水利工程模型试验计算机测量与控制系统

采用计算机测量与控制系统应用于水利工程模型试验,设计应用先进的水流循环系统、电磁流量计、电子式电动调节阀、控制接口和软件组成计算机流量闭环自动控制系统;计算机测量与控制系统通过实际使用运行,证明达到了设计指标的要求,大大提高了模型试验测量与控制的精度和工作效率,缩短了模型试验周期,有利于水利工程研究成果质量和科研水平的提高.     

O2,金属电极/YSZ界面的电化学研究

本文利用交流阻抗和直流极化的电化学方法，比较了200～500℃氧在Pt、Ag、Au、Ag－Pd四种化学镀电极上的扩散，350～600℃氧在金属电极／YSZ界面的电化学反应速度以及阴阳电荷传递系数；计算了350～600℃四种电极的界面阻抗；研究了400℃时O2在Ag－Pd电极界面的交换电流密度Io与氧分压Po2的定量关系．     

建筑垃圾界面膜化对水泥砂浆强度的影响

本文设置了不同的再生集料替代率,和不同的处理方式,并对试验结果进行了对比和分析,研究了垃圾界面膜化对砂浆强度的影响。结果表明,在取代率相同的情况下,再生骨料经过处理以后其强度最大增加25％,而且随着垃圾砂掺量的增加,砂浆强度呈现出总体下降的趋势。     

Modeling of multi-inclusion composites with interfacial imperfections:Micromechanical and numerical simulations

A micromechanical approach based on a two-layer built-in model and a numerical simulation based on boundary element method are proposed to predict the effective properties of the multi-inclusion composite with imperfect interfaces.The spring model is introduced to simulate the interface imperfection.These two methods are compared with each other,and good agreement is achieved.The effects of interface spring stiffness,volume ratio and stiffness of inclusions on the micro-and macro-mechanical behaviors of fib...     

碳酸亚乙烯酯添加剂对锂离子电池性能的影响

用循环伏安(CV)、恒电流充放电(GC)、扫描电镜(SEM)以及傅里叶红外光谱(FT-IR)方法研究了添加剂碳酸亚乙烯酯(VC)对锂离子电池负极界面膜性质及电池循环性能的影响。研究表明,在首次充电过程中VC参与了SEI膜的形成,形成的膜主要成分为Li2CO3以及VC的还原聚合物。充放电实验结果表明电解液中加入少量VC能显著提高电池的初始放电容量,电池的循环稳定性也有所提高。     

浅谈核电设计的接口管理

以广东某核电工程为例,阐明了设计过程中接口的有效管理的重要作用,简要介绍了在核电工程设计中应用接口控制手册(ICM)进行设计接口的管理的特点.同时就目前接口管理的实施情况及在后续的核电工程设计中如何更有效的进行接口管理,提出了几点建议和看法.     

电力通信标准信息服务平台的需求和构想

文章以体现电力通信专业特色为主线,对建立各单位通信专业共享的、统一的、标准检索／管理／维护一体化信息服务平台的建设进行了目标分析、需求分析和功能分析。重点探讨了平台的安全策略、数据库架构、跨平台检索、界面设计、服务和管理等方面的内容,希望能为电力通信专业标准化活动和电力通信标准信息服务平台的建设工作提供决策参考。     

Stabilizing Polymer–Lithium Interface in a Rechargeable Solid Battery

Solid polymer electrolytes (SPEs) are promising candidates for developing high‐energy‐density Li metal batteries due to their flexible processability. However, the low mechanical strength as well as the inferior interfacial regulation of ions between SPEs and Li metal anode limit the suppress ion of Li dendrites and destabilize the Li anode. To meet these challenges, interfacial engineering aiming to homogenize the distribution of Li⁺/electron accompanied with enhanced mechanical strength by Mg₃N₂ layer decorating polyethylene oxide is demonstrated. The intermediary Mg₃N₂ in situ transforms to a mixed ion/electron conducting interlayer consisting of a fast ionic conductor Li₃N and a benign electronic conductor Mg metal, which can buffer the Li⁺ concentration gradient and level the nonuniform electric current distribution during cycling, as demonstrated by a COMSOL Multiphysics simulation. These characteristics endow the solid full cell with a dendrite‐free Li anode and enhanced cycling stability and kinetics. The innovative interface design will accelerate the commercial application of high‐energy‐density solid batteries.     

Plasmon‐Induced Hot Carrier Separation across Dual Interface in Gold–Nickel Phosphide Heterojunction for Photocatalytic Water Splitting

Precise control of the topology of metal nanocrystals and appropriate modulation of the metal–semiconductor heterostructure is an important way to understand the relationship between structure and material properties for plasmon‐induced solar‐to‐chemical energy conversion. Here, a bottom‐up wet chemical approach to synthesize Au/Ni₂P heterostructures via Pt‐catalyzed quasi‐epitaxial overgrowth of Ni on Au nanorods (NR) is presented. The structural motif of the Ni₂P is controlled using the aspect ratio of the Au NR and the effective micelle concentration of the C₁₆TAB capping agent. Highly ordered Au/Pt/Ni₂P nanostructures are employed as the photoelectrocatalytic anode system for water splitting. Electrochemical and ultrafast absorption spectroscopy characterization indicates that the structural motif of the Ni₂P (controlled by the outer‐shell deposition of Ni) helps to manipulate hot electron transfer during surface plasmon decay. With optimized Ni₂P thickness, Pt‐tipped Au NR with an aspect ratio of 5.2 exhibits a geometric current density of 10 mA cm^?2 with an overpotential of 140 mV. The photoanode displays unprecedented long‐term stability with continuous chronoamperometric performance of 50 h at an input potential of 1.5 V with over 30 days. This work provides definitive guidance for designing plasmonic–catalytic nanomaterials for enhanced solar‐to‐chemical energy conversion.     

Achieving Rich and Active Alkaline Hydrogen Evolution Heterostructures via Interface Engineering on 2D 1T‐MoS2 Quantum Sheets

Large‐scale production of hydrogen from water‐alkali electrolyzers is impeded by the sluggish kinetics of hydrogen evolution reaction (HER) electrocatalysts. The hybridization of an acid‐active HER catalyst with a cocatalyst at the nanoscale helps boost HER kinetics in alkaline media. Here, it is demonstrated that 1T–MoS₂ nanosheet edges (instead of basal planes) decorated by metal hydroxides form highly active ${\text{edge}}_{{\text{1T‐MoS}}_{\text{2}}}$/ ${\text{edge}}_{\text{Ni}{(\text{OH})}_{\text{2}}}$ heterostructures, which significantly enhance HER performance in alkaline media. Featured with rich ${\text{edge}}_{{\text{1T‐MoS}}_{\text{2}}}$/ ${\text{edge}}_{\text{Ni}{(\text{OH})}_{\text{2}}}$ sites, the fabricated 1T–MoS₂ QS/Ni(OH)₂ hybrid (quantum sized 1T–MoS₂ sheets decorated with Ni(OH)₂ via interface engineering) only requires overpotentials of 57 and 112 mV to drive HER current densities of 10 and 100 mA cm^?2, respectively, and has a low Tafel slope of 30 mV dec^?1 in 1 m KOH. So far, this is the best performance for MoS₂‐based electrocatalysts and the 1T–MoS₂ QS/Ni(OH)₂ hybrid is among the best‐performing non‐Pt alkaline HER electrocatalysts known. The HER process is durable for 100 h at current densities up to 500 mA cm^?2. This work not only provides an active, cost‐effective, and robust alkaline HER electrocatalyst, but also demonstrates a design strategy for preparing high‐performance catalysts based on edge‐rich 2D quantum sheets for other catalytic reactions.