Interfacial Oxides Evolution of High-Speed Steel Joints by Hot-Compression Bonding

The interfacial oxidation behavior of Cr4 Mo4 V high-speed steel(HSS) joints undergoing hot-compression bonding was investigated by using optical microscopy(OM),scanning electron microscopy(SEM),and transmission electron microscopy(TEM).In the heating and holding processes,dispersed rod-like and granular δ-Al₂ O₃ oxides were formed at the interface and in the matrix near the interface due to the selective oxidation and internal oxidation of Al,while irregular Si-Al-O compou...     

Stress-function variational method for stress analysis of bonded joints under mechanical and thermal loads

High interfacial stresses near the ends of adherends are responsible for debonding failure of bonded joints used extensively in structural engineering and microelectronics packaging. This paper proposes a stress-function variational method for determination of the interfacial stresses in a single-sided strap joint subjected to mechanical and thermal loads. During the process, two interfacial shear and normal (peeling) stress functions are introduced, and the planar stresses of adherends of the joints are expressed in terms of the stress functions according to the static equilibrium equations. Two coupled governing ordinary differential equations (ODEs) of the stress functions are obtained through minimizing the complementary strain energy of the joints and solved explicitly in terms of eigenfunctions. The stress field of the joints based on this method can satisfy all the traction boundary conditions (BCs), especially the shear-free condition near the adherend ends. Compared to results based on finite element method (FEM) and other analytic methods in the literature, the present variational method is capable of predicting highly accurate interfacial stresses. Dependencies of the interfacial stresses upon the adherend geometries, moduli and temperature are examined. Results gained in this study are applicable to scaling analysis of joint strength and examination of solutions given by other methods. The present formalism can be extended conveniently to mechanical and thermomechanical stress analysis of other bonded structures such as adhesively bonded joints, composite joints, and recently developed flexible electronics, among others.     

Biocomposites from Musa textilis and polypropylene: Evaluation of flexural properties and impact strength

Abaca (Musa textilis)-reinforced polypropylene composites have been prepared and their flexural mechanical properties studied. Due to their characteristic properties, M. textilis has a great economic importance and its fibers are used for specialty papers. Due to its high price and despite possessing very distinctive mechanical properties, to date abaca fibers had not been tested in fiber-reinforced composites. Analysis of materials prepared showed that, in spite of reduced interface adhesion, flexural properties of the PP composites increased linearly with fiber content up to 50 wt.%. Addition of a maleated polypropylene coupling agent still enhanced the stress transfer from the matrix to the reinforcement fiber. As a result, composites with improved flexural properties were obtained. The mechanical properties of matrix and reinforcing fiber were evaluated and used for modelling both the flexural strength and modulus of its composites. In addition, the impact strength of materials was evaluated. Comparison with mechanical properties of composites reinforced with fiberglass points out the potentiality of abaca-reinforced polypropylene composites as suitable substitutes in applications with low impact strength demands.     

High Hole Mobility of GaSb Relaxed Epilayer Grown on GaAs Substrate by MOCVD through Interfacial Misfit Dislocations Array

The structural property of GaSb epilayers grown on semi-insulator GaAs (001) substrate by metalorganic chemical vapor deposition (MOCVD) using Triethylgallium (TEGa) and trimethylantimony (TMSb),was investigated by variation of the Sb:Ga (V/III) ratio.An optimum V/III ratio of 1.4 was determined in our growth conditions.Using transmission electron microscopy (TEM),we found that there was an interfacial misfit dislocations (IMF) growth mode in our experiment,in which the large misfit strain between epilayer and substrate is relaxed by periodic 90 deg.IMF array at the hetero-epitaxial interface.The rms roughness of a 300 nm-thick GaSb layer is only 2.7 nm in a 10 μm×10 μm scan from atomic force microscopy (AFM) result.The best hole density and mobility of 300 nm GaSb epilayer are 5.27×10 6 cm 3 (1.20×10 6) and 553 cm 2 ·V 1 ·s 1 (2340) at RT (77 K) from Hall measurement,respectively.These results indicate that the IMF growth mode can be used in MOCVD epitaxial technology similar to molecular beam epitaxy (MBE) technology to produce the thinner GaSb layer with low density of dislocations and other defects on GaAs substrate for the application of devices.     

Impact of surfactants on the lipase digestibility of gum arabic-stabilized O/W emulsions

The bioavailability of lipids from an emulsion can be controlled and regulated by the property of the stabilizing interfacial layer. Here we evaluate how low-molecular weight surfactants including hexadecyl trimethyl ammonium bromide (CTAB), sodium dodecyl sulfate (SDS), and Tween 80 (T80) influence the interfacial behavior of lipase and bile extract on the surface of lipid droplets stabilized with gum arabic (GA). The lipolysis behavior was influenced by surfactant type and concentration. The results showed that anionic SDS could completely displace GA from droplet surface. Cationic CTAB might either adsorb onto existing GA layers or displace GA, whereas non-ionic T80 could co-adsorb with GA on the interface. When the concentration of surfactants was much higher than the critical micelle concentration (CMC), all the surfactants would form a dense adsorption layer on the droplet interface to prevent lipase from the direct contact with lipids. A considerable amount of surfactant in the aqueous phase may also compete with the bile salt and lipase, thus leading to suppressed digestion of lipids. Ionic surfactants would denature the lipase resulting in reduced enzyme activity, and T80 micelles may interact with the lipase, hindering their adsorption onto the droplet interface as well. These results were confirmed both by the digestion model and interfacial techniques. The results provided guidance for the development of emulsion-based delivery systems for functional lipid foods.     

Interfacial and emulsifying behaviour of crayfish protein isolate

The interfacial behaviour of adsorbed protein films constituted with a crayfish protein derivate that is typically produced as by-product from the food industry, has been studied at the air-water and oil-water interfaces. An analysis of the surface pressure under compression-expansion cycles of this protein was carried out as a function of time, concentration and pH (2 and 8). Besides, interfacial tension and adsorption kinetics also were determined as a function of time at different concentrations and pH values. Interfacial rheological properties were studied under dilatational deformations applied to a single droplet, either at the initial step of film formation or once the interfacial tension was at equilibrium and the film was completely formed. The contribution of the interfacial properties to the behaviour of oil-in-water emulsions stabilised with this protein derivative were also analysed. Finally, droplet size distributions obtained for concentrated emulsions stabilised by crayfish protein were analysed and related to the interfacial tension behaviour. We have demonstrated that crayfish proteins at pH 8 show higher solubility, smaller aggregates and better interfacial activity (higher surface pressure and lower interfacial tension) with higher interfacial viscoelasticity, than at pH 2. A two-dimensional model of the results showed that oil-water and air-water interfaces are clearly related to the improved stability of emulsion made with crayfish proteins at pH 8.     

Modeling of distribution parameter,void fraction covariance and relative velocity covariance for upward steam-water boiling flow in vertical rod bundle

In order to improve the prediction accuracy of one-dimensional interfacial force formulated by ‘Andersen’ approach, the distribution parameter in a drift–flux correlation, void fraction covariance, and relative velocity covariance has been modeled for dispersed boiling two-phase flow in a vertical rod bundle. The distribution parameter has been derived by a bubble-layer thickness model. The correlations of void fraction covariance and relative velocity covariance have been developed based on prototypic 8 × 8 rod bundle data. The correlation of void fraction covariance agrees with the bundle data with the mean absolute error, standard deviation, mean relative deviation, and mean absolute relative deviation being 0.00120, 0.0415, ?0.173%, and 1.80%, respectively. The correlation of relative velocity covariance agrees with the bundle data with the mean absolute error, standard deviation, mean relative deviation, and mean absolute relative deviation being ?0.00241, 0.0452, ?0.0316%, and 2.52%, respectively. In view of the great importance of void fraction covariance and relative velocity covariance on the one-dimensional interfacial drag force formulation, it is highly recommended to include the void fraction covariance and relative velocity covariance in the one-dimensional formulation of interfacial drag force used in nuclear thermal-hydraulic system analysis codes.     

Code performance with improved two-group interfacial area concentration correlation for one-dimensional forced convective two-phase flow simulation

In gas–liquid two-phase flow simulation for reactor safety analysis, interfacial momentum transfer in two-fluid model plays an important role in predicting void fraction. Depending on flow conditions, a shape of the two-phase interface complicatedly evolves. One of the proposed approaches is to quantify the gas–liquid interface information using interfacial area transport equation. On the other hand, a more simplified and robust approach is to classify bubbles into two-groups based on their transport characteristics and utilize constitutive equations for interfacial area concentration for each group. In this paper, interfacial drag model based on the two-group interfacial area concentration correlations is implemented into system analysis code, and void fractions were calculated for the evaluation of numerical behaviors. The present analysis includes (1) comparison of one-group and two-group relative velocity models, (2) comparison with separate effect test database, (3) uncertainty evaluation of drag coefficient, (4) numerical stability assessment in flow regime transition, and (5) transient analysis for simulating the prototypic condition. Results showed that utilization of interfacial drag force term using constitutive equations of two-group interfacial area concentration yields satisfactory void fraction calculation results. The proposed solution technique is practical and advantageous in view of reducing the computational cost and simplifying the solution scheme.