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21.
22.
ABSTRACT: Physical aging of amorphous anhydrous fructose at temperature 5 °C and at 22 °C was studied using differential scanning calorimetry (DSC). The dynamic glass transition temperature, Tg0 for unaged samples was 16 °C and 13.3 °C for heating rate of 10 °C/min and 1 °C/min, respectively. The fictive temperature, Tf0 for unaged samples calculated by Richardson and Savill method was 12 °C, which is close to the dynamic value obtained from the lower DSC heating rate. The fictive temperature Tf of the aged fructose glasses at temperatures both below and above the transition region was fitted well by a non-exponential decay function (Williams-Watts form). Aging above the transition region (22 °C) for 18 d increased both the dynamic glass transition temperature Tg and the fictive temperature Tf . However, aging below the transition region (5 °C) for 1 d increased the dynamic glass transition temperature Tg but decreased the fictive temperature Tf . 相似文献
23.
对韶钢炼铁厂4号高炉炉况和操作上存在的问题进行了分析,主要原因是原材料质量较差,精料水平低,同时,高炉操作不能完全适应原材料条件.按照上稳下活工艺的原则,采取合理鼓风动能、活跃炉缸工作状态、稳定热制度、合理中部冷却强度、炉顶小高压操作以及使用上部调节手段等一系列措施,使高炉的炉况顺行得到了较大的改善,各项主要技术经济指标取得相应的进步.2001年利用系数达3.024 t/m3·d,焦比达441 kg/t. 相似文献
24.
The dynamic response of highway bridges subjected to moving truckloads has been observed to be dependent on (1) dynamic characteristics of the bridge; (2) truck configuration, speed, and lane position on the bridge; and (3) road surface roughness profile of the bridge and its approach. Historically, truckloads were measured to determine the load spectra for girder bridges. However, truckload measurements are either made for a short period of time [for example, weigh-in-motion (WIM) data] or are statistically biased (for example, weigh stations) and cost prohibitive. The objective of this paper is to present results of a 3D computer-based model for the simulation of multiple trucks on girder bridges. The model is based on the grillage approach and is applied to four steel girder bridges tested under normal truck traffic. Actual truckload data collected using a discrete bridge WIM system are used in the model. The data include axle loads, truck gross weight, axle configuration, and statistical data on multiple presence (side by side or following). The results are presented as a function of the static and dynamic stresses in each girder and compared with code provisions for dynamic load factor. The study provides an alternate method for the development of live-load models for bridge design and evaluation. 相似文献
25.
Dynamic vulcanisation of EPDM/PE-based thermoplastic vulcanisates studied along the extruder axis 总被引:1,自引:0,他引:1
Simple blending and dynamic vulcanisation of EPDM/PE blends using the resol/SnCl2 system was studied in an extruder using a series of sampling devices. The melting of the PE pellets occurs just in front of and in the first kneading zone. Upon complete melting of the PE phase, the EPDM/PE blends reach very quickly their final morphology. Crosslinking of the EPDM phase to high levels occurs already when the PE phase is not yet fully molten. The higher the EPDM content, the higher the viscous dissipation, the higher the melt temperature and, consequently, the higher the crosslinking rate. For the EPDM/PE (50/50; w/w) TPV a transition from continuous via co-continuous to fully dispersed EPDM is observed, which is driven by crosslinking. Although the degree of crosslinking of the EPDM rubber is very high, this does not prevent phase inversion of the blend. The EPDM/PE interface is rather blurred, because PE crystalline lamellae are growing into the EPDM domains, probably because of the high compatibility between PE and EPDM (60 wt% of ethene). This study shows that dynamic vulcanisation in extruders proceeds quite differently from that in batch kneaders, where melting, mixing and crosslinking are separated in time. In extruders mass and heat transport, melting of the thermoplastic, morphology development (including dispersion and phase inversion), distribution and dissolution of (crosslinking) chemicals and crosslinking of the rubber do not occur as independent phenomena, but mutually and/or continuously interact. 相似文献
26.
27.
In polyolefin processes the melt index (MI) is the most important control variable indicating product quality. Because of
the difficulty in the on-line measurement of MI, a lot of MI estimation and correlation methods have been proposed. In this
work a new dynamic MI estimation scheme is developed based on system identification techniques. The empirical MI estimation
equation proposed in the present study is derived from the 1
st
-order dynamic models. Effectiveness of the present estimation scheme was illustrated by numerical simulations based on plant
operation data including grade change operations in high density polyethylene (HDPE) processes. From the comparisons with
other estimation methods it was found that the proposed estimation scheme showed better performance in MI predictions. The
virtual sensor model developed based on the estimation scheme was combined with the virtual on-line analyzer (VOA) to give
a quality control system to be implemented in the actual HDPE plant. From the application of the present control system, significant
reduction of transition time and the amount of off-spec during grade changes was achieved 相似文献
28.
In this work, we study dynamic provisioning of multicast sessions in a wavelength-routed sparse splitting capable WDM network
with an arbitrary mesh topology where the network consists of nodes with full, partial, or no wavelength conversion capabilities
and a node can be a tap-and-continue (TaC) node or a splitting and delivery (SaD) node. The objectives are to minimize the
network resources in terms of wavelength-links used by each session and to reduce the multicast session blocking probability.
The problem is to route the multicast session from each source to the members of every multicast session, and to assign an
appropriate wavelength to each link used by the session. We propose an efficient online algorithm for dynamic multicast session
provisioning. To evaluate the proposed algorithm, we apply the integer linear programming (ILP) optimization tool on a per
multicast session basis to solve off-line the optimal routing and wavelength assignment given a multicast session and the
current network topology as well as its residual network resource information. We formulate the per session multicast routing
and wavelength assignment problem as an ILP. With this ILP formulation, the multicast session blocking probability or success
probability can then be estimated based on solving a series of ILPs off-line. We have evaluated the effectiveness of the proposed
online algorithm via simulation in terms of session blocking probability and network resources used by a session. Simulation
results indicate that our proposed computationally efficient online algorithm performs well even when a fraction of the nodes
are SaD nodes. 相似文献
29.
Software plays an increasingly important role in modern safety-critical systems. Although, research has been done to integrate software into the classical probabilistic risk assessment (PRA) framework, current PRA practice overwhelmingly neglects the contribution of software to system risk. Dynamic probabilistic risk assessment (DPRA) is considered to be the next generation of PRA techniques. DPRA is a set of methods and techniques in which simulation models that represent the behavior of the elements of a system are exercised in order to identify risks and vulnerabilities of the system. The fact remains, however, that modeling software for use in the DPRA framework is also quite complex and very little has been done to address the question directly and comprehensively. This paper develops a methodology to integrate software contributions in the DPRA environment. The framework includes a software representation, and an approach to incorporate the software representation into the DPRA environment SimPRA. The software representation is based on multi-level objects and the paper also proposes a framework to simulate the multi-level objects in the simulation-based DPRA environment. This is a new methodology to address the state explosion problem in the DPRA environment. This study is the first systematic effort to integrate software risk contributions into DPRA environments. 相似文献
30.
裂缝性油气藏采收率:100个裂缝性油气田实例的经验总结 总被引:5,自引:2,他引:3
通过对世界上100个裂缝性油气藏的综合评价,研究储集层及流体本身的性质(包括孔隙度、渗透率、黏度、可动油比例、含水饱和度、润湿性及裂缝分布特征等)和驱动机制及油藏管理战略(优化日产量和采用不同类型的提高采收率技术)对其最终采收率的影响。将裂缝性油气藏分为4类:I类的基质几乎没有孔隙度和渗透率,裂缝是储存空间和流体流动的通道;Ⅱ类的基质有较低的孔隙度和渗透率,基质提供储存空间,裂缝提供流动通道;Ⅲ类(微孔隙)的基质具有高孔隙度和低渗透率,基质提供储存空间,裂缝提供流动通道;Ⅳ类(大孔隙)的基质具有高的孔隙度和渗透率,基质提供储存空间和流动通道,裂缝仅增加渗透率。对26个Ⅱ类油气藏和20个Ⅲ类油气藏的开采历史的研究表明:Ⅱ类油气藏的采收率受水驱强度和最优日产量控制,日产量过高会很容易破坏Ⅱ类油气藏,一些Ⅱ类油气藏如果管理得当,采收率可以很高,不需要二次或三次采油;Ⅲ类油气藏的采收率主要受岩石和流体本身性质的影响,特别是基质渗透率、流体重度、润湿性以及裂缝强度等,不进行二次或三次采油不可能完全开采,往往需要采用一些提高采收率的专门技术。以往将Ⅱ类和Ⅲ类裂缝性油气藏归为一类,认识它们的区别将有助于选择更好的开发策略。 相似文献