Achieving California's 80% greenhouse gas reduction target in 2050: Technology,policy and scenario analysis using CA-TIMES energy economic systems model

The CA-TIMES optimization model of the California Energy System (v1.5) is used to understand how California can meet the 2050 targets for greenhouse gas (GHG) emissions (80% below 1990 levels). This model represents energy supply and demand sectors in California and simulates the technology and resource requirements needed to meet projected energy service demands. The model includes assumptions on policy constraints, as well as technology and resource costs and availability. Multiple scenarios are developed to analyze the changes and investments in low-carbon electricity generation, alternative fuels and advanced vehicles in transportation, resource utilization, and efficiency improvements across many sectors. Results show that major energy transformations are needed but that achieving the 80% reduction goal for California is possible at reasonable average carbon reduction cost ($9 to $124/tonne CO₂e at 4% discount rate) relative to a baseline scenario. Availability of low-carbon resources such as nuclear power, carbon capture and sequestration (CCS), biofuels, wind and solar generation, and demand reduction all serve to lower the mitigation costs, but CCS is a key technology for achieving the lowest mitigation costs.     

The impact of China's carbon allowance allocation rules on the product prices and emission reduction behaviors of ETS-covered enterprises

It is an important task for China to allocate carbon emission allowance to realize its carbon reduction target and establish carbon trading market. China has designed several allocation rules within seven pilot regions. What influence those rules may cause is closely related with the enthusiasm of emission trading scheme (ETS) covered enterprises' participation in carbon market, and more importantly, with the mechanism design and sustainable development of carbon market. For this purpose, the multi-stage profit model is developed to analyze the ETS-covered enterprises' product prices and emission reduction behaviors under different allocation rules. The results show that, first, under the rules of grandfathering, self-declaration and auctioning, when deciding the optimal product price and optimal carbon emission reduction, those enterprises may focus on maximizing current stage profit; however, under the rule of benchmarking, those enterprises may care more about the impact of current decisions on the profit in next stage. Second, the optimal product price policy is positively correlated with the price of the same kind products, consumers' low-carbon awareness and government subsidy. Finally, along with the increase of carbon price, consumers' low-carbon awareness and government subsidy and the decrease of carbon emission cap, those enterprises tend to reduce carbon emissions.     

Analytical evaluation of different carbon sources and growth stimulators on the biomass and lipid production of Chlorella vulgaris – Implications for biofuels

The key challenges in lipid production from marine microalgae include the selection of appropriate strain, optimization of the culture conditions and enhancement of biolipid yield. This study is aimed at evaluating the optimal harvest time and effect of chlorella growth factor (CGF) extract, carbon sources and phytohormones on the biomass and lipid production in Chlorella vulgaris. CGF, extracted using hot water from Chlorella has been reported to possess various medicinal properties. However, in the present study, for the first time in C. vulgaris, CGF was found as a best growth stimulator by enhancing the biomass level (1.208 kg m⁻³) significantly on day 5. Gibberellin and citrate augmented the biomass by 0.935 kg m⁻³ and 1.025 kg m⁻³. Combination of CGF and phytohormones were more effective than CGF and carbon sources. Analysis of fatty acid methyl esters indicated that the ratio of saturated to unsaturated fatty acids is higher in cytokinin, abscisic acid and CGF, and are also rich in short chain carbon atoms, ideal criteria for biodiesel. Nitrogen starvation favoured synthesis of more unsaturated fatty acids than saturated. This study shows that CGF enhances the biomass and lipid significantly and thus can be used for large scale biomass production.     

Influence of inoculum cell density and carbon dioxide concentration on fed-batch cultivation of Nannochloropsis oculata

The marine microalgae Nannochloropsis oculata is a promising source of biofuel because of its high lipid content. For achieving high productivity of oil from microalgae, a high cell concentration before harvesting is beneficial. The present study investigated fed-batch cultures of N. oculata fed with vitamins and nutrient solutions and found that the biomass yield of N. oculata in the fed-batch culture was 1.25 times higher than that in batch culture. Fed-batch cultivation, especially at high illumination, decreased the inhibitory effect of high carbon dioxide (CO₂) concentration on the microalgal growth. The specific growth rate was directly proportional to the light intensity in the CO₂ environment. A light intensity of 40,000 Lux was able to achieve high specific growth rates in fed-batch cultivation at a CO₂ volume fraction of 2%–15%. The tolerance of N. oculata to CO₂ was enhanced by the daily feeding of nutrients in the fed-batch cultivation. At 2% CO₂, a final cell density of about OD₆₈₂ = 11.4 was achieved in the fed-batch culture in 30 days. Furthermore, a cell density of 14.4 g L⁻¹ was obtained by outdoor fed-batch cultivation in 27 days.     

Baselines for carbon emissions in the Indian and Chinese power sectors: Implications for international carbon trading

The study examines the dynamics of carbon emissions baselines of electricity generation in Indian states and Chinese provinces in the backdrop of ongoing electricity sector reforms in these countries. Two Indian states—Gujarat and Andhra Pradesh, and three Chinese provinces–Guangdong, Liaoning and Hubei have been chosen for detailed analysis to bring out regional variations that are not captured in aggregate country studies. The study finds that fuel mix is the main driver behind the trends exhibited by the carbon baselines in these five cases. The cases confirm that opportunities exist in the Indian and Chinese electricity sectors to lower carbon intensity mainly in the substitution of other fuels for coal and, to a lesser extent, adoption of more efficient and advanced coal-fired generation technology. Overall, the findings suggest that the electricity sectors in India and China are becoming friendlier to the global environment. Disaggregated analysis, detailed and careful industry analysis is essential to establishing a power sector carbon emissions baseline as a reference for CDM crediting. However, considering all the difficulties associated with the baseline issue, our case studies demonstrate that there is merit in examining alternate approaches that rely on more aggregated baselines.     

Interactions between electricity-saving measures and carbon emissions from power generation in England and Wales

The relationship between electricity demand reduction and the consequent change in carbon emissions is central to greenhouse gas emissions policy. This paper examines this relationship for the power system of England and Wales. Previous analysis showed that the commonly used conversion factor based on the system average emission factor significantly underestimates these savings (Hitchin and Pout, 2002. The carbon intensity of electricity: how many kgC per kWhe?. Building Serv. Eng. Res. Technol. 23(4)). Thus any policy analysis based on the system-average emission factor will under-estimate the potential for carbon savings from reductions in electricity demand. The present paper extends the previous analysis by using more detailed modelling to explore differences between demand reductions of differing load shape and magnitude; and the sensitivity of these figures to changes of the fuel mix of the generation system.     

二氧化碳收集利用与处置技术分析

化石燃料的燃烧是百余年来大气中二氧化碳(CO2)浓度增加的主要原因。CO2的收集和处置则是抑制这一趋势的有效途径。本文通过对现有收集利用和处置技术的分析,认为火电厂是收集CO2的重点考虑对象;CO2用于三次采油及天然气回收在技术上和经济上比较可行;蓄水层储气前景广阔值得研究;深海处置有待进一步探索;CO2用于置换开采天然气水合物也是很有前景的方案。     

Photocatalytic degradation of pesticide contaminants in water

Photocatalysis has been proved to be an effective and inexpensive tool for the removal of organic and inorganic pollutants from water. Of particular interest in this context, in recent years, has been the complete photocatalytic mineralisation of a variety of pesticides into harmless products. The technique is now reaching the pre-industrial level, with several pilot plants and prototypes being operational in various countries. This paper reviews the major developments in the area, with special reference to the mechanism of the process involved, nature of the reactive intermediates and final products.     

Engineering economic analysis of biomass IGCC with carbon capture and storage

Integration of biomass energy technologies with carbon capture and sequestration could yield useful energy products and negative net atmospheric carbon emissions. We survey the methods of integrating biomass technologies with carbon dioxide capture, and model an IGCC electric power system in detail. Our engineering process model, based on analysis and operational results of the Battelle/Future Energy Resources Corporation gasifier technology, integrates gasification, syngas conditioning, and carbon capture with a combined cycle gas turbine to generate electricity with negative net carbon emissions. Our baseline system has a net generation of 123 MW_e, 28% thermal efficiency, 44% carbon capture efficiency, and specific capital cost of 1,730 $ kW_e⁻¹. Economic analysis suggests this technology could be roughly cost competitive with more conventional methods of achieving deep reductions in CO₂ emissions from electric power. The potential to generate negative emissions could provide cost-effective emissions offsets for sources where direct mitigation is expected to be difficult, and will be increasingly important as mitigation targets become more stringent.     

Thermodynamic analysis of representative power generation cycles for low‐to‐medium temperature applications

This study is focused on the analysis of representative thermodynamic cycles for power generation at low‐to‐medium temperatures (with the highest cycle temperature from 450 to 700 K). The natural working fluid of carbon dioxide is selected for the current tests and comparisons with suitable operation ranges. Energy balance and exergy loss models are established and applied to 10 selected representative thermodynamic cycles. One modified efficiency parameter is also defined for better comparison of performances, which has considered the effects of both specific thermodynamic process and cycle complexity. Based on the modified efficiency parameter, it is found that Rankine cycle yields the highest performance at 450–500 K among the 10 representative cycles, while regenerative Brayton cycle shows better behavior for 550–700 K. Detailed behaviors and optimal principals of regenerative Brayton cycles are also identified and compared in this study. Also, a new cycle is also proposed in this study, which combines the advantages of Rankine cycle and Brayton cycle. The new cycle is proved to have better work output potential but higher system complexity factor. In addition, based on the thermodynamic analysis, possible future directions of low‐to‐medium temperature power cycles are summarized. It is hoped that the results can be of help for related power generation system designs. Copyright © 2014 John Wiley & Sons, Ltd.