95W-Ni-Fe 合金工艺缺陷的 SAM 和 XPS 分析

藉助扫描俄歇探针、Ｘ射线光电子谱等分析了９５Ｗ－Ｎｉ－Ｆｅ合金碳污染和氧化的本质。发现，碳污染试样中碳的化学状态主要为石墨，少量为铁或镍的有机化合物，这些物质的界面富集使材料脆化。钨合金氧化后，氧大量富集于钨／粘结相界面，使沿着该界面的断裂更容易发生。     

四氯化碳生产中氯化反应的回火原因分析与对策

探讨了四氯化碳生产中氯化反应的回火原因及避免回火的对策 ,解决了生产中的实际问题     

担载型含稀土三组份体系在二氧化碳甲烷化反应中的催化性能

用浸渍法制备了一系列氧化锆担载的含稀土Ⅷ族金属催化剂，对其在二氧化碳甲烷化过程中的催化活性作了研究，并用漫反射紫外可见光谱，ＦＴＩＲ等手段对催化剂作了表征。结果表明，含稀土新型催化剂具有催化活性高，目标产物选择性好等优点；稀土主要以氧化物形式存在于催化剂表面，参与对氢及表面含碳物种的吸附及活化；含稀土三组份催化剂的活性与所添加稀土三价离子的４ｆ电子数有关。     

Using the high pressure methane isotherm for determination of pore size distribution of carbon adsorbents

A method of determining pore size distribution, PSD, of carbon adsorbents based on the high pressure methane isotherm is presented. A generic software package, and an IBM compatible PC, have been used to search for a PSD in the form of a histogram. The method relies on a known local isotherm, in this case, assuming a simplified model of infinite slit shaped carbon pores.Three carbons, having very different pore structures: BPL, PX-21, and PVDC, were analyzed using the new method and the results compared with those obtained from subcritical Ar, and N₂ isotherms. The analysis from the high pressure methane isotherm gave results which are different than those from the low pressure low temperature isotherms but not significantly enough to be unrealistic.     

Alkylated ureas: mineralization and evaluation as N sources

An incubation experiment was conducted for 11 weeks to study the mineralization of ten alkylated ureas and urea in soil. Six of the alkylated ureas viz. methylurea(MU), 1,3-dimethylurea(1,3DMU), 1,1-dimethylurea(1,1DMU), ethylurea(EU), 1,3-diethylurea(1,3DEU) and butylurea(BU) and urea mineralized during the experiment. Urea mineralized immediately, while alkylated ureas mineralized after an incubation period ranging from less than a week to four weeks (delay period of mineralization). The delay period increased in the following sequence MU < 1,3DMU < EU < BU < 1,1DMU < 1,3DEU, but after the delay period was over the compounds mineralized almost as rapidly as urea. The delay period varied according to the number of carbon atoms in the alkyl group and their position with respect to each other on the molecule. It appeared to be specific for each compound and was apparently not influenced by the presence of urea or other alkylated ureas. This character can be used to develop mixture of various alkylated ureas to obtain N mineralization at the desired time. Rapid evolution of CO₂ and N₂O was observed during the mineralization of urea as well as alkylated ureas. Increase in soil pH was also observed during this period. The simultaneous ocurrence of these events suggested the formation of urea as an intermediate during the mieralization of alkylated ureas. None of the alkylated ureas showed adverse affect on emergence of wheat seedlings and except DEU and BU at high concentration no other alkylated urea showed any adverse effect on initial growth of wheat seedlings.     

真空阴极弧离子镀类金刚石碳（DLC）膜的碳弧稳定性研究

选用氩气、氩气加氢气、氩气加乙炔等气体作为介质，石墨作为靶材进行真空阴极弧离子镀来制备类金刚石碳膜。石墨电弧有其独特的电弧特性曲线，不同气体介质对碳弧特性的影响不同，磁场的大小对电弧的稳定性有很大作用，碳弧下基片偏流随电弧电压的增加而减小，试验得到表面光滑的类金刚石碳（DLC）膜，对膜的表面进行了SEM分析。     

氯化氢浸渍活性炭净化汞蒸气的研究

用氯化氢对吸附汞热气用的活性炭进行浸渍处理是一种新的偿试。用氯化氢浸渍后的活性炭，对汞的吸附效率和吸附容量与没有浸渍的活性炭相比，均有很大的提高，同时，与其它吸附汞用的浸渍剂相比，具有价格低，来源广的优点，对汞的吸附效率平均在９５％以上。     

中国南海北部二氧化碳气成因

中国南海北部海域在油气勘探中发现了CO_2气,对油气有无影响?在借鉴世界、中国东部陆地CO_2气成因研究成果的基础上,从分析研究区CO_2,气的分布入手,采用多种方法,在综合分析基础上,对本区CO_2气藏进行分类.认为研究区CO_2;气藏为无机成因,其特征受各盆地或地区具体地质条件的控制.哈萨克斯坦引起了国际石油界的很大关注,但它并不是前苏联唯一的具吸引力之地.美国地质调查调查所(丹佛)和AAPG今年著名讲演者Gregory F Ulmishek说.前苏联有20多个沉积盆地生产油气或具有尚未开采的发现.Ulmishek 1980年到美国前,获得过莫斯科石油学院地质学硕士学位,作为一个地质学家在前苏联工作过23年.他的1993—1994年题为“前苏联主要油气地质学及勘探潜力”的著名演讲在1993年12月6日至17日和1994年3月28日至4月8日的巡回活动中推出.     

Influence of rainfall on the performance of bioretention systems modified with activated carbon and biochar

The use of bioretention areas is common in urban stormwater management, but their performance varies significantly depending on rainfall characteristics and design conditions. In this study, a pilot experiment using bioretention columns with different media (commercial activated carbon and river sediment-derived biochar) investigated the influence of rainfall on bioretention performance. The results indicated that the runoff volume retention ratio (R_v), which included the runoff purified and discharged at the bottom of the column, and the runoff retained in media during rainfall event, decreased significantly with increases in the rainfall event return period (p < 0.05). The R_v of the activated carbon and biochar columns decreased with a 2-yr return period and then fell further with a 50-yr return period. Porous material has been shown to improve the water-holding capacity of bioretention media, but it did not result in an improved R_v under heavy rain that exceeded the 2-yr return period. With the increase of the return period from two to 50 yr, the mass removal efficiency (R_L) of total phosphorus and phosphate illustrated a clear decreasing trend in all columns. The total nitrogen, ammonia and nitrate removal did not show a clear trend with return periods because of transformations among different forms of nitrogen and similar saturation periods during the different rainfall events. The influence of the return period on chemical oxygen demand (COD) removal was related to whether the inflow COD reached maximum COD removal capacity of the bioretention media. Under a rainfall event with a specific return period, there were no significant differences in the R_L of all nitrogen species and COD among the different columns (p > 0.05). The addition of adsorptive material, such as activated carbon and biochar, may not be the key factor for improving nitrogen and COD removal under heavy rain that exceeds the 2-yr return period. The bioretention performance of phosphorus removal from urban stormwater runoff could be improved by replacing or adding media with high adsorption capacity, but these improvements would not be significant under heavy rain that exceeds the 2-yr return period. The results provide some reference for evaluating bioretention performance and optimizing bioretention design in the future.     

中碳结构钢件的锻造成形与锻后调质一次完成的热加工新技术

本文是利用“形变诱发析出”原理通过控制热变形成形过程获得一种能在过冷分解时使碳化物呈颗粒状弥散析出的形变奥氏体状态,又通过控制冷却抑制先共析铁素体的析出,同时促进碳化物颗粒的析出,从而得到100％调质型组织,它达到了传统工艺的水平。