Diamino telechelic polybutadienes for solventless styrene-butadiene-styrene (SBS) triblock copolymer formation

High molecular weight, high functionality diamino telechelic polybutadienes (TPBs) were synthesized by ring-opening metathesis polymerization (ROMP) of 1,5-cyclooctadiene (COD) in the presence of a chain transfer agent, 1,8-dicyano-4-octene, followed by lithium aluminum hydride reduction. Melt coupling of diamino TPB with anhydride-terminated polystyrene (PS-anh) resulted in the formation of styrene-butadiene-styrene (SBS) triblock copolymers; ca. 80% maximum conversion of PS-anh was achieved within 30 s. The results from SAXS, TEM, and rheological measurements of the coupling products confirmed the formation of SBS triblock copolymers having lamellar morphology. A fluorescent-labeled PS-anh was used to study the coupling kinetics by diluting the reactants by the addition of non-functional PS.     

Integration of batching and scheduling for hot rolling production in the steel industry

This paper investigates the hot rolling production scheduling problem in the steel industry and proposes a new mixed integer programming model for this problem based on the monolithic modeling strategy that integrates batching and scheduling. Using this strategy, the new model can simultaneously schedule multiple turns and simultaneously determine the production timetable of these turns in a global optimal view. A long-term tabu search heuristic using frequency-based memory is developed to obtain near-optimal solutions for this problem. Three kinds of speed-up strategies are developed to accelerate the search procedure of the proposed tabu search. A practical scheduling system combining the proposed mathematical model and the tabu search heuristic has been developed and tested on instances collected from practical production data. The experimental results show that the proposed mathematical model and the tabu search heuristic outperform both the current manual scheduling method and the traditional serial method.     

Thermal and thermoelastic properties of fast extrusion furnace (FEF) carbon black loaded SBR vulcanizates

The effect of FEF carbon black as filler on the thermal capacity c, diffusivity a, and thermal conductivity λ, of styrene butadiene rubber (SBR) composites in the temperature range 300–420 K was studied. The filler strongly increases the thermal diffusivity, whilst strongly decreasing the thermal capacity and the thermal conductivity (except at high FEF content ≥80 phr). The influence of the filler on the thermoelastic behaviour of the same composites was also investigated. It was found that the thermoelastic temperature change (ΔT) increased with carbon black concentration as well as the entropy change per unit extension.     

堆底熔穿事故的场外后果及其对策

在压水堆核电站应急计划和应急响应中，堆底熔穿事故占有重要位置。本文用法国核电厂事故源项Ｓ３（对应于堆底熔穿事故）计算了在典型气象条件下的场外放射学的后果，根据一般防护决策原则和我国颁布的干预水平，提出了保护公众的应急防护措施的建议。     

熔体塔式造粒法生产尿基复混肥

化肥企业生产尿基复混肥对于农业科学施肥、提高肥料利用率、避免环境污染及促进企业产品结构调整都具有十分重要的意义。熔体塔式造粒法生产尿基复混肥较之其它方法优越性更为显著,笔者简要介绍该法的生产机理、工艺流程、技术特点、国内现状及产品市场前景等方面的一些情况。     

玻璃纤维毡增强热塑性复合片材的研制和应用

本文简要介绍了玻璃纤维毡增强聚丙烯片材的研制，性能和应用。     

PET熔体输送系统中熔体温度自动控制方案

在热媒温度控制系统中以熔体温度作为主参数,组成串极调节系统。投入运行后,熔体温度稳定,调节阀动作平稳,效果良好。     

PVC发泡制品用助剂--优泡剂

分析了PVC发泡制品成型加工时存在的缺陷,说明了添加优泡剂可弥补PVC发泡制品的缺陷,提高泡孔质量,介绍了优泡剂的品种和使用场合及使用量。     

汽车工业生产用热熔胶膜的研制

介绍了汽车工业生产内装饰复合材料用热熔胶膜的性能及其研制状况。这种热熔胶膜具有使用便捷,高效,生产、使用过程中没有污染的具有热熔胶膜的特长。     

汽车灯用热熔胶的研究及性能表征

介绍了生产汽车灯用热熔胶的各种原料及其在胶粘剂中所起的主要作用，为汽车灯用热熔胶原料的选择提供了参考。还介绍了汽车灯用热熔胶的制备过程和厂家所需的各种性能及其表征方法。通过选择适当的原料及配比，生产出性能优良并具有良好市场前景的产品。