新型聚丙烯接枝物的制备及应用

为制备强韧的共混材料,利用熔融接枝法研制了含有两种接技单体的新型聚丙烯接枝物,讨论了第二单体在接枝过程中的作用,并将其应用于尼龙6/聚丙烯(PA6/PP)共混体系,获得了使分散相粒径更细小、界面更模糊的增容效果。     

原位聚合制备尼龙6/纳米SiO2复合材料研究

对原位聚合制备尼龙6／纳米SiO2进行研究。结果表明，无论是否对纳米SiO2复合材料进行偶联化处理，其表面均将在原位聚合过程中与尼龙6产生接枝；SiO2表面接枝物的生成，可在某种程度上造成体系结晶程度的降低，但复合体系的力学性能主要由SiO2粒子的分散程度、粒子和其体之间的相界面性质等因素决定；采用经偶联剂处理并具有较小粒径和较大比表面积的SiO2对尼龙6进行复合，可使复合体系的力学性能指标达到较高的水平，且硅烷偶联剂的最佳用是为SiO2的3％左右。     

MC(Mid-Century)催化氧化过程的研究进展

介绍了MC催化氧化过程规律；从催化荆体系的改进、新型溶剂体系的开发、反应器构型和配套设施的改进、富氧氧化技术的开发等方面综述了近年来MC技术的发展；探讨了MC液相催化氧化技术应用范围的拓展以及MC液相催化氧化过程的发展方向。     

高分2号图像业务化大气校正查找表的设计与实现

为实现高分2号图像(GF2)业务化大气校正,利用矢量6S模型(6SV)将辐射传输散射与吸收进行分离计算,其中散射部分采用涵盖各种大气模式、气溶胶类型、成像几何等条件下的大气校正查找表(look-up tables,LUTs)表示,大气吸收部分采用6SV拟合计算的6种大气模式下大气透过率的经验公式表示,这种处理有效简化了查找表大小.在内存4 GB、主频3.10 GHz条件下,通过比较基于本查找表方法和基于FLAASH大气校正软件对北京地区一景GF2数据处理.结果表明:以6SV模型直接大气校正法结果作为真值,两者的绝对误差分别为0.8%和2.6%,处理时间分别为77 s和240 s,该大气校正查找表在处理精度和效率更加适合业务化大气校正.     

铸造铝合金轮毂T6热处理工艺的优化研究

研究了固溶时间、淬火停留时间及涂装烘烤工艺对A356合金铸造轮毂性能的影响规律并优化了T6热处理工艺，将淬火停留时间缩短到2h。研究表明：未涂装时优化工艺使合金抗拉强度达到240MPa，屈服强度达到181MPa。伸长率达到8％；涂装后抗拉强度达到262MPa，屈服强度达到179MPa，伸长率达到9％，接近并达到目前国内T6工艺的强度性能，超过了国内轮毂行业的强度性能标准，具有一定的生产实际意义。     

Infrared heat treatment of Ti-6Al-4V with electroplated Cu

The objective of this study is to investigate an innovative infrared (IR) technique to enhance adhesion of electroplated copper (Cu) on Ti-6Al-4V without dichromate dipping. The ultimate goal is to develop a Cu coating process on Ti-6Al-4V without hazardous hexavalent chromium (Cr) solution treatments. Cu coatings of around 50 μm were electroplated on Ti-6Al-4V specimens at a current density of 0.03 A/cm² in an acidic Cu solution. To improve adhesion of coatings, IR heat treatments were performed on the Cu-coated samples at different temperatures and durations: 860 °C for 600 s and 875 °C for 20–120 s. This process was accomplished in an attempt to replace the use of dichromate dipping before electroplating. For samples heat treated at 860 °C, no bonding existed, even after 600 s. It is believed that solid-state diffusion prevailed at 860 °C and that 600 s was not enough for sufficient diffusion to occur. Adhesion was poor when samples were heat treated at 875 °C for 20 s. Excellent adhesion was observed when the heat treatment holding time was increased to 40 s. For 90 s, the surface appearance of coatings partially changed from Cu-colored to a grayish color. There was no Cu left on the surface after a 120 s heat treatment. From optical microscopic observations on sample cross sections, an interlayer between the Cu and Ti-6Al-4V formed when heat treated at 875 °C for 40 s and longer. The interlayer thickness increased as the holding time increased, until depletion of Cu. The sheet resistivity of coated specimens was on the order of pure Cu for samples heat treated at 875 °C and less than 90 s. During the 875 °C heat treatment, the following occurred: solid-state diffusion of Cu in Ti-6Al-4V, formation of eutectic solutions, dissolution of Cu and Ti-6Al-4V into the liquid phase, and the formation of intermetallic compounds. The lowest eutectic temperature of 875 °C played a key role in this innovative process of Cu coating on Ti-6Al-4V. This paper was presented at the 2nd International Surface Engineering Congress sponsored by ASM International, on September 15–17, 2003, in Indianapolis, Indiana and appears on pp. 403–10 of the Proceedings.     

Oxidation behavior of 2.25Cr-1Mo steel with prior tempering at different temperatures

The oxidation behavior of a normalized 2.25Cr-1Mo steel tempered previously for 10 hr at different temperatures between 873 and 1023 K has been studied up to a maximum duration of 1000 hr in air at 773–973 K. The oxidation resistance of the steel was found to decrease significantly with the temperature of tempering. Tempering of this steel is reported to cause microstructural changes involving precipitation of Cr as carbides and a decrease in the effective (free) Cr contents, that could influence the oxidation resistance of the Cr-containing alloys. Relative compositions across the thickness of the oxide scales, as analyzed by SEM/EDX and SIMS, suggest that a less Cr-rich (and less protective) and thicker scale on the steel formed because previous tempering caused extensive depletion of free Cr.     

ZTC4筒形件温成形扩口数值模拟

对铸造Ti-6Al-4V筒形件温成形扩口成形工艺进行了数值模拟分析,得出了优化的工艺参数,并对凸模锥角进行了优化模拟,得出了合适的锥角。