Mechanism of heterogeneous catalytic ozonation of nitrobenzene in aqueous solution with modified ceramic honeycomb

The degradation efficiencies of nitrobenzene in aqueous solution were investigated by semi-continuous experiments in the processes of ozone alone, ozone/ceramic honeycomb (CH) and ozone/modified ceramic honeycomb (MCH). MCH with 1.0% Mn and 0.5% Cu had more pronounced catalytic ability than CH to accelerate the degradation of nitrobenzene, to increase the utilization efficiency of ozone, to improve the concentrations of hydrogen peroxide (H₂O₂) formation and hydroxyl radical (OH) initiation, and to enhance the removal efficiency of TOC. The modification process of CH with the metals enhanced the density of surface hydroxyl groups, which determines the initiation of OH from ozone decomposition and the generation of intermediate species on heterogeneous catalytic surface, yielding the acceleration of the degradation of nitrobenzene in aqueous solution. Possible reaction mechanism of ozone with heterogeneous catalytic surface in aqueous solution was proposed, and the formation mechanism of H₂O₂ and OH was also discussed according to the combined reactions in heterogeneous and homogeneous catalytic systems.     

Dynamic and static characterization of compact crack arrest tests of navy and nuclear steels

Recent experimental and computational work by Link and associates has demonstrated that relatively small (W = 150 mm) single edge notched tension specimens (SE(T)) can be used to obtain crack arrest data high in the ductile-to-brittle transition of ferritic structural steel using dynamic computational techniques if a thermal gradient is utilized to aid in the crack arrest. Testing has been reported on two important navy structural steels that clearly defines the relative capability of the two materials to arrest rapidly growing cracks. The HY100 material demonstrated the expected large difference between the initiation and crack arrest toughnesses which has made it impossible in the past to measure crack arrest toughness for this material using the standard ASTM procedure (E1221). The HSLA-100 steel, however demonstrated a much higher crack arrest toughness and a correspondingly smaller drop in toughness below the initiation toughness. This small difference between initiation toughness and arrest toughness suggested that the E1221 procedure, using wedge loaded, compact crack arrest (CCA) specimens would be applicable to this material. Two important issues could then be investigated using this material. First, having completed the expensive and relatively complex testing of the SE(T) specimens using tensile loading and a thermal gradient, a second, quite different geometry could be tested using the E1221 procedure, allowing an important comparison between the crack arrest measurements made using these two distinct geometries. Historically, obtaining crack arrest results using one test configuration has been so difficult, that there have been very few reports of results for the same material using two different test geometries. Transferability of the laboratory results to structural applications has thus been a matter of conjecture. Furthermore, if the E1221 CCA specimens were strain gaged to obtain crack velocity data, and analyzed using the dynamic computational procedure used by Link on the SE(T) specimens, it would be possible to compare the results the E1221 static analysis with the results of the dynamic computation procedure to determine the degree of conservatism present in the E1221 standard procedure.The results of this work have shown that the crack arrest toughness results obtained on these two specimen geometries are similar and hence insensitive to the test geometry and the difference resulting from the application of the complex dynamic computational procedure or the E1221 static analyses is small.     

起爆方式对截底椭圆形罩LSC射流成型影响的三维数值模拟

为了研究起爆方式对截底椭圆形罩LSC射流成型性能影响的特点和规律,运用ANSYS/LSDYNA对不同起爆方式下截底椭圆形罩LSC射流成型过程进行了三维数值模拟,获得了不同时刻射流横断面和正面的成型图片、射流最大速度时程曲线和射流最大速度及其出现的时刻。结果表明,对于顶部中线均布多起爆点,两端起爆时差在3μs以内时,形成的射流最大速度较大,约为4260⁴290m/s,成型性能较好,当起爆点数量大于4时,可以认为是顶部中线线起爆;对于两侧棱上均布多起爆点,两端4点同时起爆时形成的射流最大速度较大,约4800m/s,当两侧棱上均布起爆点数量大于6时,可以认为是两侧棱上线起爆;就射流最大速度而言,两侧棱上均布多起爆点普遍大于顶部中线均布多起爆点。因此,起爆方式对LSC射流成型性能影响较大,研究结果在丰富LSC射流成型理论的同时,为实际应用LSC时选择合适的起爆方式提供了参考。     

Multimedia Internet Rekeying for secure session mobility in ubiquitous mobile networks

Session mobility is one of new critical issues in the ubiquitous mobile networking environment. Session mobility provides a user changing its ongoing multimedia session, e.g., Voice-over-Internet Protocol (VoIP), from the currently using device to another by adapting user’s demand. In session Initial Protocol (SIP)-based multimedia services supporting session mobility, SIP serves as a signaling control protocol to negotiate session control, whereas media is transmitted using Real-time Transport Protocol (RTP). For securing multimedia sessions, Multimedia Internet Keying (MIKEY) is embedded in SIP signaling to negotiate security parameters for Secure RTP (SRTP), whereas SRTP is used to protect media stream. Since session mobility allows an ongoing multimedia session to be transferred from one device to another, a new security problem is raised, i.e., sensitive parameters may remain in the previous device when the ongoing multimedia session has been transferred to the current device. Unfortunately, current MIKEY cannot bear the aforementioned security problem in session mobility. Therefore, we propose Multimedia Internet Rekeying (MIRKEY) for session mobility in the ubiquitous mobile networking environment. Although MIKEY can be executed again to carry out the rekeying of the session key and Crypto Session bundle (CSB) update, the sensitive parameters still remain in previous devices. MIRKEY contains a SBK to bind the participated user and multimedia session. Besides, SBK can persist in rekeying based on the key chain whenever a multimedia session is transferred to other devices. As a result, SBK is operative only in the specific device. As a result, MIRKEY can solve the newly raised security problem in session mobility. Furthermore, we verify MIRKEY using Burrows–Abadi–Needham (BAN) logic and realize it in the implemented ubiquitous multimedia service platform (UMSP).     

基于QoS的PQ_SIP协议栈设计

针对某些网络对业务和用户划分优先级的问题,该文基于现有会话初始化协议（SIP）栈设计一种支持服务质量（QoS）的PQ_SIP协议栈,并将其应用于某部人民防空应急通信指挥系统中。实践证明,改进后的协议栈能有效提高终端资源的利用率,体现用户和数据业务的不同优先级,实现对呼叫和会话有差别的控制。     

基于SIP的无线局域网络视频电话系统

未来的电信网络无论是固网还是移动网络都将整合成一个AllIP网络的架构。因此异构网络间的信息如何正确的传递变得尤为重要,SIP协议已成为其中的重要关键技术。目前在有线的因特网上,已有许多通信软件提供了语音服务,而本研究则以SIP为基础在无线局域网络上开发视频电话系统,并设计了客户端代理者接口程序与服务器系统,在无线局域网中实现了基于SIP技术的视频电话系统。     

基于身份的P2PSIP可认证密钥协商方案

为解决点对点会话初始协议(P2PSIP)的安全性问题,根据其分布式特点,结合身份公钥密码,提出一种可认证密钥协商方案。分析其安全性、运算效率和密钥托管等问题。该方案可以实现P2PSIP呼叫过程的双向身份认证和密钥协商,抵抗中间人攻击、重放攻击和离线密码攻击,防止消息体篡改、会话劫持和身份欺骗。     

井下移动SIP通信终端的设计与实现

为实现灵活、畅通、可靠的井下通信,设计一种基于嵌入式Linux的移动会话初始协议(SIP)通信终端。该终端利用SIP作为应用层协议,在流动会话过程中提供对语音连续性的支持。设计一种灵活高效的SIP协议栈,在嵌入式平台下结合无线局域网技术,实现井下实时语音通话功能。实验结果表明,该终端通话质量较好。     

基于PTD2112的VoIP网关的软硬件设计

以往的IP电话设备主要采用H．323协议实现，但是H．323协议实现过程较复杂，在实际使用中存在很多的问题．提出一种基于FFD2112的VoIP网关的实现方法，阐述了基于FFD2112的VoIP网关的软硬件设计过程，电话接口的性能测试结果表明，所提出的方案在因特网上运行良好．     

基于强认证技术的会话初始协议安全认证模型

针对会话初始协议（SIP）的典型安全威胁,提出了基于强认证技术的SIP安全认证模型,并分析了其安全性。该认证模型通过智能卡和数字证书的强组合实现强认证,并据此对SIP做出相应扩展,将强认证技术有机地融入到SIP协议当中,实现了会话双方的安全认证,保证了SIP消息传输的机密性、真实性、完整性和不可否认性,从而提高了SIP的安全性。