电场力显微镜不同探针对表面电荷注入的影响

在电场力显微镜(EFM)下利用不同金属镀层微探针,在微纳米尺度下对聚酰亚胺薄膜的表面电荷生成特性进行研究。采用电场力显微镜导电探针在聚酰亚胺薄膜表面注入电荷,并对微纳米区域产生的电荷进行表征,结果表明不同金属镀层的微探针对聚酰亚胺薄膜上电荷注入效果不同。铂铱合金镀层具有比钴铬合金镀层更高的功函数fm,因此前者在金属-电介质接触中产生更大肖特基势垒,进而降低了电荷的注入程度。该研究为微纳米尺度下探索聚合物绝缘材料表面电荷生成、发展机理提供了一个新的研究方法和途径。     

一种低压太阳能LED草坪灯驱动控制集成电路设计

为了减少太阳能LED草坪灯控制系统的成本,降低对太阳能电池的要求,设计了一种能工作在0.8V的低压太阳能LED草坪灯驱动控制器.该电路的输出电流可以在5mA～100mA范围内调节,能够满足各种不同LED对电流的需求.控制充电回路通断的开关管集成在芯片内部,减少了外围器件,使得整个草坪灯系统只需外接一个电感、二极管、电容...     

Open‐Shell Donor–Acceptor Conjugated Polymers with High Electrical Conductivity

Conductive polymers largely derive their electronic functionality from chemical doping, processes by which redox and charge‐transfer reactions form mobile carriers. While decades of research have demonstrated fundamentally new technologies that merge the unique functionality of these materials with the chemical versatility of macromolecules, doping and the resultant material properties are not ideal for many applications. Here, it is demonstrated that open‐shell conjugated polymers comprised of alternating cyclopentadithiophene and thiadiazoloquinoxaline units can achieve high electrical conductivities in their native “undoped” form. Spectroscopic, electrochemical, electron paramagnetic resonance, and magnetic susceptibility measurements demonstrate that this donor–acceptor architecture promotes very narrow bandgaps, strong electronic correlations, high‐spin ground states, and long‐range π‐delocalization. A comparative study of structural variants and processing methodologies demonstrates that the conductivity can be tuned up to 8.18 S cm^?1. This exceeds other neutral narrow bandgap conjugated polymers, many doped polymers, radical conductors, and is comparable to commercial grades of poly(styrene‐sulfonate)‐doped poly(3,4‐ethylenedioxythiophene). X‐ray and morphological studies trace the high conductivity to rigid backbone conformations emanating from strong π‐interactions and long‐range ordered structures formed through self‐organization that lead to a network of delocalized open‐shell sites in electronic communication. The results offer a new platform for the transport of charge in molecular systems.     

电压倍增之像素设计

为了节省面板电路驱动芯片的功率损耗以及制作成本,本研究提出一种新的像素电路设计,而在设计中将会融合电荷泵电路。利用这种电路设计的像素可有效地将像素电极上的驱动电压提高到输入电压的2～3倍以上。此像素电路设计具有两个优势:第一,可以有效降低显示面板的像素功率损耗;第二,不需高电压的面板电路驱动芯片,因此可节省芯片的成本及功率损耗。由模拟结果可知,像素电极上的驱动电压确实可由此像素电路设计而提高到输入电压的2～3倍以上;而像素的功率损耗也可有效地降低,约为传统像素的1/2。     

网络理论在光伏充电站智能通信网络优化中的应用

介绍未来智能电网中光伏储能电动汽车充电站主体架构,及其通信监控架构。将网络中连通度、网络流等理论应用于光伏储能、电动汽车充电站监控系统设计中,最后通过对监控网络的连通度、稳定性、经济性的比较得出最优的监控系统设计框架。     

新型压电式传感器前置放大电路的设计

在油气井出砂检测中,压电式传感器检测到的出砂信号弱、频率高,常用的电荷放大器不能满足要求。基于此问题,文中开展了针对出砂信号的前置放大电路的研究,该电路由电荷放大器、带通滤波器、过载指示等电路组成,其中电荷放大器电路选用高阻型的运放AD823实现,带通滤波器的带宽设计为100kHz～1MHz,并且利用EWB电路仿真软件对电荷放大器和滤波电路进行了仿真,仿真结果与设计指标一致,验证了参数选取的合理性。最后,给出了该电路在出砂检测系统中的试验情况,结果表明参数选择合理、性能稳定。     

智能化医院门诊收费稽查系统的设计与实现

HIS是目前各大医院广泛使用的医院信息系统,利用HIS中门诊收费子系统的数据设计实现智能化医院门诊收费稽查系统。依托HIS中门诊收费的数据,在Delphi 7开发平台下,利用条形码技术自动将交费票据中的数据与HIS中的相关数据进行核对,完成系统的稽查功能。系统在西京医院的运行中表现良好,达到了设计要求,满足用户需要。条形码技术在稽查系统中的应用实现了收费稽查工作的自动化和智能化,极大地提高了稽查工作的效率和正确性。     

一种新型低电荷共享电荷泵电路

采用GSMC0.18μm工艺设计了性能优良的电荷泵,与传统电荷泵相比,此电荷泵具有低失配(mismatch≤2%)、低功耗(≤0.15mw)、低电荷共享的特点,可广泛应用于电荷泵锁相环(CPPLL)中。     

Acceptor-rich bulk heterojunction polymer solar cells with balanced charge mobilities

In this work, we reported efficient polymer solar cells with balanced hole/electron mobilities tuned by the acceptor content in bulk heterojunction blend films. The photovoltaic cells were fabricated with two new wide band-gap D-A polymers PBDDIDT and PBDDIDTT as the donor material. The molecular conformations of new polymers are carefully evaluated by theoretical calculations. The results of photovoltaic studies show that two devices reach their optimal conditions with rich PC₇₁BM content up to 80% in blend films, which is uncommon with most of reported PSCs. The as-cast devices based on PBDDIDT and PBDDIDTT reveal good photovoltaic performance with PCE of 7.04% and 6.40%, respectively. The influence of PC₇₁BM content on photovoltaic properties is further detailed studied by photoluminescence emission spectra, charge mobilities and heterojunction morphology. The results exhibit that more efficient charge transport between donor and acceptor occurs in rich PC₇₁BM blend films. Meanwhile, the hole and electron mobilities are simultaneously enhanced and afford a good balance in rich PC₇₁BM blend films (D/A, 1:4) which is critical for the improvement of current density and fill factors.     

Fused-ring acceptors based on quinoxaline unit for highly efficient single-junction organic solar cells with low charge recombination

Two non-fullerene small molecule acceptors (TFQ-F and TFQ-Cl) based on quinoxaline unit were designed and synthesized for efficient organic solar cells (OSCs). These two acceptors showed intense absorption up to 900 nm and high thermal stabilities with decomposition temperatures over 360 °C due to their fused-ring skeletons. TFQ-F and TFQ-Cl are the A-D-A′-D-A type acceptors (A/A′ for acceptor unit and D for donor unit). TFQ-F and TFQ-Cl have the same D-A′-D fragment, which was flanked with different ending groups. The effect of different ending groups on their photophysical properties, electrochemical behaviors, micro-structures and charge recombination properties of active layers, and device performance were investigated systematically. PM6 with the complementary absorption to the two acceptors was used as the donor material. The pristine PM6:TFQ-F blend films displayed the optimal morphologies as revealed by AFM and TEM measurement. Organic solar cells based on PM6:TFQ-Cl blend film showed high J_SC of 25.19 mA/cm² and PCE of 13.2%. The Voc, J_SC and PCE for PM6:TFQ-F film based device were 0.857 V, 23.70 mA/cm² and 13.51%, respectively. The dependence of V_OC/J_SC on various light intensities indicated that PM6:TFQ-F/Cl based device had low charge recombination.