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71.
A hybrid supercapacitor based on manganese oxide, activated carbon and polymer electrolyte was developed and electrochemically investigated. The capacitive performance obtained from the polymer electrolyte based supercapacitor was similar to that of an aqueous electrolyte based supercapacitor, tested for comparison in the same operative conditions. A durability test carried out for 2500 cycles showed stable and slowly increasing performance. The specific capacitance of hybrid supercapacitor was 48 F g−1 (192 F g−1 as a mean one electrode capacitance), in which that of the positive electrode was 384 F g−1 of MnO2 and that of negative electrode 117 F g−1 of carbon. The impedance analysis evidenced that although the polymer electrolyte based hybrid supercapacitor showed higher resistance compared to that of the liquid electrolyte based supercapacitor, this drawback was counterbalanced by better ion transport features, which were evident at lower frequencies, where similar values of capacitances were obtained from the different supercapacitors. 相似文献
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A novel heteropolyoxometallate with the formula [H3NNH3]2K2MnMo9O32·(NH3)·3H2O has been prepared in water solution. The crystal structure of the title compound was determined by the single-crystal method. This new mixed metal anionic complex crystallizes in the rhombohedral space group R3 (No. 146) with a=b=15.873(5), c=12.344(6) Å, γ=120°. The disordered structure contains three molecules in the unit cell. Full-matrix least-squares refinements of the title complex yielded final reliability (R) factors of 0.0356 (Rw=0.0868) with a goodness-of-fit (GOF, Σ2) value of 1.099 based on 1430 [I>2σ(I)] observed reflections. All Mo and Mn atoms are six-coordinated octahedrally to form a Mn-centered cage with a Mo9O32 group as the framework. 相似文献
78.
Thermal stability of metal-supported catalysts for reduction of cold-start emissions in a wood-fired domestic boiler 总被引:5,自引:0,他引:5
The aim of the present work is to develop a catalyst based on a mixture of manganese oxides and platinum supported on a metallic monolith for abatement of emissions from wood combustion, particularly during the cold-start phase. The activity and the thermal stability of the catalysts have been studied in the laboratory, before performing tests in a wood-stove. The effect of the hydrothermal treatment at 900°C on the adherence of the washcoat onto a metallic substrate was studied using scanning electronic microscope. It revealed well-adhering washcoat onto the metallic support due to the growth of the alumina whiskers during the treatment. The influence of the amount of washcoat, as well as the influence of the concentration of manganese oxides in it (Mn: 5 to 20 mol%/Al2O3) on the activity of fresh and hydrothermally-treated catalysts were studied. The activity tests were carried out using a mixture of carbon monoxide, naphthalene and methane in the presence of air, steam and carbon dioxide to resemble the flue gases from wood combustion. On the fresh catalysts, containing the same total amount of manganese, a high concentration of manganese oxides in the washcoat favoured the oxidation of carbon monoxide and naphthalene, whereas a lower concentration of manganese oxides in the washcoat gave higher activity for the oxidation of methane. An increased total amount of manganese oxides in the catalysts, which had the same amount of washcoat, resulted in an increase in activity for the oxidation of the three combustibles. After thermal treatment at 900°C for 270 h in steam, most of the manganese oxide catalysts were activated for the oxidation of carbon monoxide and naphthalene while only being slightly deactivated for the oxidation of methane. The addition of manganese oxides in the washcoat, however, lowers the temperature of the γ- to -alumina phase transformation. Platinum (0.5 mol%) was added to the manganese oxide (10 mol%) catalyst to improve its activity. A platinum catalyst was also tested for comparison. The platinum and the mixed catalysts showed similar activity for the oxidation of carbon monoxide and naphthalene, while the mixed catalysts were more active for the oxidation of methane. A similarly mixed MnOx–Pt (10–0.5 mol%) catalyst supported on Al2O3 stabilised with 3% lanthanum, but at larger scale, was tested in a wood-stove. The possibility of pre-heating the catalyst during the start-up phase was studied. The tests revealed a strong decrease of the carbon monoxide and unburned hydrocarbons emissions during the start-up phase when the catalyst was pre-heated with hot air compared with no pre-heating or no catalyst. 相似文献
79.
Spinel LiMn2O4 powders with sub-micron, narrow particle-size distribution, and phase-pure particles were synthesized at low temperatures
from aqueous solution of metal acetate containing glyoxylic acid as a chelating agent by a sol-gel method. The effects of
the calcination temperature and glyoxylic acid quantity on the physicochemical properties of spinel LiMn2O4 powders were examined with X-ray diffractometry (XRD), the Brunauer-Emmett-Teller (BET) method and scanning electron microscopy
(SEM). Porous LiMn2O4 electrode was characterized electrochemically with charge/discharge experiments and A.C. impedance spectroscopy. The cycling
performance of a Li/polymer electrolyte/LiMn2O4 cell has been discussed in terms of contact and interfacial resistance by A. C. impedance spectroscopy. 相似文献
80.
黑龙江双城市净水厂原水取用地下水,其含有铁、锰和高硬度,采用石灰软化法、曝气和常规水处理工艺,处理后水中的铁、锰和硬度均达到《生活饮用水卫生标准》(GB 5749—2006)。但由于采用石灰软化去除硬度,出水中残存的硬度多以CaCO3和Mg(OH)2沉淀物形式存在,致煮沸水中表面有白色沉淀物薄膜,因此采取在滤后水中加入少量盐酸的方法,使煮沸水中不再出现白色沉淀物薄膜。去除硬度的生产废水中含有高浓度的CaCO3和Mg(OH)2沉淀物,直接排放会堵塞下水道和污染接纳水体,故进行了生产废水处理以利于环境保护和污泥回收利用。 相似文献