Characterization of poly(vinyl alcohol)/sodium bromide polymer electrolytes for electrochemical cell applications

Sodium‐ion conducting polymer electrolytes based on poly(vinyl alcohol) complexed with sodium bromide were prepared with a solution‐casting technique. The structure of these films was determined with X‐ray diffraction, and the complexation of the salt with the polymer was confirmed with Fourier transform infrared spectroscopy studies. Electrical conductivity was measured with an alternating‐current impedance analyzer in the frequency range of 100 Hz to 1 MHz and in the temperature range of 303–373 K. It was observed that the magnitude of conductivity increased with the increase in the salt concentration as well as the temperature. The nature of the charge transport in these polymer electrolyte films was determined with both Wagner's polarization technique and the Watanabe technique. The dominant conducting species were found to be ions, particularly anions. Optical absorption studies were performed in the wavelength range of 200–600 nm, and the absorption edge, direct band gap, and indirect band gap values were evaluated. Electrochemical cells were fabricated, and their discharge characteristics were studied. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

锂离子电池正极材料的制备研究现状

叙述了锂离子电池正极材料LiC0O2、LiNiO2：LiMn2O4及锂钒氧化物的合成方法；概述了铝、镍、钛等某些掺杂元素对LiC0O2、LiNiO2、LiMn2O4、锂钒氧化物的容量和循环性能影响。通过对LiC0O2、LiNiO2、LiMn2O4及锂钒氧化物的结构、充放电容量等性能分析和合成原料成本的分析，认为LiMn2O4及锂钒氧化物有望成为新一代优良的锂离子电池正极材料。     

二次电池电极基板用复合多孔金属材料的研究

介绍了一种复合金属多孔体的制备及其方法，首先以泡沫塑料为芯膜，经过导电化处理使其具有导电性，其次进行电沉积金属铁，再进行电沉积金属镍，经过热处理后可制备出复合金属多孔体。该复合金属多孔体用铁取代金属镍，其抗拉性能优于单质泡沫镍，同时可以降低制造成本，主要用于载体如电池电极。     

聚氧乙烯 - 聚氧丙烯 - 聚苯乙烯多嵌段聚合物的力学和导电性能研究

研究了聚苯乙烯含量对聚氧乙烯－聚氧丙烯－聚苯乙烯多嵌段聚合物的力学性能及其与ＬｉＣｌＯ４络合物的离子导电性能的影响；并以电导率较高的络合物为电解质，Ｎａ１＋ｘＶ３Ｏ８复合物和Ｌｉ片分别为正、负极组装了薄型锂电池并测定其放电性能。     

基于电压陡降的VRLA容量预测新思路

重点介绍了蓄电池电压陡降与容量之间的关系及各操作因素对电压陡降的影响。由此引出一种新的蓄电池容量预测思路,并就如何实现它进行了初步探讨,最后对该思路进行了简要的展望。     

飞机碱性电瓶充放电参数测量仪的设计与研究

电瓶是民航飞机可靠供电的最后保证。飞机制造厂家提高了对电瓶的性能和容量检测要求,传统的电瓶充放电装置已经无法满足新的要求。利用单片机技术研制的飞机电瓶参数测试仪,实现了对电瓶各种参数的实时侧量和分析,为飞机电瓶维护和检测提供依据。     

离网型太阳能光伏发电系统设计研究

离网型太阳能光伏发电系统是太阳能光伏发电系统的重要组成。它具有灵活度高、分布广、项目成本低等优点。本文主要对现有离网光伏发电系统设计过程进行分析。     

基础影响下车载飞轮电池动态性能的联合仿真分析

以车载飞轮电池为研究对象,利用ADAMS软件建立了飞轮转子与等效基础的机械模型,并利用MATLAB软件建立了相应的不完全微分PID控制器模型.通过联合仿真分析了基础的加速、减速、转弯和爬坡运动,以及因路面不平整引起的基础纵向振动、横向振动和俯仰振动对高速飞轮转子系统动态性能的影响.仿真结果表明,基础的不同运动状态均会对高速飞轮转子的稳定运行产生显著影响,仿真分析结果可对车载飞轮电池的设计提供有益参考.     

Studies of structure and cycleability of LiMn2O4 and LiNd0.01Mn1.99O4 as cathode for Li-ion batteries

Lithium manganese oxides LiMn₂O₄ and rare earth elements doped LiNd_0.01Mn_1.99O₄ were synthesized by microwave method. The structure and the electrochemical performances of the samples were characterized. XRD data shows both samples exhibit the same pure spinel phase. But due to the introduction of Nd³⁺ ion into the unit cell, the lattice parameter of the Nd-doped spinel was larger than that of the undoped one. The two samples had a similar morphology including small particle size and homogeneous particle distribution as tested by SEM. The cyclic voltammmetry and constant-current charge-discharge tested that Nd-doped spinel displayed a better reversibility and cycleability.     

矿用大容量磷酸铁锂电池管理系统设计

为了保证矿用磷酸铁锂电池的安全性,结合煤矿工业实际需求,设计了8节单体60A·h磷酸铁锂电池串联、24V额定电压输出的矿用电池管理系统。该系统将微处理器配合集成芯片LTC6803组成电池保护模块,利用安时法估算电池组电量,采用电阻分流型均衡技术改善电池组性能。现场应用结果表明,该系统运行稳定可靠,保证了矿用磷酸铁锂电池的安全高效性。