二甲基硅烷芴基环氧树脂的合成、表征及非等温固化动力学分析

以双酚芴、二甲基二氯硅烷、环氧氯丙烷为原料,合成了二甲基硅烷芴基环氧树脂（BMEBF）,并利用FT IR、^1H NMR确认了产物结构,盐酸-丙酮法测定其环氧值为0.22。热重分析表明,BMEBF的初始分解温度达347.66℃,较环氧树脂E-51高89℃;在600℃时的残余质量分数也高出21个百分点。对二氨基二苯甲烷（DDM）-BMEBF固化体系的非等温固化动力学研究发现,根据Kissinger法及Ozawa法得到的该固化反应活化能分别为53.616 kJ/mol和57.980 kJ/mol,反应级数都接近1;BMEBF-DDM体系的固化温度为140-150℃,后固化温度为180-190℃。     

大规模电磁场数值计算中并行迭代方法的比较

并行计算是进行大规模数值计算发展的必然趋势.以线性方程组的并行求解为线索,对并行迭代方法在电磁场数值计算中的应用作了描述和概括,指出各种并行迭代方法的使用条件和适用范围,并对多重网格法和区域分解法这两种预处理方法进行了比较.     

Effects of addition orders on the properties of fluorine‐containing copolyimides

A series of fluorine‐containing copolyimides were synthesized by three different orders of addition of monomers. The fluorine‐containing copolyimides were prepared by the reaction of 4,4′‐diaminodiphenylmethane (DDM) with 2,2′‐bis(3,4‐dicarboxyphenyl) hexafluoropropane dianhydride (6FDA), and pyromellitic dianhydride (PMDA). The synthesis reactions of the copoly(amic acid)s (PA) were carried out by three different orders of addition of the monomers with different molar ratios of 6FDA to PMDA. The viscosity of the PA solution obtained by DDM–(6FDA+PMDA), that is, 6FDA and PMDA added simultaneously to DDM in N‐methyl‐2‐pyrrolidinone (NMP), was higher than the other two addition orders (i.e., DDM–6FDA–PMDA and DDM–PMDA–6FDA). The viscosity decreased as the relative amount of 6FDA to PMDA increased. The copolyimides formed by different addition orders but the same 6FDA‐to‐PMDA molar ratios contained different properties, such as dielectric constant, moisture absorption, contact angle, and optical transparency. All of these copolyimides were insoluble in common organic solvents, such as NMP and tetrahydrofuran. Thermogravimetric analysis showed that the onset temperature of 8% weight loss decreased slightly as [6FDA] : [PMDA] increased. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 77: 3252–3258, 2000     

基于修正快速傅里叶变换算法的仪表着陆系统信号干扰抑制与定量分析

针对日益繁忙的机场空域和周边建筑对仪表着陆系统信号干扰的增加,以及传统模拟处理技术缺陷,提出一种基于修正快速傅里叶变换(FFT)频谱校正和最小均方差(LMS)算法自适应滤波器结合实现仪表着陆系统(ILS)信号鉴频分离的技术方案。该方案应用LMS自适应滤波器对ILS信号干扰进行抑制,完成滤波器的权值系数设定,并通过修正FFT技术在时域与频域内对ILS信号进行频谱分离与提取,修正其频谱幅值,以消除由于采样引起的频谱泄露和栅栏效应对信号的影响,使得提取信号逼近理想情况,提高调制度差(DDM)识别精度。针对ILS信号的干扰抑制与频域分离进行了仿真验证,结果表明所提出的信号处理系统技术方案能够有效地对干扰进行抑制,完成信号频域识别,为飞机着陆进近阶段提供准确可靠的导航信息。     

可编程控制器在叉车自动称重系统中的应用

本文介绍了用于叉车实时称重和显示功能的称重仪的研制开发情况,讨论了可编程控制器(PLC)、西门子TD200文本显示器和DDM4A数字显示器在叉车自动称重系统中的应用,同时讨论了基于PLC的称重程序和功能模块的编制开发情况.     

High-resolution boosted reconstruction of γ-ray spectra

Direct demodulation method(DDM) was applied to reconstruct γ-ray spectra. Boosted Richardson-Lucy iteration was introduced into DDM. Monte Carlo method(here GEANT 4) was proposed to calibrate response function and establish response matrix. First, gauss function was regarded as total energy peak. Spectra line was simulated with nine gauss functions. And afterwards DDM was applied to reconstruct the simulated spectra line and determine peak positions and areas. Compared with original spectra, for case that peak position interval was about 1/3 full width half maximum(FWHM), the error of rebuilding peak position was 2 channels. The rest of peaks could be searched accurately. The relative errors of all peaks' area were less than 4%. Then, three key factors, including noise, background, response matrix, were discussed. Finally, DDM was applied to calibrate the field NaI gamma spectrometer. The errors of U, Th, K were less than 5%. Comprehensive studies have shown that it is feasible to reconstruct gamma-ray spectra with DDM. DDM can significantly pseudo-improve energy resolution of gamma spectrometer, effectively decompose doublets whose peak potential interval is1/3 FHWM, and accurately search peak and calculate areas. DDM can restrain noise strongly but is greatly influenced by background. And DDM can improve the accuracy of qualitative and quantitative analysis in combination with the conventional spectrum analysis method.     

EP/改性DDM体系的固化反应动力学及性能研究

采用非等温DSC(差示扫描量热)法对EP(环氧树脂)/改性DDM(4,4′-二氨基二苯基甲烷)体系的固化反应过程进行了跟踪。采用Kissinger、Ozawa、Crane和T-β(温度-升温速率)外推法等得到该固化体系的动力学参数和固化工艺条件,并对其力学性能和热变形温度进行了测定。结果表明:EP/改性DDM体系的表观活化能为49.43 kJ/mol,反应级数为0.869,固化条件为"85℃/2 h→125℃/2 h",热变形温度为130℃;与EP/DDM体系相比,该固化体系的表观活化能降低了7.0%,热变形温度下降了16.1%,拉伸强度和压缩强度提高了20%以上,而弯曲强度和弯曲模量基本上保持不变。     

基于动态R-树结构的DDM区域匹配算法

分析了传统数据分发管理(DDM)匹配方法,结合空间索引技术的特点,提出了一种动态R-树区域匹配方法,通过建立R-树对公布和订购区域进行组织管理,并在R-树上实现订购区域与公布区域的匹配搜索。仿真实验结果表明,选取适当参数M,可减少动态R-树DDM匹配算法的时间开销,达到较优性能。     

环氧树脂对PVC/ABS共混物性能的影响

研究了固体环氧树脂(EP)对聚氯乙烯(PVC)/丙烯腈-丁二烯-苯乙烯共聚物(ABS)/EP共混物力学性能和热稳定性的影响,重点考察了EP环氧值和固化剂DDM对共混物性能的影响。结果表明:PVC/ABS/EP共混物表现为脆性断裂;加入DDM后,共混物的拉伸强度明显提高,但冲击性能影响不大;对于PVC/ABS/EP/DDM共混物,随着EP含量的增加,共混物的拉伸强度上升,且环氧值高的EP704对共混物拉伸强度的提高更大;加入2%的低环氧值EP903后,共混物的冲击强度达到最大值,而EP704的加入则对共混物的冲击性能影响不大;环氧树脂的加入在一定程度上削弱了PVC/ABS共混物的热稳定性。     

用区域分裂法求解波导不连续性问题

基于区域分裂法（DDM）结合频域有限差分（FDFD）和波导模式展开求解矩形波导不连续性问题，在矩形波导的规则部分用解析的方法把电磁场用波导模式展开，不规则部分用FDFD方法建立关于各离散点电磁场值的方程，各个相邻的子区域间用Depres传输条件连接，通过迭代得到整个区域的解，计算了几个波导不连续性问题的散射参数，结果和其它方法结果吻合较好，证明了该算法的正确性。