掺入碳纳米管提高聚苯乙炔的导电性研究

用AlCl3作催化剂制备了聚苯乙炔（PPA），采用共混法制备了碳纳米管（CNTs）与PPA的复合材料，并进行了导电性能测试，结果表明，当CNTs含量增加时，复合材料的电导率升高，CNTs含量为3%时是复合材料导电的临界浓度，当CNTs含量达25%时复合材料达极限电导率，比纯的PPA的电导率提高了13个数量级。CNTs/PPA复合材料的导电机理符合导电通道理论。     

Cryogenic thermometry with a common diode: Type BAS16

Cryogenic test experiments often require a large number of temperatures to be monitored. In order to reduce cost, we investigated the feasibility of low-cost common diodes. We chose the Philips BAS16 diode in a type SOT23 package. By means of Stycast 2850FT, these diodes were glued into alumina holders. In total, 20 sensors were assembled and tested. With an excitation current of 100 μA and considering a temperature range from 50 K to room temperature, a quadratic least-squares-fit was obtained: T = 486.1 − 363.7V − 38.3V². All sensors agreed with this fit within an error of 1.3 K.     

Analysis on the thermal and electrical characteristics of impregnating materials for the bifilar winding-type superconducting fault current limiter

The resistive type high temperature superconducting fault current limiter (HTSFCL) limits the fault current with the resistance that generated by fault current. The generated resistance by fault current makes large pulse power which makes the operation of HTSFCL unstable. So, the cryogenic cooling system of the resistive type HTSFCL must diffuse and eliminate the pulse energy very quickly. Although the best way is to make wide direct contact area between HTS winding and coolant as much as possible, HTS winding also need the impregnation layer which fixes and protects it from electromagnetic force. This paper deals with thermal conductivity and dielectric strength of some epoxy compounds for the impregnation of high temperature superconducting (HTS) winding at 77 K. The measured data can be used in the optimal design of impregnation for HTS winding. Aluminar filling increased the thermal conductivity of epoxy compounds. Hardener also affected the thermal conductivity and the dielectric strength of epoxy compounds.     

Preparation of lithium-ion polymer battery using LiNi1/3Co1/3Mn1/3O2 as a cathode material and its electrochemical properties

In this work, LiNi_1/3Mn_1/3Co_1/3O₂ powders were synthesized from co-precipitated spherical metal hydroxide. In the voltage range of 2.8–4.2, 2.8–4.4, and 2.8–4.6 V, the discharge capacities of LiNi_1/3Mn_1/3Co_1/3O₂ electrode were 163, 177, and 193 mAh⋅g⁻¹, respectively. A gel polymer electrolyte (GPE) was also prepared using polyoxyalkylene glycol acrylate (POAGA) as a macromonomer. LiNi_1/3Mn_1/3Co_1/3O₂/GPE/graphite cells were prepared and their electrochemical properties were evaluated at various current densities and temperatures. The ionic conductivity of the GPE was more than 6.2 × 10⁻³ S⋅cm⁻¹ at room temperature. POAGA-based cells were showed good electrochemical performances such as rate capability, low-temperature performance, and cycleability.     

P_2O_5填充的PVDF复合聚合物导电膜的研制与性能研究

以聚偏氟乙烯为基质,加入适量的P2O5,制备了P2O5填充的PVDF复合聚合物质子导电膜,采用交流阻抗谱的方法研究了P2O5的质量分数不同的复合膜的导电性能及相对湿度对电导率的影响.结果表明,该电解质的室温电导率达到10-2 S·cm-1,相对湿度在20%～90%范围内,对电解质的导电性影响不大.     

Sintering and Electronic Conducting Properties of Lao.7Ca0.3CrO3 Perovskite Synthesized by a Glycine-nitrate Process

La0.7 Ca0.3 CrO3 powder consisting of superfine and uniform particles （ 100-200 nm ） were synthesized using a glycine-nitrate process （ GNP ）. The sintering and electronic conducting properties of La0.7 Ca0.3 CrO3 were invetigated in the sintering temperature range of 1 200-1 450 ℃. The desired morphology of the powder significantly improved its sinterability. La0.7 Ca0.3 CrO3 ceramics sintered at 1 250-1 450 ℃ show high relative densities above 95 % . The ceramics sintered at 1 250-1 400 ℃ have very similar electronic conduct- ing properties, providing electronic conductivities around 55 Ω^-1 cm^-1 at a measuring temperature of 800 ℃ . Further increasing the sintering temperature to 1450 ℃ led to an apparent degradation of electronic conducting properties. This research demonstrates the advantage of the GNP in producing La0.7 Ca0.3 CrO3 with respect to the enhanced sintering properties and superior electronic conducting properties.     

基于测量数据优化修匀的特性曲线样条插值方法

针对传感器特性曲线拟合存在的一些问题,提出了测量数据优化修匀思想以有效消除测量数据的随机误差.应用数值处理软件Matlab结合实验数据研究了基于不同修匀方案的特性曲线的三次样条插值表示并提供了可视化的结果.经过对比不难发现,依据优化修匀数据的三次样条插值误差明显减小,可应用于任意类型传感器或其它仪器仪表的特性曲线的描述与分析.     

Coupled mechanics and finite element for non‐linear laminated piezoelectric shallow shells undergoing large displacements and rotations

A theoretical framework is presented for analysing the coupled non‐linear response of shallow doubly curved adaptive laminated piezoelectric shells undergoing large displacements and rotations. The formulated mechanics incorporate coupling between in‐plane and flexural stiffness terms due to geometric curvature, coupling between mechanical and electric fields, and encompass geometric non‐linearity effects due to large displacements and rotations. The governing equations are formulated explicitly in orthogonal curvilinear co‐ordinates and are combined with the kinematic assumptions of a mixed‐field shear‐layerwise shell laminate theory. Based on the above formulation, a finite element methodology together with an incremental‐iterative technique, based on Newton–Raphson method is formulated. An eight‐node coupled non‐linear shell element is also developed. Various evaluation cases on laminated curved beams and cylindrical panels illustrate the capability of the shell finite element to predict the complex non‐linear behaviour of active shell structures including buckling, which is not captured by linear shell models. The numerical results also show the inherent capability of piezoelectric shell structures to actively induce large displacements through piezoelectric actuators, by jumping between multiple equilibrium states. Copyright © 2005 John Wiley & Sons, Ltd.