卤素离子对铝合金阳极的活化作用

镓锡合金沉积子铝阳极表面，形成活化点，是含镓、锡铝合金阳极活化的根本原因。溶液中的卤素离子在氧化膜上的吸附及在其中的扩散也促进了铝电极的阳极溶解。合金元素及溶液中的阴离子通过改变铝电极表面的零电荷，影响着合金元素在铝电极表面的沉积的难易程度，从而影响着铝合金阳极的活化性能。     

芘四硫酸四钠盐／甲基紫精复合物光物理性质的研究

本文通过吸收光谱滴定和时间分辨瞬态吸收光谱对芘四硫酸四钠盐（ｐｙｒｅｎｅｔｅｔｒａｓｕｌｆｏｎｉｃａｃｉｄｔｅｔｒａｓｏｄｉｕｍｓａｌｔ，ＰｙＴＳ）／甲基紫精（ｍｅｔｈｙｌｖｉｏｌｏｇｅｎ，ＭＶ２＋）复合物在水溶液中的光物理性质进行研究．用甲基紫精滴定芘四硫酸四钠盐时，得到该复合物的组成成份是１∶１，反之，用芘四硫酸四钠盐滴定甲基紫精时，同样得到１∶１组成成份的复合物．该复合物的形成常数是２．４×１０６ｍｏｌ－１·Ｌ，当用光激发该复合物时，发现其中存在芘四硫酸四钠盐到甲基紫精的电子转移过程，并得到该过程的动力学模型．     

某弹射弹推进剂装药设计

通过对某弹射弹功能和使用要求分析，确定了该弹射弹的极限特征参数及弹道性能，提出了装药用推进剂的选取原则，经过弹道计算和分析，初步确定了所用推进剂及装药的药型，并进行了试验验证，为该弹射弹的研制打下了良好的基础。     

B位掺杂钙钛矿结构化合物LaSr2Mn2-xFexO7的电磁性能

研究了以Fe离子(Fe3 )掺杂取代部分锰(Mn)离子的层状钙钛矿结构化合物LaSr2Mn2-xFexO7(O≤x≤O.3)的电性和磁性.结果发现:Fe3 的掺杂抑制了LaSr2Mn2-xFexO7低温的反铁磁性交换作用,使Neel温度TN由x=0的138K降至x=0.3的l0lK.同时,LaSr2Mn2-xFex07的自旋玻璃态、电荷有序和金属一绝缘体转变温度都由于Fe3 取代Mn离子而受到抑制.产生上述现象的原因是因为Mn位被取代导致产生无序状态.由于Fe3 取代Mn粒子,致使双交换作用通道被打破,化合物的电阻率随x的增加而迅速增加.所有化合物的电阻率在低温阶段都可以用Mott的变程跳跃理论来拟合;在高温阶段可以用最近小声子极化理论来拟合.     

激发态光物理的拓扑控制：对（N，N＇－二正癸基）氨基苯甲腈的簇集与光诱导分子内电荷转移

在水－二氧六环混合介质中，对二正癸基氨基苯甲腈（ＤＤＡＢＮ）分子，在水的体积分数超过０．５后，发生簇集并可观察到双重荧光发射且长波长发射带位置与在纯二氧六环中相近。该发射带被证实系分子内扭转电荷转移（ＴＩＣＴ）带。吸收光谱表明ＤＤＡＢＮ簇集体为Ｊ－型。     

用于频率综合的电荷泵锁相环电路设计

在阐述了锁相环频率综合的工作原理、分析和设计方法的基础上,结合环路稳定性和相位噪声两方面因素对锁相环电路进行了建模及分析。采用安捷伦公司的ADS软件对锁相环进行了系统设计及仿真,并采用Cadence公司的Spectre-RF系列软件进行了锁相环具体电路设计和仿真。采用该方案设计的锁相环输出频率范围18.15 23 GHz,相位噪声-90 dBc/Hz,锁定时间小于5μs。     

Li_(1.52)Ni_(0.30)Mn_(0.78)Co_(0.06)O_(2.00)正极材料的电化学性能

以Li2CO3、Ni(CH3COO)2·2H2O、Mn(CH3COO)2·4H2O、Co(CH3COO)2·4H2O和Na2CO3为原料,通过直接沉淀法制备了具有α-NaFeO2型层状结构的微米Li1.52Ni0.30Mn0.78Co0.06O2.00正极材料.通过X射线衍射、扫描电镜、恒电流充放电、交流阻抗、循环伏安法等方法研究了样品的结构和电化学性能.结果表明:充电截止电压4.6V时样品的充放电性能最佳.在电流200 mAh·g-1时,该样品第1循环和第40循环的放电容量分别为150.2 mAh·g-1、155.0 mAh·g-1;样品的电化学反应受电荷传递阻抗和和Li+扩散的共同控制.     

Non-coalescence and chain formation of droplets under an alternating current electric field

The dynamic behaviors of two droplets and droplet cluster under an alternating current (AC) electric field are investigated. Two droplets generally undergo transformation from complete coalescence to partial coalescence and finally to non-coalescence as the electric capillary number Ca_p increases. The critical electric capillary number Ca_pc for complete coalescence in the AC electric field remains unchanged and is twice as large as that in the direct current (DC) electric field when the frequency f ≥ 250 Hz. Charge transfer and reversal of electric field result in the reversal of the direction of electric force, which is the fundamental mechanism of non-coalescence of two droplets and chain formation in droplet cluster. The number of rebounds dramatically increases as f increases, promoting the stability of droplet chain. The droplet chains in the high-frequency AC electric field are longer and more stable than those in the low-frequency AC electric field.     

Growth of Au nanocrystals on CdS nanorods

Nanorods of S²⁻ rich CdS were synthesized by a reaction of excess S versus Cd precursors in the presence of ethylene diamine. The photoluminescence (PL) emission from the S²⁻ rich CdS nanorods was broad with a peak at ∼710 nm, which was 40 nm longer in wavelength than the PL peak from Cd²⁺ rich CdS (∼670 nm) nanorods. The influence of surface electron or hole trap states on the luminescent pathway of CdS nanorods will be discussed to explain these shifts in wavelength. Nanocrystals of Au ∼2 nm in size were grown on S²⁻ rich surfaces of CdS nanorods. Significant luminescence quenching was observed from the Au nanocrystals on the CdS nanorods due to interfacial charge separation. Change separation by the Au nanocrystals on the CdS resulted in enhanced photocatalytic degradation of Procion red mix-5B (PRB) dye in an aqueous solution under UV light irradiation.     

Electrical properties of La0.6Sr0.4Co1-yFeyO3 cathode material

The electrical properties of La0.6Sr0.4Co1-yFeyO3 （LSCF, y=0-1.0） cathode materials were measured by DC four probes, X-ray photo-electron spectrum （XPS） was also introduced to determine the chemical state of Co, F.e ions in LSCF. It is found that the electrical conductivity of each sample has a maximum value with increasing temperature. XPS analysis shows that Co ion has three different chemical states, corresponding to two with Fe ion. The analyses indicates that the small-polaron hopping mechanism dominates the electron conduction at low temperature, while at high temperature, the three factors such as the thermally activated disproportionation of Co^3＋ ions into Co^2＋ and Co^4＋ pairs, the ionic compensation of oxygen vacancies formed at high temperatures, and Fe^4＋ ions charge compensation preferential to Co^4＋, all contribute to electrical conduction.