钛精矿回转窑直接还原过程结圈可能性的探讨

通过煤种，入窑球冷态强度和还原过程强度，以及钛精矿与煤灰混合物的软化温度等分析探讨了钛精矿预热球团回转窑直接还原产生结圈的可能性，获得了可以避免结圈的结论。     

A Theoretical Framework for Core Material Properties Identification in Cellular Solids using Novelty Detection

Abstract:  This paper presents a novelty detection-based technique to identify core material properties of honeycombs and cellular structures. A numerical model (finite element) representing full scale and/or reduced size of the cellular solid is used to generate transmissibilities between topological homologous points at cells in different locations. In order to make the procedure robust against noise, these transmissibilities are artificially corrupted. This step is representative of a series of experimentally obtained measurements which automatically return information relating to the size and shape of data noise along with the mean measurement. The next stage, both in this paper and in the proposal for the experimental approach, is to generate several further sets of transmissibilities from the finite element model; the only difference being that the core material properties are altered from the original values. A novelty detection framework is then adopted to find a similarity measure between each of these 'test' transmissibilities and the original set thereby identifying the material properties. Although this work is concerned with identifying only one material property, the methodology extends to identifying several properties.     

珠钢不锈钢冶炼技术探讨

本文阐述了不锈钢冶炼的关键技术，为生产准备提供帮助。     

化学还原法制备纳米铜粉的研究

本文采用KBH4在液相中化学还原CuSO4,并加入KOH和络合剂EDTA ,制得了纳米级的纯净的铜粉 ,通过调整反应物的浓度 ,可以消除Cu2 O等杂质。制备的纳米铜粉还存在一定程度的团聚 ,需试验加入分散剂来改善。     

薄板坯连铸生产SS400钢工艺技术研究

对唐钢薄板坯连铸机生产的SS400钢的生产工艺进行了分析,认为薄板坯连铸机生产的SS400钢,在采取了精炼站在线定氧,将钢水全氧控制在25×10~(-6)左右,同时连铸采取保护浇注和轻压下等技术后,能够确保薄板坯连铸SS400钢的顺利浇注,轧制的板带材表面质量良好,机械性能符合要求。     

Catalytic reduction of N2O with CH4 and C3H6 over Ag–Rh/Al2O3 bimetallic catalyst in the presence of oxygen

A study of nitrous oxide (N₂O) reduction with methane (CH₄) and propene (C₃H₆) in the presence of oxygen (5%) over Ag/Al₂O₃, Rh/Al₂O₃ and Ag–Rh/Al₂O₃ catalysts, with Ag and Rh loadings of 5 wt% and 0.05 wt% respectively, has been performed. From the results, it was observed that the Ag–Rh bimetallic catalyst was the most active for both nitrous oxide removal (more than 95%) and hydrocarbon oxidation. This high activity seems to be connected with a synergistic effect between Ag and Rh. The findings from X‐ray diffraction and X‐ray photoelectron spectroscopy studies showed also, that there were no strong interactions (eg alloying) between Ag and Rh. Copyright © 2005 Society of Chemical Industry     

Inhibiting and deactivating effects of water on the selective catalytic reduction of nitric oxide with ammonia over MnOx/Al2O3

The effect of water on the selective catalytic reduction (SCR) of nitric oxide with ammonia over alumina supported with 2–15 wt.-% manganese oxide was investigated in the temperature range 385–600 K, with the emphasis on the low side of this temperature window. Studies on the effect of 1–5 vol.-% water vapour on the SCR reaction rate and selectivity were combined with TPD experiments to reveal the influence of water on the adsorption of the single SCR reactants. It turned out that the activity decrease due to water addition can be divided into a reversible inhibition and an irreversible deactivation. Inhibition is caused by molecular adsorption of water. TPD studies showed that water can adsorb competitively with both ammonia and nitric oxide. Additional kinetic experiments revealed that adsorbed ammonia is present in excess on the catalyst surface, even in the presence of water. Reduced nitric oxide adsorption is responsible for the observed reversible decrease in the reaction rate; the fractional reaction order changes from 0.79 in the absence of water to 1.07 in its presence. Deactivation is probably due to the dissociative adsorption of water, resulting in the formation of additional surface hydroxyls. As the amount of surface hydroxyls formed is limited to a saturation level, the deactivating effect on the catalyst is limited too. The additional hydroxyls condense and desorb in the temperature range 525–775 K, resulting in a lower degree of deactivation at higher temperature. A high temperature treatment at 775 K results in a complete regeneration. The amount of surface hydroxyls formed per unit surface area decreases at increasing MnO_x-loading. The selectivity to the production of nitrogen is enhanced significantly by the presence of gas phase water.     

具有减少辨识参数的随机多变量极点配置自适应控制器

本文提出了一种新的限制输出个数减少随机多变量自适应控制中辨识参数的方法，并给出了减少辨识参数的极点配置自适应算法。虽然采用ｎ个输入１个输出的减少辨识参数的模型来设计控制器，但所提出的控制器能够保证被控系统的几个输出跟踪参考输入信号，仿真结果表明，所提出的方法是成功的。     

镁法海绵钛生产工艺中大型无隔板镁电解槽的节能实践

以镁法海绵钛生产工艺中大型无隔板镁电解槽的实际节能情况为例，探讨了在镁电解生产中的非生产耗电、生产耗电、漏电等因素造成的能量浪费，阐述了生产中粗镁直流电耗、电流效率、工作电压3者之间的关系，指出了影响电解槽工作电压的有关因素及降低电解槽工作电压的途径。