy (TEM) have been used for characterizing the local structure and morphology of ferric oxyhydroxides, α-FeOOH and γ-FeOOH, with and without chromium. These ferric oxyhydroxide powders were prepared from aqueous solutions containing iron and chromium ions. Radial structural functions for iron obtained by Fe K edge EXAFS spectra showed that the linkage of structural units formed by FeO₆ octahedra in γ-FeOOH is distorted by chromium addition, while such distortion in α-FeOOH is not clearly detected. On the other hand, Cr K edge EXAFS spectra showed that the local structure around chromium does not necessarily correspond to the local structure around of iron, which is observed by Fe K edge EXAFS spectra. This suggests that the structural units containing iron and chromium are heterogeneously distributed in these ferric oxyhydroxides. The local structural information was discussed coupled with morphological features of these ferric oxyhydroxides observed by TEM.     

H13模具钢离子渗氮层的组织与性能

利用10kW的等离子体气相沉积炉对H13钢进行了离子渗氮处理，研究了不同温度及时间对渗氮层组织及性能的影响。结果表明，采用合适的处理温度和时间，可以得到最佳的渗氮层化合物相组成及表面硬度，在保证一定的渗氮层深度条件下，H13钢的耐磨性能明显提高。     

Effect of welding heat input on HAZ character in ultra-fine grain steel welding

In this essay, we studied how heat input affected the microstructure, hardness, grain size and heat-affected zone (HAZ) dimension of WCX355 ultra-fine grain steel which was welded respectively by the ultra narrow-gap welding (UNGW) process and the overlaying process with CO2 as protective atmosphere and laser welding process. The experimental results show when the heat input changed from 1.65 kJ/cm to 5.93 kJ/cm, the width of its HAZ ranged from O. 6 mm to 2. 1 ram. The average grain size grew up from 2 ~ 5 pln of base metal to 20～70 um and found no obvious soften phenomenon in overheatedzone. The width of normalized zone was generally wide as 2/3 as that of the whole HAZ, and the grain size in this zone is smaller than that in base metal. Under the circumstance of equal heat input, the HAZ width of UNGW is narrower than that of the laser welding.     

N80钢CO2腐蚀产物膜研究

在模拟油田CO2腐蚀环境下，用XRD、EDS和SEM研究了N80钢腐蚀产物膜的形成与发展情况。结果表明，在本试验条件下N80钢CO2腐蚀产物膜对基体具有一定的保护作用，可以降低腐蚀速率。腐蚀产物膜分3层，讨论了3层膜的结构特征与形成机理。初步研究了腐蚀产物膜的破坏特征。腐蚀产物膜的晶体类型是（Fe,Ca)CO3复盐。     

K/Na-V-Mo复合变质对轧辊用高速钢组织及性能的影响

通过对轧辊用高速钢进行复合变质及热处理。探讨了含碱金属K/Na以及V、Mo合金元素的变质剂的加入量对轧辊用铸造高速钢共晶组织的影响。试验结果表明：在1．0％范围内，随着复合变质剂含量的逐渐增加，共晶碳化物的形貌和分布得到了改善，晶粒得到细化，分布趋于均匀，轧辊用高速钢的硬度略有下降，但韧性有很大提高。变质剂含量继续增加，组织和性能没有明显改善。进一步分析表明：变质剂中的合金元素可促进在晶粒中或沿晶界均匀分布的非连续状硬质碳化物的生成．从而达到改善组织、提高力学性能的作用。     

冲击腐蚀磨损系统中影响因素的正交分析

用改进的MLD-10型冲击腐蚀磨损试验机，对不同条件下的冶金矿山用低碳高合金钢的冲击腐蚀磨损性能进行了试验。用正交分析法研究了磨粒，冲击功和pH值在低碳高合金钢冲击腐蚀磨损过程中的作用。结果表明，磨粒在冲击腐蚀磨损过程中对材料的影响最大，其次为冲击功，pH值的影响最小。     

双金属复合板带可逆冷轧有限元模拟

本文应用ANSYS有限元软件分析了热轧复合的不锈钢复合板在冷轧过程中的变形特性和界面上应力应变分布 ,分析确定了界面结合强度 ,以及确定成卷可逆带张力冷轧时的最大道次压下量值。用 3D FEM模拟了接触表面上的应力 ,计算出总轧制压力 ,与理论公式进行了对比。     

反渗透前不锈钢换热器失效的原因及其防护

嘉兴发电厂二期工程化学补给水系统两套板框式316不锈钢加热器在短时间内相继损坏失效,在对换热器运行条件、失效宏观特征、腐蚀产物特征和材料化学成分的分析后,得出了应力腐蚀破裂的结论,并提出了相应的防范措施。