Design of Lu2O3-reinforced Cf/SiC-ZrB2-ZrC ultra-high temperature ceramic matrix composites: Wetting and interfacial reactivity by ZrSi2 based alloys

The wettability and infiltration of molten ZrSi₂ and ZrSi₂-Lu₂O₃ alloys into C_f/SiC and B₄C-infiltrated C_f/SiC composites were investigated to understand the interfacial interactions that occur during the development of C_f/SiC-ZrC and C_f/SiC-ZrB₂-ZrC-Lu₂O₃ materials. A significant evaporation of Si from the liquid affected the wetting behaviour of the alloy when tested in a vacuum at 1670 °C. The better wetting and spreading of the alloy over the surface was observed for the composites with lower overall porosity (12 %). On the other hand, the formation of an outer dense layer, followed up by the uniform infiltrated region up to ～ 1 mm was observed for the C_f/SiC with higher porosity (21 %). The infiltrated alloy reacted with SiC matrix to form ZrC or with B₄C-infiltrated SiC matrix to form ZrB₂-ZrC-SiC. The Lu₂O₃ particles were not wetted by the melt, and were pushed away of the reaction zone by the solidification front.     

Wet-chemical coating of silicon carbide fibers with hexagonal boron nitride layers

Hexagonal BN fiber coatings and BN powders were prepared by pyrolysis of the raw materials boric acid and urea in an atmosphere consisting of hydrogen and nitrogen. The powders were used to determine the appropriate mixing ratio of the raw materials to produce BN with the desired composition and crystal structure. The pyrolysis of boric acid and urea in a molar mixing ratio of 1:2 resulted in a BN that was hexagonal and had a near-stoichiometric composition.To prepare a solution for the coating of fibers, boric acid and urea were dissolved in an ethanol-water mixture. The coating was then applied to SiC filaments using a continuous roll-to-roll dip-coating process. It could be shown by SEM/EDS that BN layers were applied to the fibers. No significant bridging in the fiber bundle was found. Furthermore, it could be demonstrated by grazing incidence x-ray diffraction that the layers were crystalline.     

精密铸造磷酸盐粘结自硬型芯的试验研究

介绍了一种新型专利———浇注成形自硬制芯材料及相应的制芯工艺。这种芯料采用水溶性磷酸盐为粘结剂、氧化镁为固化剂、高纯二氧化硅为耐火骨料。简要介绍了芯料的组成和固化机理。在不同条件下检测了该种型芯的一些重要工艺参数,如常温、高温强度和发气性,分析归纳了这些参数的影响因素,同时对某些应用性能,如浆料的工作时间和型芯的精度、表面粗糙度、抗热震性、溃散性、可化学清理性和对铸造合金液体的热化学稳定性等进行了评价和描述。     

熔模铸造型壳废弃物组成及其再利用分析

分别分析了最常用的水玻璃型壳和硅溶胶型壳在脱蜡后的型壳，焙烧后的型壳和浇注后清理的型壳废弃物的物相组成，即水玻璃型壳的主要物相是石英或Al-Si系材料物相；硅溶胶型壳的主要物相是Al-Si系材料物相。并依此提出了型壳废弃物资源化利用的一些途径：①作建筑材料，如水泥、沙料、砖、填料；②作熔模铸造的原材料，如耐火粉料和砂料、粘接剂、硬化剂。     

激光重熔工艺对热喷涂陶瓷层微观结构的影响

研究了在１Ｃｒ１８ＮｉｏＴｉ基体上热喷涂Ａｌ２Ｏ３－１３％ＴｉＯ２陶瓷层，进行激光重熔对陶瓷微观结构的影响。激光重熔陶瓷层中，主要组成相为ａ－ＡＩ２Ｏ３及ＡＩ２ＴｉＯ５，在条件合适时，在ａ－ＡＩ２Ｏ３中还有一种超结构，即有序相析出；有序相的存在可阻碍表面裂纹的产生；激光重熔陶瓷层中，扫描速度增加，表面裂纹的宽度增加；激光输出功率增加，表面裂纹的宽度亦增加。     

新型连铸结晶器铜管的开发

将自蔓延高温合成技术与离心铸造技术结合，开发了陶瓷内衬复合铜管技术，可在铜管内表面涂敷耐磨性和耐蚀性优良的陶瓷涂层。为提高陶瓷涂层致密度、韧性和结合强度，研究了添加剂的影响，结果表明，在铝热剂中加入SiO2、CrO3可提高致密度，加入N2B4O7可提高结合强度，加入ZrO2可提高断裂韧性。陶瓷内衬复合铜管应用于管坯结晶器，可提高使用寿命，降低成本。     

球墨铸铁Dg75阀体消失模近净型铸造

介绍消失模工艺生产Dg75闸阀阀体铸件的铸造工艺，生产过程中铸件重要装配尺寸精度的保证，铸件表面粗糙度、铸件表面碳夹杂缺陷及表面皱皮现象控制等试验情况。通过模具结构设计、成型工艺及参数的调整、浇注工艺的调整、陶瓷成型浇道的应用等措施，使铸件表面质量及尺寸精度符合客户验收标准。同时使铸件表面因轻微缺陷的返修率由试验初期的90％下降到10％以内，产品合格率达到99％。     

借助差热分析研究镍基高温合金/陶瓷型壳界面反应

借助差热分析研究镍基高温合金/陶瓷型壳的界面反应,分别从热力学和动力学的角度分析出镍基高温合金叶片在生产过程中陶瓷型壳所需的最佳面层涂料是CoAl2O4.     

新型导电纤维电缆制作工艺

介绍以合成纤维长丝为原料,对其表面进行一系列的物理化学处理后,均匀地镀上一层附着力很强的金属层,使其非导体变成电的良导体,以此线芯制成新型导电纤维电缆。对该电缆线芯之导电性、镀层厚度、强度、抗弯性及可焊性进行了检测,同时利用电镜对其表面形貌进行了观察。结果表明,新型导电材料性能优良,各项指标满足使用要求,可以代替铜导线在微电流范围内使用。     

短纤维增强复合材料的仿生模型──Ⅰ 哑铃状短纤维增强复合材料的应力分析

受生物体构件的启发，提出了哑铃状短纤维增强复合材料的模型．分析了带球短纤维和基体中的应力分布，发现端头半径粗化将改善纤维中轴向应力分布，使之趋于均匀化，同时可减少纤维端部界面的剪应力．研究表明纤维长径比对纤维端头应力影响较小．讨论了纤维－基体模量比对纤维轴向最大拉伸应力和界面最大剪应力的影响．