It is shown that steady-state kinetic data do not allow the discrimination between the redox and associated mechanisms of the partial oxidation reactions. A discrimination between these mechanisms was performed using transient experiments. The obtained rate expressions are in agreement with experimental kinetic data for catalytic partial oxidation of o-xylene.
An influence of the conjugate oxidation of a catalyst surface on dynamics and kinetics of the heterogeneous catalytic oxidative reactions is considered. Computing simulation of methane oxidative coupling of methane reaction at lowered temperature and elevated pressure has been performed. It showed that the reaction order with respect to oxygen exceeding unity is consistent with the chain branching mechanism of the reaction in the presence of TiSi2 and TiB2 and showed the important role of the branching chain cycles in the low-temperature OCM reaction at elevated pressure. 相似文献
A new technique, namely, the open-die backward extrusion test technique, was developed as an alternative method to the ring compression test in order to quantitatively evaluate the coefficient of friction, μ, at the die/workpiece interface. This technique relates the percentage deformation in height of the specimen to the percentage increase in extruded height of the specimen. In this study, the open-die backward extrusion tests (ODBET) were simulated for different aspect ratios, (H/D), and different die geometries, (d/D), by utilizing an elastic-plastic finite element code (ANSYS) in order to obtain the friction calibration curves (FCCs). The results indicated that the extruded height is related to the friction conditions at the die/workpiece interface. Therefore, ODBET can be used to generate FCCs to determine the coefficient of friction at the die/workpiece interface in large deformation processes. 相似文献
The durability of a cold wall MHD generator consisting of metal electrodes and alumina-coated peg insulators was experimentally examined in the oil-fired MHD condition with the additive of SO2 corresponding to S = 0.54 wt%. The structure of the electrode wall and various anode and cathode materials were tested, with particular reference to developing long-life electrodes. It was clarified that Pt, SHOMAC (28.8 Cr−1.9 Mo) and SUS-304 as anodes and W---Cu (70 W−30 Cu) and WC---Ag (60 WC−40 Ag) alloys as cathodes were promising for durability and that the structure of an anode divided into two elements connected to each other with an SnO2 resistor was very useful for uniformity of the anode corrosion pattern and the inter-anode voltages. It is reasonable to expect, from the test results, that the lifetime of a cold wall MHD generator in an oil-fired commercial plant will be over 4000 h, and therefore, a foundation for its commercial use has been established. 相似文献
Recrystallization and grain growth evolutions during metal forming processes are considered. Coupling between the thermo-mechanical and microstructure processes is realized. Die forging of a rear-axle flange is simulated numerically on the base of the finite element method. Material parameters of the models are obtained experimentally. The influence of interpass and holding times on grain size distributions in the end product is shown. 相似文献
At the shipyards, the aluminium alloy 5083 is welded with a multi-pass sequence using the metal inert gas technique. If, while checking the weld integrity either after welding or during service, defects are detected in the vicinity of the weldment, repairs are usually employed to extend the service life.
The repair method involves removal of the upper passes, depending on the thickness and re-welding under the same conditions.
Purpose of this paper is to examine the microstructural changes accompanying repair welding, define their effect on properties of primary importance and set, if possible, an upper limit as far as the number of repairs is concerned. 相似文献
Bilayered palladium (30 nm thick)–magnesium (350 nm thick) thin films were prepared using the pulsed laser deposition technique in the presence of various background gases (Ar, He and a mixture He + H2) under different partial pressures (47 and 27 Pa). According to the deposition atmosphere, the Pd/Mg interface shows either a sharp or an extended transition. The electrochemical hydriding properties and the mechanical stability upon cycling of the Pd/Mg film are greatly improved when an extended «intermixing» zone between the Pd and Mg layers is present. The Pd–Mg films prepared under pure helium fulfill these conditions. 相似文献