2500m^3高炉基础自动化系统构成

介绍新钢2×2500m^3高炉基础自动化系统各个子系统的构成,以及环形网络的构成及配置方法。     

Vibrational dynamics and heat capacity in syndiotactic poly(propylene) form I

Normal modes of vibration of syndiotactic polypropylene (sPP) and their dispersion are obtained in the reduced zone scheme for helical form I having the conformational sequence (t₂g₂) using Urey-Bradley force field and Wilson's GF matrix method as modified by Higgs. Optically active frequencies corresponding to the zone center and zone boundary are assigned and characteristic features of the dispersion curves are discussed. In general the dispersion in the helical form is less as compared to the planar form. Heat capacity has been calculated via density-of-states using Debye relation in the temperature range 10-460 K and compared with the experimental measurements.     

间羟基二乙基苯胺生产废水预处理研究

间羟基二乙基苯胺是一种染料中间体,其生产废水CODCr高,成分复杂。应用曝气吹脱 电解法对其高盐废水预处理工艺进行了可行性的研究,建立了曝气吹脱 电解法预处理方案。曝气吹脱与电解法的CODCr去除率分别可达20%与80%,提高了可生化性,便于后接生化处理。经实验优选最佳工艺参数为:曝气吹脱pH值4 0,曝气吹脱时间90min;电解进水pH值7 0左右,电解外加电压7V,电解停留时间120min,电极板间距3cm。     

给水球墨铸铁管腐蚀特性及腐蚀对水质的影响

为研究给水球墨铸铁管腐蚀特性及腐蚀对水质的影响,以球墨铸铁管为主体制作三电极反应体系,以微生物为控制变量利用电化学工作站测定球墨铸铁管电化学腐蚀参数,同时分析腐蚀体系内水体水质变化.结果表明:非灭菌组自腐蚀电位66 d均值-0.515 V,自腐蚀电流密度均值7.61×10-4m A/cm~2,期间水质迅速变差,总铁质量浓度3 d后超标,色度和浊度最终分别达72、115 NTU.灭菌组自腐蚀电位66 d均值-0.471 V,自腐蚀电流密度均值5.26×10-4m A/cm~2,腐蚀强度较灭菌组稍缓,但水体最终变成"黄水".没有或失去防腐涂层而暴露于水体中的给水球墨铸铁管初期极易发生以电化学腐蚀为主的综合性腐蚀,严重影响水质.     

广州市用水结构空间均衡差异性分析

以空间均衡治水方针为指导思想,采用基于洛伦兹曲线、基尼系数的方法,对广州市用水结构整体趋势及均衡差异性进行了分析。结果表明:广州市用水结构空间分配不够均衡,大部分区域已超过设定的警戒线标准;农业用水空间分配差距较大,主要集中于从化、花都、增城区等市内非核心区;工业用水结构虽然整体分布较均衡,但黄埔区与其余区域存在巨大差异,区位熵是其他区域工业平均区位熵的3倍;居民生活、城镇公共、生态环境用水结构空间分配差距悬殊,表现为向天河、越秀、荔湾等市内核心区域集中,且用水量保持逐年增加的趋势,这在一定程度上加剧了区域差异性;各类用水结构差异性虽已得到有效控制,空间均衡性处于平稳阶段,但仍未达到"空间均衡"治水目标,应进一步强化用水监督管理,实现用水结构合理布局和水资源的优化配置。     

红外/热导法检测C-103中氧氮含量

使用LECO ON736氧氮分析仪,采用红外和热导法,对C-103铌铪合金中氧、氮含量进行检测。通过助熔剂处理、坩埚选择、定量下限、分析功率、试样质量、精密度和加标回收实验,建立了C-103中氧、氮含量的检测方法。该方法氧和氮的RSD分别为3.36%和6.86%,加标回收率分别为95.5%~106.0%和92.5%~107.5%,精密度和加标回收实验结果良好,满足分析需要。     

平面铰链四杆机构的轨迹综合方法

为提高平面铰链四杆机构轨迹综合的速度与精度,提出基于B样条曲线的综合方法.采用三次非均匀B样条曲线对连杆曲线进行拟合,将B样条曲线控制多边形各相邻两边的夹角作为连杆曲线的特征参数,将大量连杆曲线特征参数和对应的机构尺寸参数存入计算机以建立电子图谱库;当输入一定数目的有序离散数据点时,通过B样条曲线拟合得到期望曲线,提取期望曲线的特征参数;再利用神经网络将期望曲线的特征参数与电子图谱库中特征参数进行匹配,从而找到满足要求的机构,最终达到轨迹综合的目的.设计实例表明,该方法可快速实现四杆机构的轨迹综合,综合的精度高且所提取的特征参数与连杆曲线方位、缩放比例无关,减少了图谱库的数据冗余.     

FEM analysis of vacuum hot bulge forming of Hastelloy C-276 thin-walled cylindrical workpiece

A stress relaxation test has been carried out for Hastelloy C-276 at temperature of 800 ~C and initial stress level of 250 MPa. Based on the experimental stress relaxation curve, the relationship between creep strain rate and stress has been derived. Then, a set of creep constitutive equations has been built and the values of constants arising in the constitutive equations have been determined by fitting the creep strain rate-stress curve. Close agreement between computed results and experimental ones is obtained for stress relaxation data. The creep constitutive equation set has been integrated with the commercial FE （finite element） solver MSC.Marc via the user defined subroutine, CRPLAW, for the vacuum hot bulge forming process modelling of Hastelloy C-276 thin-walled cylindrical workpiece. The temperature field, the radius-direction displacement field and the stress-strain field are calculated and analyzed. Furthermore, the bulging dimension and the final internal diameter of workpiece are predicted and the test results verify the reliability of the finite element method.     

中温固体电解质Ce_(0.8)Gd_(0.2-x)Y_xO_(2-δ)(x=0,0.05,0.10)的制备与性能研究

用溶胶-凝胶法合成了固体电解质Ce0.8Gd0.2-xYxO2-δ(x=0,0.05,0.10).用X射线衍射谱、拉曼光谱分析了样品的微观结构,用交流复阻抗谱研究了样品的电学性能.结果表明:800℃焙烧的所有样品均为具有氧缺位的单相立方萤石结构,晶胞参数随钇(Y)掺杂量增加而减小.钇掺杂量x=0.05的样品Ce0.8Gd0.15Y0.05O2-δ的电导率最高,导电活化能最小,(σ700℃=5.58×10-3S·cm-1,Eα=0.92 eV),高于未掺杂Y的Ce0.8Gd0.2O2-δ样品的电导率(σ700℃=5.38×10-3S·cm-1Eα=1.09 eV).说明适量双掺杂Y提高了Ce0.8Gd0.2-xYxO2-δ的电导率并且降低了其活化能.     

Oxidation behavior of 2.25Cr-1Mo steel with prior tempering at different temperatures

The oxidation behavior of a normalized 2.25Cr-1Mo steel tempered previously for 10 hr at different temperatures between 873 and 1023 K has been studied up to a maximum duration of 1000 hr in air at 773–973 K. The oxidation resistance of the steel was found to decrease significantly with the temperature of tempering. Tempering of this steel is reported to cause microstructural changes involving precipitation of Cr as carbides and a decrease in the effective (free) Cr contents, that could influence the oxidation resistance of the Cr-containing alloys. Relative compositions across the thickness of the oxide scales, as analyzed by SEM/EDX and SIMS, suggest that a less Cr-rich (and less protective) and thicker scale on the steel formed because previous tempering caused extensive depletion of free Cr.