敞口消解-ICP-MS测定微合金钢中4种微量元素的方法研究

采用HNO3＋HCl混合酸消解体系敞口消解试样,选取74Ge作为测定48Ti,52Cr,59Co,61Ni的内标元素,建立了微合金钢中微量元素钛、铬、钴、镍的电感耦合等离子体质谱（ICP-MS）测定方法。该方法线性关系良好（相关系数r=0.99985～0.99998）,检出限为6pg·g-1～39pg·g-1,平均加标回收率达到98%～102%,方法精密度好,相对标准偏差（n=9）在0.47%～2.04%之间。所建立的分析方法实现了对微合金钢样品中4种微量元素的测定,实际样品的测定结果与参考值相符。     

Estimation of uncertainties of the method to determine the concentrations of Cd, Cu, Fe, Pb, Sn and Zn in tomato paste samples analysed by high resolution ICP-MS

Cadmium, copper, iron, lead, tin and zinc were determined in tomato paste samples by using high resolution inductively coupled plasma mass spectrometry. This study was a part of Proficiency Testing scheme conducted by National Metrology Institute (UME) of Turkey. The method was validated. The percentage relative errors obtained for each element ranged between 1.4% and 9.0% for NIST SRM 1573a, tomato leaves. Measurement uncertainties of all elements were calculated by applying bottom-up approach. The calculated percentage relative uncertainties for the elements were between 8.2% and 16.4%. The major contributions to the uncertainty budget came from the calibration curves, repeatability and recovery. Tomato paste samples gathered from the supermarkets in Turkey were analysed by using the validated method. Their levels were compared both with the literature values and European Commission Regulations.     

Chemical diffusion in the iridium-richA1 andL12 phases in the Ir-Nb system

The diffusion in iridium-rich Ir-Nb alloys has been studied by single-phase interdiffusion experiments. The chemical diffusion coefficient has been measured for the primary fcc solid-solution and theL1₂ ordered compound Ir₃Nb in the temperature range between 1650 and 1950 °C, using Ir/Ir-8Nb and Ir-26Nb/Ir-28Nb diffusion couples, respectively (numbers indicate mol%). While the chemical diffusion coefficient in the solid-solution phase is close to the tracer self-diffusion coefficient of pure iridium, the diffusion in the compound phase is extremely slow: the chemical diffusion coefficient is 1/40 to 1/50 of that in the solid solution. The low diffusion rate in the compound must be beneficial for high-temperature performance of refractory superalloys based on the Ir-Nb system. This article was presented at the Multicomponent-Multiphase Diffusion Symposium in Honor of Mysore A. Dayananda, which was held during TMS 2006, 135th Annual Meeting and Exhibition, March 12–16, 2006, in San Antonio, TX. The symposium was organized by Yongho Sohn of University of Central Florida, Carelyn E. Campbell of National Institute of Standards and Technology, Richard D. Sisson, Jr., of Worcester Polytechnic Institute, and John E. Morral of Ohio State University.     

现代家具设计应用传统元素的创意模式浅析

传统元素承载着传统文化千年的意涵,将传统元素运用于现代家具设计,既可传承传统又可将其精神与功能相结合,使家具推陈出新。本文从现代家具设计个案中,分析其应用传统元素的设计创新,根据对传统元素采取的复制、变形、组合、简化等手法,归纳出现代家具设计应用传统元素的创意模式,分别为：1.造型传承2.特征取用3.分解重组4.质感变化5.寓意转化。     

库哈斯的宣言——第十四届威尼斯建筑双年展

雷姆·库哈斯策展的第十四届威尼斯建筑双年展由一个大主题”原理”和3个副主题“吸收现代性：1914年～2014年”（国家馆）、“建筑的元素”（中央展馆）和”图景宏大的意大利“（军械库展馆）构成。文章对各个主题及相应展馆进行初步介绍．同时引征库哈斯对本届建筑双年展策展的想法及思考．并附上简要解读和个人理解。     

镍基单晶高温合金扩散阻挡层的研究进展

综述了镍基单晶高温合金扩散阻挡层的国内外研究进展。简要介绍了高温防护涂层/镍基单晶高温合金基体元素的互扩散现象,说明了扩散阻挡层的作用机理,阐述了扩散阻挡层的设计原则和要求,通过对比分析了各类扩散阻挡层的优缺点。最后对镍基单晶高温合金用扩散阻挡层的研究做出了展望。     

2011年闽东茶区春季茶青中稀土残留的检测与分析

采用电感耦合等离子体质谱(ICP-MS)技术,对60份茶青中残留稀土元素含量进行了测定,并对测定结果进行了分析。参照国家标准GB2762—2005《食品中污染物限量》(其中茶叶稀土的限量指标为≤2.0mg/kg,以La、Ce、Pr、Nd、Sm的氧化物总量计)对茶青中的稀土残留量进行评价分析,所测的闽东茶区春季茶青样品稀土合格率高达100%。     

Band gap uniformity and layer stability of HgTe-CdTe superlattices grown by photon-assisted molecular beam epitaxy

Two material properties important to the application of HgTe/CdTe superlattices for device fabrication are band gap uniformity and thermal stability. In this paper, we present the results of an infrared photoluminescence study of (211)B HgTe/CdTe superlattices grown by photon-assisted molecular beam epitaxy which show that cut-off wavelength uniformity can be controlled to a level commensurate with the demands of advanced infrared detector fabrication. Infrared photoluminescence and transmission electron microscopy were also employed to demonstrate that (211)B HgTe/CdTe superlattices are less prone to interdiffusion than previously believed.