GH169高温合金主要相分析

用透射电镜对GH169高温合金主要强化相γ′、γ″进行分析观察及稳定相δ的亚结构及有关晶体学的测量计算。结果得出,γ″相具有三种不同位向的变体。利用γ′、γ″在(110)倒易面上超结构斑点重合来同时显现γ′、γ″相。通过迹线分析方法测量得出δ相的亚结构为层错,层错面为。     

2.4GHz和5GHz WLAN干扰对比分析

通过对WLAN干扰机制和干扰类型进行较为详细的理论分析,然后进行了全面的实际测试,得出了2.4 GHz WLAN的干扰较严重,5 GHz WLAN干扰比较小的结论。这一结论为5 GHz WLAN的引入提供了较为有力的依据。     

Two Subgroups within the GH43_36 α-l-Arabinofuranosidase Subfamily Hydrolyze Arabinosyl from Either Mono-or Disubstituted Xylosyl Units in Wheat Arabinoxylan

Fungal arabinofuranosidases (ABFs) catalyze the hydrolysis of arabinosyl substituents (Ara) and are key in the interplay with other glycosyl hydrolases to saccharify arabinoxylans (AXs). Most characterized ABFs belong to GH51 and GH62 and are known to hydrolyze the linkage of α-(1→2)-Ara and α-(1→3)-Ara in monosubstituted xylosyl residues (Xyl) (ABF-m2,3). Nevertheless, in AX a substantial number of Xyls have two Aras (i.e., disubstituted), which are unaffected by ABFs from GH51 and GH62. To date, only two fungal enzymes have been identified (in GH43_36) that specifically release the α-(1→3)-Ara from disubstituted Xyls (ABF-d3). In our research, phylogenetic analysis of available GH43_36 sequences revealed two major clades (GH43_36a and GH43_36b) with an expected substrate specificity difference. The characterized fungal ABF-d3 enzymes aligned with GH43_36a, including the GH43_36 from Humicola insolens (HiABF43_36a). Hereto, the first fungal GH43_36b (from Talaromyces pinophilus) was cloned, purified, and characterized (TpABF43_36b). Surprisingly, TpABF43_36b was found to be active as ABF-m2,3, albeit with a relatively low rate compared to other ABFs tested, and showed minor xylanase activity. Novel specificities were also discovered for the HiABF43_36a, as it also released α-(1→2)-Ara from a disubstitution on the non-reducing end of an arabinoxylooligosaccharide (AXOS), and it was active to a lesser extent as an ABF-m2,3 towards AXOS when the Ara was on the second xylosyl from the non-reducing end. In essence, this work adds new insights into the biorefinery of agricultural residues.     

选区激光熔化成形Inconel 625合金的激光焊接头组织及高温蠕变性能

选区激光熔化的制造过程不可避免地会在构件内部和表面产生缺陷,如何从“合于使用”的角度评价缺陷微观尺度扩展行为对结构寿命周期服役完整性的影响是目前亟需解决的主要问题之一. 为了定量揭示疲劳裂纹萌生行为,借助Tanaka-Mura位错模型描述选区激光熔化成形GH3536合金的疲劳裂纹萌生及短裂纹扩展情况,分析由于缺陷位置、缺陷尺寸和缺陷类型等导致疲劳裂纹的表面和内部萌生的竞争情况. 结果表明,随着缺陷距表面距离的减小或等效缺陷尺寸的增加,疲劳失效模式由表面变为内部失效;选区激光熔化成形GH3536存在对应条件下的损伤容限,当缺陷尺寸较小时,构件的裂纹萌生模式不发生变化,但随着缺陷数量增多,疲劳短裂纹的扩展路径发生多次偏转且萌生寿命明显降低.     

磷对GH169合金组织性能的影响

对不同磷含量5炉GH169(IN718)合金进行力学性能测试及显微组织分析,结果表明,磷具有\     

GH169合金在长期时效过程中组织的稳定性

经电子显微镜观察，ＧＨ１６９合金经５５０℃长期时效后，晶内有盘状γ’相和少量层状δ相。５５０℃５００ｈ时效后，２０℃δｂ为１４５３ＭＲａ，δ０．２为１２４０ＭＰａ，５５０℃１０００ｈ时效后，６５０℃δｂ为１１５３ＭＰａ，δ０．２为１０４０ＭＰａ。     

Creep-fatigue crack growth behavior in GH4169 superalloy

This study aims to examine the crack growth behavior of turbine disc GH4169 superalloy under creep-fatigue loading. Crack growth experiments were performed on compact tension specimens using trapezoidal waveform with dwell time at the maximum load at 650 °C. The crack growth rate of GH4169 superalloy significantly increased with dwell time. The grain boundaries oxidize during the dwell process, thereby inducing an intergranular creep-fatigue fracture mode. In addition, testing data under the same dwell time showed scattering at the crack growth rate. Consequently, a modified model based on the Saxena equation was proposed by introducing a distribution factor for the crack growth rate. Microstructural observation confirmed that the small grain size and high volume fraction of the d phase led to a fast creep-fatigue crack growth rate at 650 °C, thus indicating that two factors, namely, fine grain and presence of the d phase at the grain boundary, increased the amount of weakened interface at high temperature, in which intergranular cracks may form and propagate.     

缺口对GH3536镍基高温合金蠕变性能的影响

针对GH3536镍基高温合金无应力集中和带典型应力集中圆棒试样在160,200,240 MPa应力条件下的高温(750℃)蠕变性能进行了试验和有限元分析,研究了缺口的存在对材料蠕变性能的影响。采用扫描电镜分析了试样断口的形貌,确定了材料的断裂机制。结果表明:缺口的存在对GH3536镍基高温合金试件的蠕变性能影响较大,其降低了试件的最大蠕变应变及在蠕变各个阶段的蠕变速率。缺口对试件的蠕变寿命存在硬化作用,缺口根部轴向应力的再分配和松弛可简单认为是导致缺口对该合金蠕变寿命起硬化作用的影响因素。断口形貌分析表明由于缺口的存在,2种试件的表面形貌虽有不同,但蠕变断裂机理都是由微孔洞不断增大与聚集引起的。     

GH3145合金的研制

在Inconel X-750合金成分的基础上，添加Mg、Zr、B等微量合金元素，研制了GH3145合金，结果表明，在适当的热处理条件下与Inconel X-750合金相比，GH3145合金在500℃-700℃区间的塑性得到改善，并且消除了缺口敏感性，达到了汽轮机紧固件用材料的技术要求。     

不同热处理工艺下GH864合金的组织性能分析

通过对不同热处理工艺条件下的GH864材料的金相组织、性能以及晶界析出物的分析可知,水冷的机械性能优于空冷,1080℃时的硬度较1020℃时高,1080℃时的一次固熔的晶粒较1020℃有所长大。且不同热处理方式对晶界行为的影响不同,但强化相γ′均呈细小弥散状析出。