Hydriding and Dehydriding Characteristics of Mechanically Alloyed LaMg_(17) Ni Composite Material

Magnesiumandmagnesiumalloyshavebeenin vestigatedashydrogenstoragematerialsforseveralde cadesbecausefarmorehydrogenbyweightcanbestoredinthemthaninmostoftheothercurrentlyknownhydrogenstoragealloys .Moreover ,thehighnaturalabundanceofMg ,itslightmassandenviron mentalcompatibilitypotentiallymakemagnesiumoneofthemostprospectivecandidatesforfuturehydrogenstoragematerials .Unfortunately ,thepracticalappli cationofMganditsalloyshasbeenlimitedonlytocertainstoragedevicebecauseoftheirpoorhydriding dehydr…     

Effect of C/Ti ratio on the laser ignited self-propagating high-temperature synthesis reaction of Al-Ti-C system for fabricating TiC/Al composites

TiC/Al composite was successfully synthesized utilizing laser ignited self-propagating high-temperature synthesis (SHS) of Al-C-Ti system with the different C/Ti molar ratio. When the molar ratio of C to Ti is below 1:1 in the starting materials, in addition to fine TiC particulates, a large amount of Al₃Ti phase was found in the composites; however, when the molar ratio of C to Ti is 1:1 in the starting materials, the Al₃Ti phase was almost completely eliminated and the distribution of TiC particulates generally appeared to be more homogeneous throughout the products synthesized.     

超支化聚合物的性能、合成及其功能化应用研究

超支化聚合物，具有多端基的“缺陷核壳”空间结构，化学反应性活泼，易于改性，与相应的线型聚合物相比，拥有特殊的性能，在多领域展现出广阔的应用前景。随着合成技术的进步，它们的应用研究，尤其是功能化的应用研究，成为多年来的研究热点。主要介绍超支化聚合物的结构、性能、合成及其功能化应用研究概况。     

Study on Adsorption Behavior of Rare Earth Complexes on Nanometer-Size Titanium Dioxide with ICP-AES

Inrecentyears ,rareearthelements (REEs)havebeenwidelyusedinfunctionalmaterials ,cata lystsandotherproductsinindustry ,diagnosisreagentsofmagneticresonanceimaging (MRI)inmedicineandsomefertilizersinagricultureespeciallyinChina .However,asaresultoftheirusage ,moreandmoreREEsaregettingintotheenvironment,andalsointohumanbodyviafoodchain[1,2 ] .Itisnotclearwhetherrareearthelementsareessentialforman ,soitisveryurgenttostudythebiologicaleffectofrareearthelementsinhumanhealthandenvironment .Inthes…     

Crystalline Behavior and Magnetic Properties of Nd60Fe30-x Al10Cox（x = 0,5,10） Bulk Amorphous Alloys

Crystalline behavior and magnetic properties of Nd60Fe30-xAl10Cox( x = 0, 5, 10) bulk amorphous alloys were investigated by differential scanning calorimeter (DSC), X-ray diffraction (XRD) and the vibrating sample magnetometer (VSM). Neither glass transition nor supercooled liquid region before crystallization was observed for the as-cast Nd60Fe30-xAl10Cox ( x = 0,5,10) bulk amorphous alloys. The glass forming ability can be improved significantly by the addition of Co. The as-cast Nd60Fe30-xAl10Cox (x = 0,5,10) alloys show hard magnetic behavior. With the addition of Co content, intrinsic coercivity (iHc) increases while the saturation magnetization(σs) and remanence (σr) decrease. The Curie temperature for the as-cast Nd60Fe30-xAl10Cox alloys increases from 451 K for x =0 to 468 K for x = 10. Some pre-cipitation of crystalline phases does not affect the hard magnetic properties of Nd60Fe30-xAl10Cox(x = 0,5,10) alloys, while the hard magnetic behavior disappears quickly after the alloys being completely crystallized.     

Influence of Ni Interlayers on the Mechanical Properties of Ti6Al4V/(WC-Co) Friction Welds

Ni interlayers were introduced prior to dissimilar friction welding of Ti6Al4V base material to three cemented carbide substrates. The fracture strength of Ti6Al4V/(WC-6 wt% Co) welds were poor and were markedly improved when 20-µm thick Ni interlayers were introduced prior to dissimilar friction welding. These results were only produced when the (WC-6 wt% Co) cermet was electroplated prior to friction welding. When the Ti6Al4V alloy was electroplated prior to friction welding, fractured WC particles and cracking were observed in the (WC-Co) carbide substrate. The fracture strengths of Ti6Al4V/(WC-11 wt% Co) and Ti6Al4V/(WC-24 wt% Co) welds were not improved when 20-µm thick Ni interlayers were introduced prior to friction welding. During mechanical testing, the Ni layer retained at the dissimilar joint interface created a region of weakness.     

Ti-45Al-10Nb合金的高温氧化行为

研究了Ti—45A1—10Nb(原子分数，％)合金在800-960℃在氧气和空气中的氧化行为．结果表明，该合金具有较好的高温抗氧化性能，其氧化增重速率与铁基耐热不锈钢相似或略优．与Ti—50A1合金相反，Ti-45A1-10Nb合金在空气中的氧化增重速率明显低于在纯氧中的氧化增重速率．X射线衍射与能谱分析表明，Ti-45Al一10Nb合金在氧气中的氧化产物主要有TiO2和Al2O3，但在空气中的氧化产物中有TiN相．这是降低氧化速率的主要原因，同时，合金元素Nb稳定了氧化层中的TiN相，因而提高了合金在空气中的抗氧化性能．