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991.
Precursors for yttrium aluminum garnet (Y3Al5O12—YAG) were synthesized by simple decomposition of concentrated aqueous solution of nitrates and combustion of concentrated aqueous solution of nitrates with urea on a heater. The precursor formed by the former reaction was granules of agglomerated powder while that from the latter reaction was a voluminous and porous sponge-like mass. Both precursors were ground to powders and subjected to detailed thermogravimetric–differential thermal analysis and X-ray diffraction studies. The precursor from the simple decomposition of nitrates exhibited a total loss in weight of about 18% in stages (25 to 300 °C and 300 to 600 °C) accompanied by endotherms—characterized as processes of dehydration of absorbed moisture and decomposition of residual nitrates, respectively. The as formed precursor and that heated to 820 °C were amorphous. Crystallization to YAG phase occurred from an amorphous oxide characterized by an exotherm above 820 °C with no loss of weight. The precursor from nitrate–urea combustion reaction was found to exhibit a weight loss of 2.5% accompanied by a shallow endotherm in the range of 25 to 300 °C—characterized as the process of dehydration of absorbed moisture. No further weight loss or heat effect was noticed, confirming it to be chemically pure YAG. This as formed precursor was found to be crystalline YAG. The difference in chemical composition of the precursors formed by these two reactions is attributed to the difference in the actual reaction temperatures during their formation—lower reaction temperature for the endothermic decomposition of nitrates and higher reaction temperature for the exothermic combustion associated with the formation of a bright flame. The morphology of the precursor powder formed by the former reaction exhibited only cracks while that of the precursor from the latter reaction exhibited pores and voids. The precursor from the former reaction was calcined at 1100 °C to form into chemically pure YAG. Zeta potential variation with pH for the aqueous suspensions of the crystalline YAG powders from both the reactions exhibited a maximum value in the range of 40 to 50 mV around a pH of 4, indicating stability of these dispersions towards coagulation at this pH. Particle size distribution of wet ground powders (slurries with 20%, v/v, solid at a pH of 4) showed that the powder from combustion reaction could be formed into a finer size than that from simple nitrate decomposition, indicating the agglomerates of combustion reaction were softer. 相似文献
992.
G. X. Wang Y. Chen K. Konstantinov Jane Yao Jung-ho Ahn H. K. Liu S. X. Dou 《Journal of Alloys and Compounds》2002,340(1-2):L5-L10
Nanosize cobalt oxides (Co3O4) were synthesised by chemical decomposition of cobalt octacarbonyl in toluene at low temperature. Electrochemical properties of as-prepared Co3O4 as anodes in Li-ion cells were tested. The nanosized Co3O4 electrode demonstrate a stable reversible lithium storage capacity of 360 mAh/g within 30 cycles. The reactivity of as-prepared Co3O4 in Li-ion cells could be attributed to nanosize particles of Co3O4 and its lithiation products. 相似文献
993.
Synthesis and hydrogen storage properties of Mg-based alloys 总被引:8,自引:0,他引:8
Mg-based alloys have been made by mechanical alloying Mg with some transition and non-transition elements. The thermal stability and hydrogen storage properties have been investigated. It was found that mechanical alloying results in a supersaturated solid solution of some elements in the Mg phase. Thermal annealing and/or hydrogenation cause irreversible decomposition of supersaturated solid solution leading to a composite of Mg or MgH2 with other phase(s) depending on the composition and contents. Therefore, the plateau pressure or thermodynamic properties of hydrogen absorption/desorption of the supersaturated solid solution are no different from that of the Mg composite. While in some equilibrium systems, the formation of Mg solid solution is reversible upon hydrogenation/dehydrogenation. The plateau pressure of the hydrogenation/dehydrogenation is increased due to the interaction of the alloying elements with the Mg lattice in the solid solution. The Mg–Li system is an exception because of the formation of stable LiH upon hydrogenation of Mg(Li) solid solution. No interaction takes place between Mg or MgH2 with LiH, therefore, no destabilization of MgH2 is observed. 相似文献
994.
Development of dieldrin,endosulfan, and hexachlorobenzene‐imprinted polymers for dye‐displacement array sensing 下载免费PDF全文
Ofelia V. Silverio Regina C. So Katrina Jean S. Elnar Christian A. Malapit Ma. Cristine M. Nepomuceno 《应用聚合物科学杂志》2017,134(2)
Due to the toxicity associated with the exposure to organochlorine pesticides, new materials capable of selectively capturing and detecting these compounds are highly desirable. In this study, imprinted polymers were prepared using three organochlorine pesticides—dieldrin (DE), endosulfan (EN), or hexachlorobenzene (HCB) as templates. The MIPs were polymerized via precipitation polymerization. The yields were over 90% with particle sizes ranging from 62 to 214 nm. Binding studies combined with GC‐ECD analysis showed that each template is more selective to its corresponding MIP compared with the other two structurally homologous templates. These results were consistent with those obtained using UV–vis where more bromocresol green (BCG) dye was released when higher template concentrations were introduced to the corresponding BCG‐impregnated MIPs. Since unique selectivity response pattern for each of the MIPs was obtained, this demonstrated that the MIPs were selective and can be potentially used in dye‐displacement array sensing. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 44401. 相似文献
995.
简要介绍了高抗冲聚苯乙烯(HIPS)家电专用料产品的开发、生产及应用情况。并根据国内HIPS家电专用料的实际情况及市场需求,对今后HIPS产品的研究和开发提出了建议和想法。 相似文献
996.
《Journal of the European Ceramic Society》2019,39(11):3315-3319
Multilayer ceramic capacitors (MLCCs) of lead-free NBT-based ceramics are produced and their electrocaloric effect (ECE) is characterised for the first time. Dense MLCCs with 97μm-thick active layers are successfully produced by tape casting. Dielectric permittivity measurements reveal the MLCCs to have properties similar with that reported for the corresponding bulk ceramics, including Td∼50°C and TS∼100°C. Direct ECE measurements also reveal agreement and confirm the previously reported tendency of the high-field ECE peak to shift towards TS. The highest value of ECE, ΔTmax∼1.7K is measured at 90°C under 90kV/cm. A low breakdown strength of 93kV/cm needs to be solved to realise stronger electric fields and achieve commercially viable ECE values. 相似文献
997.
In recent years, the use of fiber‐reinforced polymer composites in civil infrastructure has been promoted as a solution to the deterioration of bridges, buildings, and other structures composed of traditional materials, such as steel, concrete, and wood. Any application of a polymer composite in an outdoor environment invariably involves exposure to moisture. There is also potential for exposure to saline conditions in waterfront or offshore structures, and alkaline environments, as would be encountered by a reinforcing bar in a cementitious material. This study characterizes the sorption and transport of distilled water, salt solution, and a simulated concrete pore solution in free films of vinyl ester, isophthalic polyester (isopolyester) and epoxy resins, all commercially important materials for use in structural composites. Diffusion of all three liquids in each of the three materials was observed to follow a Fickian process. Mass loss was observed for the isopolyester in salt water and concrete pore solution at 60°C, suggesting hydrolysis that was accelerated by the high temperature exposure. Both the rate of uptake, as well as the equilibrium uptake, were greater at 60°C, compared with ambient conditions. Diffusion coefficients calculated from the mass uptake data revealed that, although the epoxy resin had the highest equilibrium uptake, it had the lowest diffusion coefficient. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 71: 483–492, 1999 相似文献
998.
999.
Keizo Uematsu Jin-Young Kim Masayori Miyashita Nozomu Uchida Katsuichi Saito 《Journal of the American Ceramic Society》1990,73(8):2555-2557
The internal structure of spray-dried alumina granules was characterized by optical microscopy by immersing them in a liquid having a refractive index close to that of alumina. This method provides a unique technique for the detailed analysis of the internal structure of spray-dried granules. 相似文献
1000.
Do-Kyun Kwon Clive A. Randall Thomas R. Shrout Michael T. Lanagan 《Journal of the American Ceramic Society》2004,87(6):1088-1092
The dielectric properties and frequency dispersion associated with a dielectric relaxation were evaluated within the perovskite (1− x )BiScO3 – x Ba(Mg1/3 Nb2/3 )O3 solid solution systems (0.7 ≤ x ≤ 1). With increasing BiScO3 , the room-temperature dielectric permittivity at low frequency (100 Hz) increased up to 115 at x = 0.7, and a dielectric relaxation phenomenon was evident. Relaxation parameters were analyzed using several Arrhenius-type equations, and the microwave dielectric property measurement using rectangular wave-guide method enabled confirmation of the extrapolated value of the Arrhenius plot. The result of the microwave dielectric property measurement was also checked with J -function fitting based on the frequency-dependent Gaussian distribution of the associated dielectric loss data at low frequency. 相似文献