葡萄糖电解氧化还原工艺研究

采用自制的无膜电解槽，对同时电解氧化还原葡萄糖生成葡萄糖酸和山梨醇的工艺进行了研究。所得到的最佳工艺条件为：葡萄糖浓度０．４ｍｏｌ／Ｌ，ｐＨ值１１，电流密度３Ａ／ｄｍ￣２。在此条件下电解１２ｈ，葡萄糖转化率可达９６．４％，葡萄糖酸产率８８％，山梨醇产率１０％。同时，考察了和Ｚｎ￣（２＋）加入以及ｐＨ值对电流效率的影响。     

尼龙6表面金属(Ni)化膜材料的制备及性能研究

用化学还原法制得了尼龙６表面金属（Ｎｉ）化膜材料。研究了还原条件，金属盐浓度对膜材料电性能的影响，以及膜材料的电发热性能，用光电子能谱和扫描电子显微镜对其表面及形貌进行了表征。     

Nitrogen dioxide effect in the reduction of nitric oxide by propane in oxidizing atmosphere

The role of nitrogen dioxide in the selective reduction of NO by propane over a Cu-MFI zeolite is investigated. NO₂ and NO reductions were carried out under similar conditions of reaction. In the presence of oxygen, the reduction of NO by C₃H₈ does not differ significantly from that of NO₂. In the absence of oxygen, the reduction of NO₂ by propane occurs with a partial decomposition of the nitric dioxide molecule. Such a decomposition leads to the formation of oxygen, which is responsible for the increase in catalytic activity by comparison with the same reaction performed with NO. NO₂ formed and released in the gas phase during the reduction of NO by propane in the presence of oxygen does not play a predominant role in the catalytic process.     

Electrochemical noise analysis for estimation of corrosion rate of carbon steel in bicarbonate solution

We have investigated the electrochemical noise behavior of carbon steel in fully deaerated aqueous bicarbonate solutions, and discussed the optimum conditions of the noise analysis for estimating corrosion rate of the steel. Noise of the potential difference and of the short-circuit current between two identical steel coupons were successfully measured. The time-series noise patterns were transformed into frequency domain by fast Fourier transformation, and then their power spectrum densities (PSDs) at a frequency were determined to be compared with the corrosion rate. The PSDs of the potential and of the current varied with changing environmental factors of bicarbonate concentration, pH, and immersion time. The factors also controlled the corrosion rate of the steel. The PSDs were associated with the corrosion rate, and then it was found that the PSDs of the potential and of the current showed linear correlation with the corrosion rate in log-log scale. There was also linear relationship between the corrosion rate and a spectral noise resistance obtained from the PSDs of the potential and the current. The linearities of the three correlations were better at a lower analyzed frequency. Furthermore, the PSDs of the current and the noise resistance indicated more linear correlation with the corrosion rate than that of the potential. As the simplicity of the measurement system is additionally considered, it is concluded that the PSD of the current noise at an analyzed frequency of 3 mHz is the optimum conditions for estimating the corrosion rate from 10⁻² to 10⁰ A m⁻² in this study.     

太钢3号卷取机TDC控制系统开发与应用

太钢热连轧厂3号卷取机改造前所采用的美国西屋公司WDPF控制系统已不能满足目前生产和质量的要求，进而应用西门子公司的TDC控制系统对其进行了改造。该项目的设计、编程、调试由太钢自行完成，改造中采用了带钢头部张力优化控制、夹送辊张力控制、卷取机平滑曲线减张控制、卸卷小车横移极限升降极限模拟控制等多项新技术。其改造后产品产量、综合成卷率和卷形良好率均明显提高。     

Evaluation of rainfall networks using entropy: II. Application

This paper, the second in the series, applies the entropy approach to space and time evaluation of rainfall networks in Louisiana. The evaluation is made for five sampling intervals: daily, 2-day, weekly, monthly, and yearly, and for two separate seasons. In each case, the best combination of raingages is suggested and the lines of equal information (isoinformation contours) are constructed showing the areas of greater or less information transfer. The isoinformation lines are especially suitable in decisions concerning the expansion of the existing network or deleting the unnecessary raingages.     

Parallel associative combinator evaluation II

A new evaluation model for SK combinator expressions is presented and used as a basis for the design of a novel processor. The resulting machine architecture resembles a dataflow ring, but executions are constrained to be fully lazy. An automatic dynamic load sharing mechanism for a distributed multiprocessor architecture is suggested, and initial simulation results are presented.     

炼厂碱渣处理工艺及设计优化

针对催化裂化装置汽油和液态烃精制产生的含硫废弃物的碱渣处理，讨论了碱渣提酚、碱渣湿式氧化脱臭两种处理工艺的环境治理效果，并就碱渣湿式氧化脱臭工艺如何降低运行成本、减少污水排放等内容进行了探讨。     

Potential control under thin aqueous layers using a Kelvin Probe

Kelvin Probes can be modified to control as well as monitor potential. The design and operation of two different Kelvin Probe Potentiostats (KPPs) are described in this paper. One approach uses a permanent magnet and double coil to oscillate the needle at a fixed frequency, an AC backing potential, and software analysis and control schemes. This technique can also control the distance between the tip and sample, thereby tracking the topography of the sample. Both KPPs were used to make measurements on Type 304L stainless steel under thin layers of electrolyte. Cathodic polarization curves exhibited a limiting current density associated with oxygen reduction. The limiting current density varied with solution layer thickness over a finite range of thickness. Anodic polarization curves on 304L in a thin layer of chloride solution resulted in pitting corrosion. The breakdown potential did not vary with solution layer thickness. However, the thin layer was observed to increase in volume remarkably during pit growth owing to the absorption of water from the high humidity environment into the layer with ionic strength increased by the pit dissolution. The open circuit potential (OCP) and solution layer thickness were monitored during drying out of a thin electrolyte layer. Pitting corrosion initiated, as indicated by a sharp drop in the OCP, as the solution thinned and increased in concentration.     

植物油、脂肪酸和植物油甲酯在塔河稠油掺稀降黏中的应用评价

稠油由于富含沥青质、胶质等重质组分而具有很高的黏度，给稠油的开采和运输带来了很大的困难。降低稠油黏度进而改善其流动性成为一项十分重要的工作。以植物油、脂肪酸及植物油甲酯为掺稀介质，以塔河油田稠油为研究对象，考察对比了3种不同的掺稀介质对稠油的掺稀降黏效果。研究结果表明，3种掺稀介质对稠油具有良好的掺稀降黏效果，在同一掺稀比下，植物油甲酯对稠油的降黏效果最显著，其次是脂肪酸，再次是植物油。通过斑点试验考察了掺稀介质和稠油的相容性和体系稳定性。结果显示，植物油甲酯与稠油相容性和稳定性最好，脂肪酸和植物油与稠油的相容性和稳定性相对较差。