Use of fluorescence to probe the surface dynamics during disorder-to-order transition and cluster formation in dihalonaphthalene-water thin films on Al2O3(0001)

Amorphous dihalonaphthalenes that are prepared by vacuum deposition onto a cold Al₂O₃ surface form electronically excited dimers when optically pumped, and their emission is characteristically red-shifted, broad and featureless compared to the monomeric fluorescence. If the surface is heated, the adlayer undergoes a disorder-to-order transition at a temperature characteristic of the molecule. Since pure crystalline dihalonaphthalenes typically fluoresce and do not exhibit excimeric features, the transition was studied by taking advantage of the changes in the spectral characteristics of the adlayer. These included transmittance, and emission from fluorescence and excimer. The combination of these methods allowed a close look at the surface dynamics of molecules on the surface of Al₂O₃ as the adlayer was heated from the deposition temperature to desorption.If a bilayer is formed by depositing water onto the surface with the organic adlayer on top, water, with its lower desorption energy, can be made to percolate into the organic layer. The optical probes indicate that the water clearly associates with the organic molecules while the excess water desorbs. By varying the coverage of either the water or the dihalonaphthalene, the stoichiometric composition of the cluster can be determined and are reported here.     

大型塑料模具钢模块淬火工艺的有限元分析

采用有限元软件MSC Marc模拟大型P20钢模块在复杂淬火工艺下的冷却过程,通过分析淬火过程中的温度变化历程及最终组织分布,为厂方生产的P20钢模块制定合理的淬火工艺.     

应用AFS—930型双道原子荧光光度计联合测定水中的砷和硒

本文采用原子荧光光谱法,研究了联合测定水样中砷和硒的技术。用10%盐酸和1%硫脲-1%抗坏血酸混合试剂处理样品,并以2.0%硼氢化钾和0.5%氢氧化钠为还原剂,在5%的盐酸介质测定砷和硒。砷和硒的检出限分别为:0.20μg/L和0.13μg/L,本方法具有操作简便、快速、基体干扰少、灵敏度高等优点,可用于水样中砷和硒的联合测定。     

稀土系贮氢合金的快淬及退火研究进展

快淬及退火对贮氢合金的组织和电化学性能影响很大.详细综述了近年来稀土系贮氢合金的各种快淬和退火工艺,以及不同工艺对合金电化学性能和组织的影响,旨在为提高贮氢合金的电化学性能提供思路和依据.     

利用铽与钙调素的荧光熄灭作用测定精锌中镉

研究了Cd2+对铽离子与钙调素(CaM)所形成的配合物(Tb43+.CaM)的荧光熄灭作用,考察了常见金属离子的干扰情况,在pH=5.0的六次亚甲基四胺缓冲溶液中,不断通入N2作保护气体可防止O2对Tb43+.CaM荧光的熄灭作用。由此建立了测定Cd2+的新方法,Cd2+浓度在0.0723~15.80μg/mL范围内与荧光熄灭值ΔIF具有良好的线性关系,检测下限为0.044μg/mL,相对标准偏差为5.1%。用该方法测定了精锌中镉的含量,平均回收率为96.1%。     

Quenching of self-excited vibrations

Stable normal-mode vibrations in engineering can be undesirable and one of the possibilities for quenching these is by embedding the oscillator in an autoparametric system by coupling to a damped oscillator. There exists the possibility of destabilizing the undesirable vibrations by a suitable tuning and choice of nonlinear coupling parameters. An additional feature is that, to make the quenching effective in the case of relaxation oscillations, one also has to deform the slow manifold by choosing appropriate coupling; this is illustrated for Rayleigh and van der Pol relaxation.     

基于模糊控制的钢轨双频淬火微机系统

对典型Fuzzy控制器的优缺点进行深入分析的基础上，提出了对多变量非线性系统使用Fuzzy-PI的控制策略，用于提高钢轨淬火生产线的温度控制精度，提高产品质量。现场运行表明，系统稳定性好，抗干扰能力强，超调量小，过渡时间短，实现了工况的自动监测、控制，其精度完全达到预期要求。     

低合金钢亚温淬火强韧化研究

借助扫描电镜，透射电镜，Ｘ射线衍射仪等对低合金钢２７ＳｉＭｎ亚温淬火的强韧机理进行了研究。结果表明，位错强化，固溶强化，细晶强化及铁素体韧化等综合作用合金钢亚温淬火后强韧化效果较好。     

预烧淬火速度对NiCuZn铁氧体性能的影响

采用传统的氧化物法制备NiCuZn铁氧体,预烧保温后采用了三种不同方式冷却,研究了冷却速度对材料微观结构和磁性能的影响。发现随着冷却速度的加快,可获得更好微观结构、更高起始磁导率、更低损耗、更高烧结密度之低温共烧材料。