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排序方式: 共有2192条查询结果,搜索用时 171 毫秒
51.
Discontinuous mass-change measurements and corrosion-product analyses were made for Fe-20Cr and Ni-20Cr alloys after exposing them to Ar-H
2
O-HBr gas mixtures at 1000 K for 24 hours. Predominantly chromia scales formed on both alloys. Upon cooling, the scales remained adherent to the Fe-20Cr alloy but spalled extensively from Ni-20Cr samples. After tests in HBr-rich gas mixtures, bromine-rich corrosion products were found underneath chromia scales on both alloys while nickel evaporation was observed from Ni-20Cr samples. Preoxidation of the Ni-20Cr alloy prior to exposure to Ar-H
2
O-HBr gas mixtures increased chromia scale adherence but did not prevent nickel loss from the alloy. Chromia scales formed on the Fe-20Cr alloy were more protective due to the absence of iron oxides in the scale. Large NiO crystals formed over the Ni-20Cr alloy decreased chromia-scale adherence and increased nickel loss from the alloy due to the low stability of NiO in HBr-containing gas mixtures. 相似文献
52.
F~-对钛在NaBr水溶液中阳极极化行为的影响 总被引:1,自引:0,他引:1
利用电化学方法研究了F对工业纯钛(TAl)在NaBr水溶液中阳极极化行为的影响。结果发现,F加速了钛表面膜的阳极溶解速度,减缓了膜的增厚,提高了孔蚀电位,但对再钝化电位无影响。 相似文献
53.
Ping Cai Ling Ding Ziming Chen Dianhui Wang Hongliang Peng Changlai Yuan Chaohao Hu Lixian Sun Yuriy N. Luponosov Fei Huang Qifan Xue 《Advanced functional materials》2023,33(30):2300113
2D Ti3C2Tx MXene, possessing facile preparation, high electrical conductivity, flexibility, and solution processability, shows good application potential for enhancing device performance of perovskite solar cells (PVSCs). In this study, tetrabutylammonium bromide functionalized Ti3C2Tx (TBAB-Ti3C2Tx) is developed as cathode buffer layer (CBL) to regulate the PCBM/Ag cathode interfacial property for the first time. By virtue of the charge transfer from TBAB to Ti3C2Tx demonstrated by electron paramagnetic resonance and density functional theory, the TBAB-Ti3C2Tx CBL with high electrical conductivity exhibits significantly reduced work function of 3.9 eV, which enables optimization of energy level alignment and enhancement of charge extraction. Moreover, the TBAB-Ti3C2Tx CBL can effectively inhibit the migration of iodine ions from perovskite layer to Ag cathode, which synergistically suppresses defect states and reduce charge recombination. Consequently, utilizing MAPbI3 perovskite without post-treatment, the TBAB-Ti3C2Tx based device exhibits a dramatically improved power conversion efficiency of 21.65% with significantly improved operational stability, which is one of the best efficiencies reported for the devices based on MAPbI3/PCBM with different CBLs. These results indicate that TBAB-Ti3C2Tx shall be a promising CBL for high-performance inverted PVSCs and inspire the further applications of quaternary ammonium functionalized MXenes in PVSCs. 相似文献
54.
Jan Kapa?a 《Calphad》2011,35(2):219-223
The thermodynamic properties of ABr-PrBr3(A=Li-Cs) systems were assessed by the CALPHAD method. The liquid phase in the systems was described by the non-stoichiometric associate model. The entropies of mixing in the liquid were evaluated from experimental liquidus and enthalpy of mixing data. For the pseudobinary compounds A3PrBr6,APr2Br7, and A2PrBr5 (A=K,Rb) and Cs3PrBr6 and CsPr2Br7, the dependences of Gibbs energies of formation on temperature were calculated. The anomalies of sequences of thermodynamic properties in RbBr-PrBr3 were observed and discussed. The nature of the liquid phase and precision of calculations of the Rb2PrBr5(s) compound were discussed. 相似文献
55.
56.
以溴代正丁烷与N-甲基咪唑为原料,利用微波法合成咪唑类离子液体1-丁基-3-甲基咪唑溴盐([Bmim]Br),考查设定温度、微波功率、反应时间及原料摩尔比对产品收率的影响.实验结果表明较优的实验条件为:设定温度120℃,微波功率400 W,反应时间15 min,n(N-甲基咪唑)∶n(溴代正丁烷)=1∶1.1;收率为98.81%.产品结构经红外光谱、核磁氢谱确证.并对1-丁基-3-甲基咪唑溴盐的吸水性及溶解性进行测试. 相似文献
57.
Mahendra Nath Roy Bhoj Bahadur Gurung Vikas Kumar Dakua 《International Journal of Thermophysics》2006,27(5):1539-1550
Electrolytic conductivities of potassium halides, KX (X = Cl−, Br−, I−) have been investigated in 10, 20, and 30 mass% glycerol + H2O mixtures at 298.0, 308.0, and 318.0 K. The conductance data have been analyzed by the Fuoss-conductance–concentration equation in terms of the limiting molar conductance (Λ0), the association constant (K
A
), and the distance of closest approach of ion (R). The association constant (K
A
) tends to increase in the order: 10 mass% < 20 mass% < 30 mass% glycerol + water mixtures, while it decreases with temperature. Thermodynamic parameters ΔH
0, ΔG
0, and ΔS
0 are obtained and discussed. Also, Walden products (Λ0η) are reported. The results have been interpreted in terms of ion–solvent interactions and structural changes in the mixed solvents. 相似文献
58.
A new method for the determination of DNA was developed with azocarmine G(AG) in the presence of cetyltrimethylammonium bromide(CTAB) by the resonance light scattering (RLS) technique. The synthetic samples were determined with satisfactory results, and the reaction mechanism was also studied. The results show that under the optimum conditions, the weak RLS signal of AG can be enhanced by DNA, which results from the formation of a new ternary complex AG-CTAB-DNA with large size. Moreover, the enhanced RLS intensity at 552 nm is directly proportional to the concentration of DNA in the range of 0 - 1.0 μg/mL for fish sperm DNA (fsDNA) and 0 - 1.5μg/mL for calf thymus DNA (ctDNA). Based on this, a new assay of DNA can be established. The detection limits (3σ) are 2. 1 ng/mL for fsDNA and 2.2 ng/mL for ctDNA, respectively. 相似文献
59.
塑料换热技术在溴化锂吸收式制冷机上的应用展望 总被引:6,自引:0,他引:6
溴化锂吸收式制冷机在工业中有着广泛的应用,但换热装置腐蚀及其引起的冷量衰减一直以来是人们难以解决的问题.根据现有的溴化锂吸收式制冷机组的性能,结合塑料换热装置的一些特点,提出了采用塑料换热装置代替金属换热装置来解决溴化锂吸收式制冷机的这个难题;并以研制一台制冷量为3.49×104W的溴化锂吸收式制冷机组为例,对塑料换热装置的溴化锂吸收式制冷机组与传统金属溴化锂吸收式制冷机组相关部件的参数进行比较.通过对溴化锂吸收式制冷机组的传热面积、管道阻力的计算和安全强度的校核,发现塑料换热装置应用在溴化锂吸收式制冷机上是可行的,塑料换热技术在溴化锂吸收式制冷机上有着较好的应用前景. 相似文献
60.
Temperature–entropy (T–s) diagrams have the unique capability of being able to quantify processes in terms of both the first and second laws of thermodynamics. Although use of generalised T–s diagrams has been made to indicate or represent generalised absorption cycles, with the exception for NH3/water systems, these diagrams have not been specifically tailored to scale to quantify LiBr/water systems. The main barrier for this is that the diagram needs to represent the necessary properties of both the refrigerant (water) and of the solution (LiBr/water). This paper describes the use of the T–s diagram of water extended with additional curves to represent real and ideal LiBr/water absorption cycles. An explanation is provided on several methods available, including details of the thermodynamic justification of the method that was used, to construct the extended diagrams. Finally, the extended T–s diagram is provided with the representation of a real single-effect LiBr/water absorption refrigeration cycle. This should prove to be a valuable tool for design and research engineers to study and optimise LiBr/water chillers. 相似文献