Oligomer-Rich Fraction from Polydisperse Sample of Poly(bis(β-phenoxyethoxy)phosphazene)

Poly[bis(-phenoxyethoxy)phosphazene] [PBPEP] had been shown in our previous paper to be a very useful polymer for investigating the crystallization mechanism of polymers, as the crystallization rate of PBPEP is extraordinarily small when isothermally crystallized from the melt. The crystallization of the low molecular weight oligomers of PBPEP was first studied in comparison to the high molecular weight polymers. The oligomer-rich fraction was obtained by fractionation of the as-polymerized sample, which had a broad molecular weight distribution. The fractions thus obtained were characterized by solution viscometry and size exclusion chromatography. The melting temperature and the growth rate of the spherulite from the melt were investigated by differential scanning calorimetry and optical microscopy. The growth rate was one or two orders of magnitude smaller in the oligomer-rich fraction than in the other high molecular weight fractions. A collapsed spherulite appeared in the oligomer-rich fraction at high crystallization temperatures. It is speculated that in the oligomer-rich fraction there is an excess free energy due to defects in the crystal phase. This defect is considerably larger in the oligomer-rich fraction than in the other fractions because a large quantity of short length chains is present.     

云模型在测井曲线分层中的应用

针对由模糊信息导致测井曲线人工分层的不准确,提出了一种基于云模型的测井曲线自动分层方法.而云模型能同时体现概念的随机性和模糊性,利用云变换从测井曲线中提取定性概念,然后对提取的概念进行概念跃升,使得算法输出的概念层次更符合实际.实验表明,该方法能够较准确地提取和表征定性概念,所提取的概念中心与传统测井曲线分层方法得到的概念中心吻合较好,验证了算法的有效性,提高了测井曲线分层的准确性.     

NURBS曲线C~1连续参数优化算法

曲线的参数特性直接决定基于自由曲线的路径规划、运动控制等算法的质量.为了生成满足C1连续的近似弧长参数化,提出一种基于分段三次重新参数化的参数优化算法.首先利用Simpson方法离散积分能量,然后使用极值求解法求得初始解,最后通过LM(Levenberg-Marquardt)优化算法计算出曲线的最优参数表示.与C1连续的分段有理重新参数化方法相比,该算法能够在分段数量很少的情况下达到局部最优.最后通过实例说明了文中算法的有效性.     

基于轮廓线局部描述符的三维人脸识别

提出了一种基于等测地轮廓线的局部描述符来识别三维人脸。首先对三维人脸数据进行预处理, 得到统一的人脸区域并进行姿态归一化; 然后根据测地距离提取到鼻尖点相同距离的点组成等测地轮廓线, 对轮廓线进行重采样, 并对轮廓线上每个采样点的邻域提取局部描述符; 最后在建立测试人脸和库集人脸的点对应关系后进行局部描述符的加权融合和比较, 给出最终识别结果。算法在FRGC(face recognition grand challenge)v2. 0数据库上进行测试, 实验结果表明该方法具有较好的识别性能。     

13C n.m.r. study of raw materials for carbon black

¹³C n.m.r. spectroscopy has been applied to investigate a number of coal tar and petroleum-derived carbon black feedstocks. Application of the J-modulated spin echo technique is especially rewarding, as this method renders the quaternary carbons directly detectable. Thus the quality of carbon black feedstocks can additionally be gauged on the basis of the contents of quaternary carbons, which is a direct indication of the carbon yield in the carbon black production process.     

Analysis of epoxidized natural rubber. A comparative study of d.s.c., n.m.r., elemental analysis and direct titration methods

A comparative analysis of epoxidized natural rubber samples by ¹H and ¹³C n.m.r., titrimetric, elemental and d.s.c. techniques has been made. Whereas the titrimetric method is only applicable at low epoxy contents (< 15 mol%) both n.m.r. methods give reasonable precision over the compositional range of 20–75 mol%. Elemental analysis appears less reliable. D.s.c. analysis through measurement of T_g provides the highest precision of measurement but requires independent calibration by one or more of the primary methods. The epoxy content may also be related to the polymer density.     

无磷助洗剂δ-层状二硅酸钠

分析了现用助洗剂三聚磷酸钠、4A沸石、偏硅酸钠存在的问题及禁磷的重要性,重点论述了δ-层状结晶二硅酸钠用作助洗剂的各种性能及效果,认为δ-层状结晶二硅酸钠是一种良好的无磷助洗剂,它具有其他助洗剂所不具备的优良性能;对δ-层状结晶二硅酸钠的制备工艺作了简要介绍,并作了市场及在国内工业化生产的可性行分析。     

The influence of an intermediate MoO3 layer on the solid state reaction of cobalt oxide withγ-Al2O3

In view of the importance for Co_xO_y,-MoO₃/-Al₂O₃ hydrodesulphurization (HDS) catalysts, the reactivity of cobalt oxide layers towards cobalt aluminate formation was investigated on both MoO₃-covered and bare -Al₂O₃ substrates. Co₃O₄/MoO₃/-Al₂O₃ and Co₃O₄/-Al₂O₃ systems were prepared by vapour-deposition of MoO₃ (12 × 10¹⁵ Mo atoms/cm²) and Co (400 × 10¹⁵ Co atoms/cm²) layers onto a -Al₂O₃ substrate, followed by oxidation of the Co layer to Co₃O₄. After annealing at 800°C for 40 h, the interfacial reaction to cobalt aluminate was assessed using Rutherford backscattering spectrometry. The presence of molybdenum oxide appeared to enhance cobalt aluminate formation. The Mo atoms, which spread out over the entire cobalt-containing layer, presumably caused a high defect density, which explains the observed higher reaction rate. The amount of MoO₃ was much too low to stabilize all cobalt atoms by cobalt molybdate formation.     

轻骨料混凝土应力应变关系的试验分析

通过轻骨料混凝土LC30,LC40与普通混凝土C30,C40的对比试验,研究了同等强度等级下轻骨料混凝土与普通混凝土的力学性能;得出了不同强度等级的轻骨料混凝土的应力应变关系曲线.将试验结果与规程模型进行对比,分析其差异,进一步给出下降段的应力应变曲线方程.     

7.63m特大型焦炉砌筑施工技术及要点

主要针对7.63m特大型焦炉砌筑施工技术,从工程实践效果分析其施工技术在质量、工期、成本等方面收到良好的经济效益和社会效益,现对7.63m特大型焦炉施工技术作简要介绍。