Relationship between HOMO energy level and open circuit voltage of polymer solar cells

A series of π-conjugated polymers (PDHF-BT and PDHF-TBT) with 4-(3,4-ethylenedioxythienyl)-2,1,3-benzothiadiazole (BT), 4,7-bis(3,4-ethylenedioxythienyl)-2,1,3-benzothiadiazole (TBT), and 9,9′-dihexylfluorene were synthesized by the Suzuki coupling reaction. The HOMO energy level of PDHF-BT was −5.47 eV, which was lower than that of PDHF-TBT (−5.22 eV), while the LUMO energy level of PDHF-BT (−3.45 eV) was very similar to that of PDHF-TBT (−3.42 eV). These energy levels of PDHF-BT and PDHF-TBT were also supported by a DFT calculation. The power conversion efficiency (PCE) of the polymer solar cell (PSC) with a structure of ITO/PEDOT:PSS/PDHF-BT:PCBM (1:1)/Al was determined as 0.34% and it was larger than that of the device based on PDHF-TBT (0.22%). Correspondingly, the V_oc of the PSC based on PDHF-BT (0.71 V) was much larger than that of the device based on PDHF-TBT (0.40 V). The results support that the V_oc of polymer based PSCs is strongly related to the HOMO energy level of the active polymers.     

基于加窗DFT的相位差高精度测量算法

本文提出一种基于加窗离散傅立叶变换(DFT)的相位差微机高精度测量算法，详细论述算法原理及实现步骤。采用该算法，相位差测量值理论上与信号频率无关，从而不需要跟踪测量信号频率，不需要对信号整周期采样。算法实现简单，计算量较小，精度高，对高次谐波和噪声具有较强的抑制能力，仿真计算和工程应用验证了其可行性和有效性。     

基于密度泛函理论计算的3d过渡金属掺杂CuGaS2电子结构分析

3d transition metals doped CuGaS2 are considered as possible absorbing material candidates for intermediated band thin film solar cells. The electronic structure and optical properties of 3d transition metals doped CuGaS2 are investigated by using density functional theory calculations with the GGA ＋ U method in the present work. The doping with 3d transition metals does not obviously change the crystal structure, band gap, and optical absorption edge of the CuGaS2 host. However, in the case of CuGa1-χTMχS2 （TM = Ti, V, Cr, Fe, and Ni）, there is at least one distinct isolated impurity energy level in the band gap, and the optical absorption is enhanced in the ultraviolet-light region. Therefore, these materials are band thin film solar ceils. The calculated results are very well better explain them. ideal absorber material candidates for intermediated consistent with experimental observations, and could better explain them.     

基于多相滤波器的高分辨率信道化接收机设计

针对无盲区的多相数字信道化接收机,综合考虑了原型滤波器的瞬态响应时间和系统后续处理速度,推导出选择滤波器过渡带宽的数学公式,为信道化接收机的滤波器合理设计提供了评判标准。针对信道化接收机的频率分辨率受信道带宽限制的缺点,在系统后续处理中提出了重叠的离散傅里叶变换算法,减小计算量的同时提高了系统的实时性。能够灵活设置单组DFT运算点数,提高了接收机频率测量的精度。最后,通过仿真分析验证了该高效设计的可行性。     

Hierarchical NiMn Layered Double Hydroxide/Carbon Nanotubes Architecture with Superb Energy Density for Flexible Supercapacitors

A hierarchical nanostructure composed of NiMn‐layered double hydroxide (NiMn‐LDH) microcrystals grafted on carbon nanotube (CNT) backbone is constructed by an in situ growth route, which exhibits superior supercapacitive performance. The resulting composite material (NiMn‐LDH/CNT) displays a three‐dimensional architecture with tunable Ni/Mn ratio, well‐defined core‐shell configuration, and enlarged surface area. An electrochemical investigation shows that the Ni₃Mn₁‐LDH/CNT electrode is rather active, which delivers a maximum specific capacitance of 2960 F g^–1 (at 1.5 A g^–1), excellent rate capability (79.5% retention at 30 A g^–1), and cyclic stability. Moreover, an all‐solid‐state asymmetric supercapacitor (SC) with good flexibility is fabricated by using the NiMn‐LDH/CNT film and reduced graphene oxide (RGO)/CNT film as the positive and negative electrode, respectively, exhibiting a wide cell voltage of 1.7 V and largely enhanced energy density up to 88.3 Wh kg^–1 (based on the total weight of the device). By virtue of the high‐capacity of pseudocapacitive hydroxides and desirable conductivity of carbon‐based materials, the monolithic design demonstrated in this work provides a promising approach for the development of flexible energy storage systems.     

双向DFT对称补偿测相法

为提高给定数据长度下的相位估计精度,该文提出双向DFT对称补偿测相法。该方法对样本做前向和后向两次DFT变换,再从前、后DFT谱的对称峰值谱位置做谱综合而提取出中心样点的精确相位信息。基于此,推导出了相位估计方差的闭合理论表达式,仿真实验验证了该表达式的正确性,并且证明了该文方法的相位估计方差处于全相位FFT(apFFT)估计法和两参数克拉美罗限(CRLB)之间。该文方法测相精度高,具有广泛应用前景。     

Theoretical study of the structural,elastic and thermodynamic properties of chalcopyrite ZnGeP2

The structural, elastic, and thermodynamic properties of ZnGeP₂ with chalcopyrite structure are investigated using the pseudo-potentials plane wave method based on the density functional theory with the generalized gradient approximation. The lattice parameters (a, c and u) are directly calculated and agree well with previous experimental and theoretical results. The obtained negative formation enthalpy shows that ZnGeP₂ crystal has strong structural stability. We have also calculated the bulk modulus B and the elastic parameters (C₁₁, C₁₂, C₁₃, C₃₃, C₄₄, and C₆₆) which have not been measured yet. The accuracy and reliability of the calculated elastic constants of ZnGeP₂ crystal are discussed. In addition, the pressure and temperature dependencies of the lattice parameters, bulk modulus, Debye temperature, Grüneisen parameter, entropy, volume thermal expansion coefficient, and specific heat capacity are obtained in the ranges of 0–20 GPa and 0–1200 K using the quasi-harmonic Debye model. To our knowledge this is the first quantitative theoretical prediction of the thermodynamic properties for ZnGeP₂ compound and still awaits experimental confirmations.     

一种新型低峰值功耗的BIST设计研究

随着手持设备的兴起和芯片对晶片测试的要求越来越高,内建自测试的功耗问题引起了越来越多人的关注。文章对目前内建自测试的可测性设计技术进行了分析,并提出了折叠种子优化降低节点峰值功耗的模型,通过调整种子结构和测试向量的相关性的办法来避免过高的SoC测试峰值功耗。采取了屏蔽无效测试模式生成、提高应用测试向量之间的相关性以及并行加载向量等综合手段来控制测试应用,使得测试时测试向量的输入跳变显著降低,从而大幅度降低节点的峰值功耗。实验结果表明,该方案可以有效地避免BIST并行执行可能带来的过高峰值功耗。     

基于线性迭代的DFT调制滤波器组的设计算法

该文研究了单原型的DFT调制滤波器组的设计方法。在该方法中,滤波器组的设计问题被归结为一个无约束的优化问题,其目标函数为滤波器组的传递失真、混叠失真和原型滤波器的阻带能量的加权和。结合线性化方法,原型滤波器通过迭代求解。在单步迭代中,原型滤波器的系数通过解析式求解得到。仿真表明,与传统的设计算法相比,本文方法设计所得的DFT调制滤波器组重构误差减小了约40dB,阻带衰减提高了约2dB。并且新算法的计算复杂度明显低于传统算法。     

Joint use of time-domain and windowed method for design of modulated DFT filter banks

A novel and efficient technique to design modulated discrete Fourier transform （DFT） filter banks is introduced in this paper. The proposed method first relaxes the limits that the synthesis filters are the time-reversed version of the analysis filters and then adopts the time domain formula of the perfect reconstruction property as the solution to design the synthesis filters. The prototype filter in analysis filter banks is designed based on Fourier-Kaiser window approach. Simulation results show that the designed filter banks approximately satisfy the perfect reconstruction with controllable reconstruction errors.