回收轮胎粉反应增韧PVC性能的研究

将甲基丙烯酸缩水甘油酯(GMA)、丙烯酸(AA)、马来酸酐(MAH)3种不同单体分别通过开炼机剪切加入废旧轮胎粉(GRT)后与聚氯乙烯(PVC)直接反应挤出,制备了3种PVC/GRT复合材料。利用万能电子试验机测定了材料的力学性能,实验结果表明:3种不同单体修饰的GRT/PVC复合材料中PVC/GRTg-GMA复合材料韧性提高显著,在GRT用量为5 phr,GMA、St、DCP用量分别为4、4、0.15 phr时,PVC/GRT复合材料缺口冲击强度提高25.6%。扫描电镜结果显示GMA的加入改善了界面相容性。     

Study on new GMA welding process with duplex current feeding

Gas metal arc welding (GMAW) under pure argon shielding gas atmosphere (pure argon-GMAW) is suitable to obtain a high-strength and high toughness welded joint. However, it is difficult that pure argon-GMA welding is applied practically welding structure because of arc instability. In order to perform stable pure argon-GMA welding, duplex current feeding GMAW (DCF-GMAW) has been developed. The DCF-GMAW consists of primary GMA welding current and secondary welding current by constant-current power resource. DFC-GMAW can feed larger current near wire tip. This effect makes that weld penetration depth is deeper, weld bead shape is improved using DCF-GMAW.     

功能单体对聚合物原位处理木材冲击韧性的改善

针对甲基丙烯酸缩水甘油酯(GMA)单体原位聚合处理木材存在脆性较大的缺点,选择具有柔性链段的乙二醇二甲基丙烯酸酯(EGDMA)对之进行增韧改性.采用GMA和EGDMA混合单体溶液浸注木材,再通过加热聚合方式制备木材-GMA-EGDMA复合材料.利用扫描电子显微镜、红外光谱仪和X射线衍射仪观察与分析木材-GMA-EGDMA复合材料的微观形貌、组分特征和聚合物的聚集态;借助冲击韧性试验机测试分析木材-GMA-EGDMA复合材料的冲击韧性.结果表明:GMA+EGDMA单体在木材细胞腔中原位聚合成聚合物,并以无定形态均匀填充木材细胞腔;聚合物与木材基质间存在相对较强的黏结力;聚合物的冲击断面呈典型的韧性断裂特征.木材-GMA-EGDMA复合材料的冲击韧性较木材素材和GMA单体原位聚合处理木材分别提高了98%和220%.     

Synthesis and characterization of binary copolymers of methyl methacrylate with glycidyl methacrylate and 2‐hydroxy ethyl methacrylate as carriers for cellulase

Cellulase was immobilized directly on methyl methacrylate‐glycidyl methacrylate copolymer (MMA‐co‐GMA) and methyl methacrylate‐2‐hydroxy ethyl methacrylate copolymer (MMA‐co‐HEMA) by covalent attachment and crosslinking methods. The properties of the immobilized cellulase were investigated and compared with those of the free one. For the assays carried out through crosslinking method at 25°C and pH 7, the retained activities were found to be 91.92% and 74.63%, respectively, for MMA‐co‐GMA and MMA‐co‐HEMA crosslinked with 0.1% of 1‐cyclohexyl‐3‐(2‐morpholino‐ethyl) carbodiimide metho‐p‐toluenesulfonate (CMCT), respectively. The immobilized cellulase had better stability and higher retained activities with respect to pH, temperature, and storage stability than the free one. In the repeated use experiments, the immobilized cellulase using (MMA‐co‐GMA)‐CMCT (0.1%) and (MMA‐co‐HEMA)‐CMCT (0.1%) did not change after 10 and eight times of repeated use and maintained 67% and 62% from their original activities after 25 times, respectively. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Research on droplet transfer in oscillating arc narrow gap GMA welding

In this paper, the droplet transfer in oscillating arc narrow gap gas metal arc （ GMA ） welding was studied. According to the experimental results, the oscillating arc has effect on the droplet transfer mode. The droplet transfer frequency in narrow gap groove is higher than that in bead-on-plate welding. Because of the change of arc location in narrow gap groove, the droplet transfer in oscillating arc narrow gap changes regularly. The droplet transfer frequency near groove sidewall is higher than that at the middle of narrow gap groove.     

应用于自动化设备的超磁致伸缩微位移驱动器的研究

设计了一种利用超磁致伸缩材料的驱动器并对其结构和工作原理进行说明,在此基础上建立所研制驱动器的数学模型,进行时域和频域特性分析,由于存在位置误差,设计了PID控制器进行校正,得出控制器的有效控制效果,表明了设计的超磁致伸缩驱动器的合理性。     

Human serum albumin adsorption on poly[(glycidyl methacrylate)‐co‐(methyl methacrylate)] beads modified with a spacer‐arm‐attached L‐histidine ligand

Poly(GMA/MMA) beads were synthesized from glycidyl methacrylate (GMA) and methyl methacrylate (MMA) in the presence of a cross‐linker (i.e. ethyleneglycol dimethacrylate) (EGDMA) via suspension polymerization. The epoxy groups of the poly(GMA/MMA) beads were converted into amino groups with either ammonia or 1,6‐diaminohexane (i.e. spacer‐arm). An L ‐histidine ligand was then covalently immobilized on the aminated (poly(GMA/MMA)‐AH) and/or the spacer‐arm attached (poly(GMA/MMA)‐SAH) beads using glutaric dialdehyde as a coupling agent. Both affinity adsorbents were used in human serum albumin (HSA) adsorption/desorption studies under defined pH, ionic strength or temperature conditions in a batch reactor. The spacer‐arm attached affinity adsorbent resulted in an increase in the adsorption capacity to HSA when compared to the aminated counterpart (i.e. poly(GMA/MMA)‐AH). The maximum adsorption capacities of the affinity adsorbents were found to be significantly high, i.e. 43.7 and 80.2 mg g^?1 (of the beads), while the affinity constants, evaluated by the Langmuir model, were 3.96 × 10^?7 and 9.53 × 10^?7 mol L^?1 for poly(GMA/MMA)‐AH and poly(GMA/MMA)‐SAH, respectively. The adsorption capacities of the affinity adsorbents were decreased for HSA by increasing the ionic strength, adjusted with NaCl. The adsorption kinetics of HSA were analysed by using pseudo‐first and pseudo‐second‐order equations. The second‐order equation fitted well with the experimental data. Copyright © 2005 Society of Chemical Industry     

A comparative study of softeners and catalyst systems upon dimensional changes and sectioning quality of glycol methacrylate sections

It is shown that softeners and temperature have an important influence upon the stretching parameters of glycol methacrylate sections. Also it is demonstrated that the catalyst system used may significantly interfere with section stretching.     

HDPE-g-GMA对PA6/UHMWPE共混物性能的影响

采用自制甲基丙烯酸缩水甘油酯接枝高密度聚乙烯(HDPE-g-GMA)作为增容剂来增容尼龙6/超高分子量聚乙烯(PA6/UHMWPE)共混物。通过Molau试验、红外光谱分析、扫描电子显微镜观察和物理力学性能测试,研究了HDPE-g-GMA在熔融共混过程中对PA6/UHMWPE共混物的增容作用。结果表明,HDPE-g-GMA与PA6发生化学反应所生成的接枝聚合物对PA6/UHMWPE共混物有较好的增容作用;PA6/UHMWPE共混物的界面形态和力学性能均有较大改善．吸水率也有所降低。     

A new,less toxic polymerization system for the embedding of soft tissues in glycol methacrylate and subsequent preparing of serial sections

The paper describes a new polymerization system for embedding soft tissues in glycol methacrylate (GMA). The polymerization of GMA is initiated by means of a barbituric acid derivative in combination with chloride ions and dibenzoyl peroxide. The catalyst system contains no aromatic amines which constitutes a toxicological advantage over the commonly employed system of peroxide/aromatic amine. Clear blocks are obtained from which 1–2 μm sections are easy to cut. In combination with an appropriate softener, polyethylene glycol 400 , serial sectioning may be practised.