The Synthesis of Covalent Triazine-Based Frameworks via Friedel–Crafts Reactions of Cyanuric Chloride with Thienyl and Carbazolyl Derivatives for Fluorescence Sensing to Picric Acid,Iodine and Capturing Iodine

A multifunctional thiophene-based covalent triazine framework (TTPATTh) with triphenylamine as core is synthesized by Friedel–Crafts reaction of cyanuric chloride with thienyl derivative for the first time. The yield of TTPATTh (99.59%) is far higher than that of the carbazole-based CTF (TTPATCz, 47.03%). TTPATTh and TTPATCz possess high BET surface areas with 1235 and 2501 m² g^–1 as well as high pore volumes with 1.60 and 2.23 cm³ g^–1, respectively. TTPATTh and TTPATCz have high thermal stability with high thermal decomposition temperatures of 514 and 598 °C in nitrogen atmosphere. With the introduction of triazine rings, the fluorescence sensing sensitivities of TTPATTh and TTPATCz to picric acid and iodine are improved significantly. Especially for TTPATTh, the K_sv values reach 5.95 × 10⁵ and 1.61 × 10⁴ L mol^–1, and LODs reach 1.02 × 10^–12 and 1.86 × 10^–12 mol L^–1. To the best of the knowledge, this is the most sensitive value among thiophene-based porous organic polymers to PA and I₂. Furthermore, TTPATTh and TTPATCz can also adsorb iodine in vapor phase, cyclohexane solution and aqueous solution, and release iodine by heating or in ethanol solution. The efficiency of controlling the release of iodine is higher than that in ethanol.     

Degradable Superhydrophilic Iron-Pillared Bentonite Doped with Polybutylene Adipate/Terephthalate Open-Cell Foam: Its Application in Dye Degradation,Removal of Heavy Metal Ions,and Oil–Water Separation

Development of industrialization has brought convenience to people's lives; however, it has also brought serious harm to the environment, where, water pollution is the most obvious. Here, a polybutylene adipate terephthalate (PBAT) open-cell foam doped with iron-pillared bentonite (IPB) is prepared by using sugar as a pore-forming agent and solution phase separation, and then combined with a solution dipping method to coat the foam surface with a polyacrylamide/SiO₂, which makes the PBAT foam superhydrophilic. The static adsorption effect of superhydrophilic IPB-doped PBAT open-cell foam on methylene blue (MB) and Cu²⁺ is studied. The adsorption isotherm fitting shows that the adsorption conforms to the Langmuir model and it has biased toward monolayer adsorption. The adsorption kinetics fitting confirms that the adsorption process is in line with the pseudo-second-order adsorption model, which is dominated by chemical adsorption. The modified PBAT open-cell foam has an adsorption effect on Cu²⁺; however, it has weak cyclic adsorption capacity. It shows a good cyclic adsorption ability for the cationic dye MB and it has >95% photodegradation efficiency of the MB after five time's cyclic adsorption. The superhydrophilicity makes the foam to have better applications in oil–water separation.     

Highly Thermal Stable Polyimides Applied in Flexible Resistive Memory

Flexible memory devices are one of the most crucial elements in the wearable electronics. In this work, polyimides (PIs)-based flexible resistive memory devices with an excellent thermal and mechanical durability are demonstrated. Four kinds of functional PIs are derived from the heterocyclic diamines including 2,6-diaminodibenzo-p-dioxin (OODA) and 2,6-diaminothianthrene, and dianhydrides including 4,4′-(hexafluoroisopropylidene)diphthalic anhydride (6FDA) and 3,3′,4,4′-biphenyltetracarboxylic dianhydride. PI with diamine of OODA and dianhydride of 6FDA (PI(OODA_6FDA)) possesses outstanding thermal and mechanical properties with a high glass transition temperature of 352 °C, a low coefficient of thermal expansion of 28.1 ppm K⁻¹, and a high elongation at break of 10%. In addition, PI(OODA_6FDA)-based memory shows write-once-read-many behavior with a high on/off current ratio of 10⁶ and a stable data retention, attributed to the donor–acceptor charge transfer between the polymer chains. The retained current levels at a low resistive state can be observed even with thermal treatment at 200 °C for 24 h or 1000 times cyclic bending at a bending radius of 5 mm. These results demonstrate the potential of heterocyclic PIs for flexible resistive memory.     

Catalytic feasibility of Ce-doped LaCoO3 systems for chlorobenzene oxidation: An analysis of synthesis method

A family of Ce-doped LaCoO₃ perovskites are presented as possible catalysts for Cl–VOCs elimination. These materials with different contents of Ce were obtained through the citrate and the reactive grinding methods. The insertion of Ce in the original perovskite structure favours the presence of Co²⁺/Co³⁺ and Ce³⁺/Ce⁴⁺ redox pairs and a higher content of oxygen vacancies that enhances the catalytic performance in chlorobenzene combustion based on differential kinetics studies. The family obtained by the grinding method presents a performance as high as that synthesized by citrate method. Thus, the reactive grinding is a feasible green chemistry alternative to obtain a catalyst with the same performance as that obtained from traditional methods. Finally, the stability of samples was evaluated under total combustion reaction conditions showing an excellent activity during 45 h time on stream.     

除草剂炔草酯的合成研究

以5氯2,3二氟吡啶与(R)2(对羟基苯氧基)丙酸为原料,以二甲基甲酰胺(DMF)为溶剂,K2CO3为缚酸剂,在70℃下醚化反应4h,然后再加入氯丙炔,以甲苯为溶剂,反应温度70～75℃,降温后过滤除盐,DMF洗涤,脱溶,再用乙醇/水结晶,干燥得产品,含量98%,以(R)2(对羟基苯氧基)丙酸计总收率86%。     

Asynchronous decentralized event-triggered control

In this paper we propose an approach to the implementation of controllers with decentralized strategies triggering controller updates. We consider set-ups with a central node in charge of the computation of the control commands, and a set of not co-located sensors providing measurements to the controller node. The solution we propose does not require measurements from the sensors to be synchronized in time. The sensors in our proposal provide measurements in an aperiodic way triggered by local conditions. Furthermore, in the proposed implementation (most of) the communication between nodes requires only the exchange of one bit of information (per controller update), which could aid in reducing transmission delays and as a secondary effect result in fewer transmissions being triggered.     

Utility of stereoscopic displays for indirect-vision driving and robot teleoperation

The effectiveness of an active shutter-glasses stereoscopic display (SD) and a passive polarised SD was evaluated in a live robot-teleoperation task and a simulated indirect-vision driving task in various terrains. Overall, participants completed their tasks significantly faster with the SDs in three-dimensional (3D) mode than with the SDs in the baseline 2D mode. They also navigated more accurately with the SDs in 3D mode. When the effectiveness of the two types of SDs was examined separately, results showed that the active shutter-glasses SD resulted in faster responses and task completion times than the passive polarised SD, though most of the differences failed to reach statistical significance. Perceived workload when interacting with the two SD systems did not differ significantly between the active versus passive display types or between the 3D and 2D modes of operation; however, participants reported more severe discomfort after interacting with the passive polarised SD.     

A 3D analysis of the joint torques developed during driver's ingress–egress motion

Providing an easy ingress–egress (I/E) movement remains a challenge for car designers. I/E has been largely studied in kinematics, but not in dynamics. This study proposes: (1) to evaluate and describe the motor torques developed in the lower limbs and lumbar joints during I/E motions and (2) to analyse the influence of the car geometry and subject anthropometry. An experiment was performed to observe 15 subjects of three anthropometrical groups getting in and out of a car mock-up simulating three different vehicle configurations. Motor torques were extracted using an inverse dynamics analysis. Both ingress and egress motions were primarily characterised by large torques. Overall, the taller a subject and the lower the seat of the vehicle were, the larger the peak torques were. Moreover, peak torques were higher for egress than ingress. These results are discussed in regard to the current knowledge on I/E ergonomics.     

A hybrid intelligent system for medical data classification

In this paper, a hybrid intelligent system that consists of the Fuzzy Min–Max neural network, the Classification and Regression Tree, and the Random Forest model is proposed, and its efficacy as a decision support tool for medical data classification is examined. The hybrid intelligent system aims to exploit the advantages of the constituent models and, at the same time, alleviate their limitations. It is able to learn incrementally from data samples (owing to Fuzzy Min–Max neural network), explain its predicted outputs (owing to the Classification and Regression Tree), and achieve high classification performances (owing to Random Forest). To evaluate the effectiveness of the hybrid intelligent system, three benchmark medical data sets, viz., Breast Cancer Wisconsin, Pima Indians Diabetes, and Liver Disorders from the UCI Repository of Machine Learning, are used for evaluation. A number of useful performance metrics in medical applications which include accuracy, sensitivity, specificity, as well as the area under the Receiver Operating Characteristic curve are computed. The results are analyzed and compared with those from other methods published in the literature. The experimental outcomes positively demonstrate that the hybrid intelligent system is effective in undertaking medical data classification tasks. More importantly, the hybrid intelligent system not only is able to produce good results but also to elucidate its knowledge base with a decision tree. As a result, domain users (i.e., medical practitioners) are able to comprehend the prediction given by the hybrid intelligent system; hence accepting its role as a useful medical decision support tool.     

Validation of a task demand measure for predicting mental workloads of physical therapists

The purpose of this study is to validate an analytical method in assessing demanded mental workloads for physical therapists, and to discuss its possible ergonomics implications on the design of healthcare working systems in which physical therapists are considered as the users. A task analysis was first used to understand the operation steps of three identified physical therapies. Then, the McCracken–Aldrich technique was applied to assign ratings of mental workload demanded for performing each step of the therapies. Finally, the assigned ratings were validated by the analysis of correlation with the answers of the NASA-TLX questionnaire collected from seventeen physical therapists in the rehabilitation center of a university-affiliated hospital. Results showed that the proposed McCracken–Aldrich technique was suitable as an analysis tool for predicting metal workloads of physical therapists. Some possible implications about the information provision and user interface design for reducing therapists' mental workloads on current therapy operations were discussed.Relevance to industryResults of this paper are expected to contribute the research and development in healthcare industry on its system design and workflow analysis.