全文获取类型
收费全文 | 18443篇 |
免费 | 1615篇 |
国内免费 | 1538篇 |
专业分类
电工技术 | 753篇 |
综合类 | 2518篇 |
化学工业 | 1711篇 |
金属工艺 | 1649篇 |
机械仪表 | 1031篇 |
建筑科学 | 1386篇 |
矿业工程 | 412篇 |
能源动力 | 828篇 |
轻工业 | 673篇 |
水利工程 | 673篇 |
石油天然气 | 748篇 |
武器工业 | 144篇 |
无线电 | 1370篇 |
一般工业技术 | 3416篇 |
冶金工业 | 731篇 |
原子能技术 | 206篇 |
自动化技术 | 3347篇 |
出版年
2024年 | 54篇 |
2023年 | 272篇 |
2022年 | 332篇 |
2021年 | 478篇 |
2020年 | 529篇 |
2019年 | 497篇 |
2018年 | 437篇 |
2017年 | 491篇 |
2016年 | 534篇 |
2015年 | 497篇 |
2014年 | 781篇 |
2013年 | 1049篇 |
2012年 | 1055篇 |
2011年 | 1321篇 |
2010年 | 920篇 |
2009年 | 1045篇 |
2008年 | 1158篇 |
2007年 | 1271篇 |
2006年 | 1229篇 |
2005年 | 1044篇 |
2004年 | 910篇 |
2003年 | 815篇 |
2002年 | 657篇 |
2001年 | 574篇 |
2000年 | 569篇 |
1999年 | 459篇 |
1998年 | 412篇 |
1997年 | 375篇 |
1996年 | 347篇 |
1995年 | 271篇 |
1994年 | 235篇 |
1993年 | 182篇 |
1992年 | 174篇 |
1991年 | 146篇 |
1990年 | 129篇 |
1989年 | 110篇 |
1988年 | 79篇 |
1987年 | 37篇 |
1986年 | 24篇 |
1985年 | 11篇 |
1984年 | 15篇 |
1983年 | 13篇 |
1982年 | 8篇 |
1981年 | 14篇 |
1980年 | 4篇 |
1979年 | 4篇 |
1976年 | 3篇 |
1974年 | 3篇 |
1955年 | 5篇 |
1954年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
11.
12.
Mingzhi Zhao Jianwei Cao Zhi Wang Guohua Li 《Journal of the European Ceramic Society》2019,39(7):2427-2435
The crystallization phenomena of spinel in CaO-MgO-Al2O3-SiO2-Fe2O3 glass have received much attention due to the particular role in preparation of glass-ceramic materials, which represent an effective option to manage hazardous waste. In this study, both preliminary spinel and secondary spinel were precipitated in the precursor glass. The formation of these spinel was meticulously assessed by a combination of X-ray diffractometry and scanning electron microscopy. The structure of the microenvironment in the precursor glass was characterized by Raman spectrums. These advanced techniques highlight the potential for one-step crystallization of the glass. The investigation, which focused on one-step crystallization, demonstrated the growth of pyroxene on spinel accompanying a migration of chromium. The results also show the microstructure of the obtained glass-ceramic was very dependent on the heat-treat temperature. This study not only unambiguously reveals the precipitation mechanisms of spinel but also provides more documentation for one-step crystallization in the glass-ceramics field. 相似文献
13.
《Journal of the European Ceramic Society》2020,40(9):3437-3444
xBi2/3Cu3Ti4O12/(1-x)CaCu3Ti4O12 composites were prepared by traditional solid-state reaction method. Extremely high nonlinear coefficient of 25 and breakdown field of 18.92 kV·cm−1 were obtained in small current range of 0.1−1 mA·cm-2. In addition, reduced dielectric loss of 0.055 was achieved with high dielectric constant of 1369. Optimized nonlinear and dielectric properties were integrated to make the composites a promising dual-function varistor-capacitor candidate. Microstructure analysis discovered two areas with various Bi/Ca ratio, designated as Bi-H and Bi-L respectively. It was found that the maximum ratio of Bi-H/Bi-L heterogeneous interface corresponded to optimized nonlinear and dielectric performance, which was associated with elevated potential barrier height and huge grain boundary resistance. Combined with relaxation analysis, a core-shell structure was proposed to elaborate microstructure evolution in xBi2/3Cu3Ti4O12/(1-x)CaCu3Ti4O12 composite. According to the core-shell model, variation of heterogeneous interface was illustrated on how to influence nonlinear properties, which was well fitted to experimental results. 相似文献
14.
《Ceramics International》2020,46(8):11846-11853
Cr2AlC and its composites containing α-Al2O3 (6.1 and 15.2 wt %) were prepared by hot pressing and their corrosion behaviors in air-saturated 3.5 wt % NaCl aqueous solution were investigated by electrochemical testing methods. It was revealed that the secondary phase of Al2O3 particles mainly distributed along grain boundaries of Cr2AlC matrix. The potentiodynamic polarization measurements showed that the corrosion current densities of these Cr2AlC composites were lower than that of the pure Cr2AlC. The Aluminum in Cr2AlC was prone to be attacked more easily. When immersed at open circuit potential (OCP), Al readily slipped out from Cr2AlC matrix into NaCl solution in the form of dissoluble species. But in the case of polarization, regardless of potentiostatic polarization or potentiodynamic polarization, more de-intercalated Al, reacted with the electrolyte to form corrosion products of Al2O3 and/or AlOOH and deposited on the sample surface. For Cr2AlC/α-Al2O3 composites, the presence of Al2O3 weakened the corrosion along grain boundaries by partly blocking the permeation of electrolyte and inhibiting the anodic dissolution process. 相似文献
15.
《Ceramics International》2021,47(22):31329-31336
Traditional inorganic materials exhibit rigidity owing to the lack of polymer chains in polymer materials or atom slipping in metals. However, nanometerization has been recently proposed for the conversion of inorganic oxide materials into flexible materials. Herein, the flexible inorganic luminescent material, CaTiO3:0.2%Pr3+, was synthesized through electrospinning, and the macroscopic flexibility of pure inorganic CaTiO3:0.2%Pr3+ was achieved. The flexible membrane was characterized via X-ray diffraction, thermogravimetry, scanning electron microscopy (SEM), and photoluminescence analyses. The grain size was analyzed at various calcination temperatures via SEM, and the results suggested that the increase in the calcination temperature resulted in the growth of crystal grains. Studies have reported that the growth of crystal grains is beneficial for improving the luminescence performance; however, to obtain better flexibility, smaller crystal grains are required. This study provides an important reference for the design of flexible inorganic materials. 相似文献
16.
Maria Yousaf Lodhi Muhammad Azhar Khan Majid Niaz Akhtar Muhammad Farooq Warsi Asif Mahmood Shahid M. Ramay 《Ceramics International》2018,44(3):2968-2975
The influence of neodymium and nickel substitution on structural and dielectric parameters was investigated in strontium-barium X-type hexagonal ferrites having composition SrBaCu2?xNixNdyFe28?yO46 (x = 0, 0.2, 0.4, 0.6, 0.8, 1 and y = 0, 0.02, 0.04, 0.06, 0.08, 0.1). Sol-gel method was employed for synthesizing these hexagonal ferrites. The XRD plots of all studied materials which were annealed at 1250 °C show single phase characteristics. Lattice parameter ‘c’ increased as a consequence of larger radius of rare earth ion (Nd3+) as compared to (Fe3+), while lattice parameter ‘a’ showed very small variation. The cell volume was obtained in the range 2508.32–2523.75 (Å3). The inclusion of Nd-Ni also affected X-ray density, bulk density and porosity. The FTIR spectroscopy indicated the particular absorption peaks of hexagonal ferrites and it was performed in the range of 500–700 cm?1. On account of Nd-Ni doping, the dielectric constant, dielectric loss and AC-conductivity showed decreasing trend. The occupancy of Nd3+ ions at octahedral site impedes the valence alternation of Fe3+; therefore there was decrease in dielectric permittivity. Ac conductivity has been decreased from 9.14 to 6.49 (Ω cm)?1 at frequency of 2.7 GHz. The Cole-Cole plots of synthesized materials noticeably revealed grain boundary contribution. The appearance of single semi-circle in impedance Cole-Cole graphs confirms the exceptional role of grain boundaries in the conduction process. The considerably lower dielectric parameters of investigated nano X-type ferrites propose their feasibility for high-frequency applications (phase shifters, dielectric resonators, stealth technology etc). 相似文献
17.
Mohan B. Ponnuchamy G. Mohan Muralikrishna Venkateswara Rao Mannava G. Srinivas Reddy 《Ceramics International》2018,44(13):15019-15023
Nanocrystalline nickel oxide (NiO) was prepared from nickel hydroxide by Spark plasma sintering (SPS) and the mechanisms involved in the densification of NiO were studied. Reverse precipitated nickel hydroxide powders were SPS processed at 400, 600 and 700?°C with 70?MPa pressure. Pure NiO with 12?nm crystallite size formed after 400?°C sintering process. However NiO grains had grown to 18 and 38?nm after 600 and 700?°C sintering respectively. NiO pellets prepared using 600 and 700?°C SPS sintering schedules had relative densities of 83% and 94% respectively. Two displacement rate regimes were observed during densification of NiO in both 600 and 700?°C sintering processes. Decomposition of nickel hydroxide and particle sliding of NiO led to first displacement rate maximum while inverse Hall-Petch based plastic deformation facilitated densification during the constant second displacement rate regime. No densification occurred during sintering holding times indicating the limited role that diffusion played during densification. 相似文献
18.
19.
Seyed Ali Maghami 《热应力杂志》2015,38(2):250-270
Thermal bending analysis of doubly curved laminated shell panels with general boundary conditions and laminations is presented. The equations of equilibrium are derived in the form of two coupled sets of ordinary differential equations based on a general shell theory and solved through the state-space approach in a repeated manner. It is depicted that the results of the present method are in great agreement with analytical solutions. Cylindrical shell panels with general boundary conditions and laminations, where no analytical solution is available, are solved. It is found that the present method exhibits a high convergence rate as well as presenting accurate results in all cases. 相似文献
20.
In this study, we have proposed an automated classification approach to identify meaningful patterns in wind field data. Utilizing an extensive simulated wind database, we have demonstrated that the proposed approach can identify low‐level jets, near‐uniform profiles, and other patterns in a reliable manner. We have studied the dependence of these wind profile patterns on locations (eg, offshore vs onshore), seasons, and diurnal cycles. Furthermore, we have found that the probability distributions of some of the patterns depend on the underlying planetary boundary layer schemes in a significant way. The future potential of the proposed approach in wind resource assessment and, more generally, in mesoscale model parameterization improvement is touched upon in this paper. 相似文献