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51.
We review our X-ray absorption spectroscopy studies of adsorbate geometries on the O-terminated (000
) and Zn-terminated (0001) basel faces, as well as the non-polar (10
0) prism face of ZnO. Studies employing near-edge X-ray absorption fine-structure (NEXAFS) and surface X-ray absorption fine-structure (SEXAFS) are included. 相似文献
52.
Plant fibers are rich in cellulose and they are a cheap, easily renewable source of fibers with the potential for polymer reinforcement. The presence of surface impurities and the large amount of hydroxyl groups make plant fibers less attractive for reinforcement of polymeric materials. Hemp, sisal, jute, and kapok fibers were subjected to alkalization by using sodium hydroxide. The thermal characteristics, crystallinity index, reactivity, and surface morphology of untreated and chemically modified fibers have been studied using differential scanning calorimetry (DSC), X‐ray diffraction (WAXRD), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM), respectively. Following alkalization the DSC showed a rapid degradation of the cellulose between 0.8 and 8% NaOH, beyond which degradation was found to be marginal. There was a marginal drop in the crystallinity index of hemp fiber while sisal, jute, and kapok fibers showed a slight increase in crystallinity at caustic soda concentration of 0.8–30%. FTIR showed that kapok fiber was found to be the most reactive followed by jute, sisal, and then hemp fiber. SEM showed a relatively smooth surface for all the untreated fibers; however, after alkalization, all the fibers showed uneven surfaces. These results show that alkalization modifies plant fibers promoting the development of fiber–resin adhesion, which then will result in increased interfacial energy and, hence, improvement in the mechanical and thermal stability of the composites. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 2222–2234, 2002 相似文献
53.
The phenomenon of slow stable crack growth in polyethylene is investigated using notched specimens subject to constant load and the concepts of fracture mechanics. The effect of specimen geometry and dimension, the loading and the mode of loading on the applied stress intensity factor versus crack speed () curves has been studied to demonstrate that Kc is the controlling stress parameter for crack growth under suitable conditions. curves are obtained for a high density polyethylene homopolymer in distilled water and in a diluted detergent solution at four different temperatures. Results are also obtained for a much tougher medium density polyethylene copolymer whenever possible. Several mechanisms can be identified from the form of the curves. Two, in particular, have been observed but not explained before: (i) crack growth with a time dependence of 0.25, and (ii) the high slopes for crack growth in a tough copolymer. With the help of scanning electron microscopic studies of the fracture surfaces, (i) is postulated to be due to diffusion controlled void growth process and (ii) is considered to be the result of crack tip blunting effects. From the temperature dependence of crack growth, the activation energy of the diffusion controlled crack growth process is found to coincide with that of the x-relaxation process in polyethylene implying that diffusion controlled crack growth may be related to the motion of main chains in the polymer. 相似文献
54.
Mostafa Rezaei Azadeh Shirzad Nadereh Golshan Ebrahimi Marianna Kontopoulou 《应用聚合物科学杂志》2006,99(5):2352-2358
We performed surface modification of ultra‐high‐molecular‐weight polyethylene (UHMWPE) through chromic acid etching, with the aim of improving the performance of its composites with poly(ethylene terephthalate) (PET) fibers. In this article, we report on the morphology and physicomechanical and tribological properties of modified UHMWPE/PET composites. Composites containing chemically modified UHMWPE had higher impact properties than those based on unmodified UHMWPE because of improved interfacial bonding between the polymer matrix and the fibers and better dispersion of the fibers within the modified UHMWPE matrix. Chemical modification of UHMWPE before the introduction of PET fibers resulted in composites exhibiting improved wear resistance compared to the base material and compared to unmodified UHMWPE/PET composites. On the basis of the morphological studies of worn samples, microploughing and fatigue failure associated with microcracking were identified as the principle wear mechanisms. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci, 2006 相似文献
55.
H1 technology needlepunching machinery is one of the recent developments in the needleloom technology. H1 technology needlepunching nonwoven machinery has been effectively utilized to develop a set of nonwoven substrates at different punching rates. The effect of needlepunching speeds on the frictional properties of H1 technology polyester nonwoven webs is reported in this article. The frictional properties of nonwoven webs have been characterized using a simple normalized friction factor. In addition, the surfaces of the nonwoven substrates were scanned using scanning electron microscopy. The results show that for the three different penetration rates studied there seems to be a marginal difference in the frictional properties. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 3626–3631, 2003 相似文献
56.
In this paper, we propose a new continuous self‐collision detection (CSCD) method for a deformable surface that interacts with a simple solid model. The method is developed based on the radial‐view‐based culling method. Our method is suitable for the deformable surface that has large contact region with the solid model. The deformable surface may consist of small round‐shaped holes. At the pre‐processing stage, the holes of the deformable surface are filled with ghost triangles so as to make the mesh of the deformable surface watertight. An observer primitive (i.e. a point or a line segment) is computed so that it lies inside the solid model. At the runtime stage, the orientations of triangles with respect to the observer primitive are evaluated. The collision status of the deformable surface is then determined. We evaluated our method for several animations including virtual garments. Experimental results show that our method improves the process of CSCD. 相似文献
57.
Julius Parulek Daniel Jönsson Timo Ropinski Stefan Bruckner Anders Ynnerman Ivan Viola 《Computer Graphics Forum》2014,33(6):276-287
Molecular visualization is often challenged with rendering of large molecular structures in real time. We introduce a novel approach that enables us to show even large protein complexes. Our method is based on the level‐of‐detail concept, where we exploit three different abstractions combined in one visualization. Firstly, molecular surface abstraction exploits three different surfaces, solvent‐excluded surface (SES), Gaussian kernels and van der Waals spheres, combined as one surface by linear interpolation. Secondly, we introduce three shading abstraction levels and a method for creating seamless transitions between these representations. The SES representation with full shading and added contours stands in focus while on the other side a sphere representation of a cluster of atoms with constant shading and without contours provide the context. Thirdly, we propose a hierarchical abstraction based on a set of clusters formed on molecular atoms. All three abstraction models are driven by one importance function classifying the scene into the near‐, mid‐ and far‐field. Moreover, we introduce a methodology to render the entire molecule directly using the A‐buffer technique, which further improves the performance. The rendering performance is evaluated on series of molecules of varying atom counts. 相似文献
58.
《Computer Aided Geometric Design》2014,31(7-8):475-485
In this paper, we introduce triangular subdivision operators which are composed of a refinement operator and several averaging operators, where the refinement operator splits each triangle uniformly into four congruent triangles and in each averaging operation, every vertex will be replaced by a convex combination of itself and its neighboring vertices. These operators form an infinite class of triangular subdivision schemes including Loop's algorithm with a restricted parameter range and the midpoint schemes for triangular meshes. We analyze the smoothness of the resulting subdivision surfaces at their regular and extraordinary points by generalizing an established technique for analyzing midpoint subdivision on quadrilateral meshes. General triangular midpoint subdivision surfaces are smooth at all regular points and they are also smooth at extraordinary points under certain conditions. We show some general triangular subdivision surfaces and compare them with Loop subdivision surfaces. 相似文献
59.
The objectives of this research article is to evaluate the mechanical and tribological properties of glass‐fiber‐reinforced epoxy (G–E) composites with and without graphite particulate filler. The laminates were fabricated by a dry hand layup technique. The mechanical properties, including tensile strength, tensile modulus, elongation at break, and surface hardness, were investigated in accordance with ASTM standards. From the experimental investigation, we found that the tensile strength and dimensional stability of the G–E composite increased with increasing graphite content. The effect of filler content (0–7.5 wt %) and sliding distance on the friction and wear behavior of the graphite‐filled G–E composite systems were studied. Also, conventional weighing, determination of the coefficient of friction, and examination of the worn surface morphological features by scanning electron microscopy (SEM) were done. A marginal increase in the coefficient of friction with sliding distance for the unfilled composites was noticed, but a slight reduction was noticed for the graphite‐filled composites. The 7.5% graphite‐filled G–E composite showed a lower friction coefficient for the sliding distances used. The wear loss of the composites decreased with increasing weight fraction of graphite filler and increased with increasing sliding distance. Failure mechanisms of the worn surfaces of the filled composites were established with SEM. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 2472–2480, 2007 相似文献
60.
室温固化高温使用环氧胶粘剂的进展 总被引:3,自引:1,他引:3
本文介绍了室温固化高温使用环氧胶粘剂的主要成份、结构、性能及其特点,并对其存在的问题及未来的发展趋势化了简述. 相似文献