Preparation of cobalt-modified magnetite and its magnetic properties

Magnetite was modified by reaction with alkaline solution containing Co^2 and Fe^2 to obtain a cobalt ferrite layer on the surface of particles. The influences of modification conditions on the properties were investigated. The as-prepared particles were characterized by X-ray diffraction(XRD) and transmission electron microscope(TEM). The results show that pH value influences the particles composition directly, the desirable CoFe2O4 is obtained as pH value is 12. The coercivity of particles increases with the increase of cobalt content, and the cobalt efficiency reaches a maximum value at cobalt content of 2.71% (mass fraction). With cobalt modification, the magnetite particles have the similar lattice constant and structure to that without cobalt modification, and the squareness ratio is almost 0.5. The increase of the coercivity is attributed to the uniaxial magnetic anisotropy and magnetocrystalline anisotropy of cobalt-ferrite itself.     

Mathematical modeling of electromagnetic dimensionless number for electromagnetic casting of metals and its application

in order to estimate the feasibility of electromagnetic casting (EMC) for different metals, a mathematical model named the electromagnetic dimensionless number (EMDN) was presented, and its validity was proved by the experiments of aluminum and Sn-3~Pb alloy. From the experiment and the analysis of EMDN it can be concluded that the EMC of steel can be attained only when the magnetic flux density is larger than 0. 09 T, while that required for aluminum is only 0. 04 T. The mathematical expression of the electromagnetic dimensionless number was given out.     

三自由度混合电磁轴承的参数设计与控制系统实验研究

将永磁铁改为插槽式改进了三自由度混合轴承结构。设计系统的控制器,采用现代工业最常用的控制形式——传统PID控制、非线性补偿PID控制以及基于遗传算法的PID控制方法对电磁轴承的控制效果进行比较研究。利用MAT-LAB中的Simulink模块库对所设计的PID控制参数进行调试整定。结果表明:非线性补偿PID控制明显优于传统的PID控制,基于遗传算法的PID控制方法控制效果最优。     

HiB钢与低温高磁感取向硅钢性能比较

对HiB钢和低温高磁感取向硅钢的晶粒大小、磁性均匀度、晶粒位向、磁致伸缩、产品实际应用性能方面的差异进行了研究。结果表明,相同磁性能条件下,HiB钢与低温高磁感取向硅钢的晶粒结构明显不同,HiB钢中与高斯位向的偏离角在0°～2°范围内的晶粒所占比例比低温高磁感取向硅钢大。在应用方面,HiB钢产品磁性能具有一定优势,低温高磁感取向硅钢应以改善晶粒位向,减小与高斯位向的偏离角为主要研究方向。     

Magnetic property and recording performance of chemical deposition CoP thin films

The thickness of CoP thin films prepared by wet chemical deposition is of crucial importance on magnetic property and recording perform-ance. The coercivity of CoP films decreased with increasing film thickness. The coercivity was 45.37 kA m 1 at the thickness of 300 nm, and decreased to 21.65 kA m 1 at 5.7 μm. Recording performance tests indicate that, for drums with the same size, different recorded magnetic pole density have different thickness requirements. For 40 mm diameter magnetic drum, the optimal ...     

纳米铁酸锌/丙氨酸改性聚乳酸复合磁性微球的制备和表征(英文)

以改进液相化学法合成铁酸锌纳米磁流体来代替传统的铁氧化物磁粉,同时以D,L型丙交酯与丙氨酸为单体进行本体聚合,得到氨基酸改性聚乳酸,再以改性聚乳酸包封纳米磁流体构建磁性高分子微球。采用X射线衍射、傅立叶红外光谱仪、核磁共振仪、扫描电镜、透射电镜、振动样品磁强计、热重分析仪等对所合成的材料进行表征。结果表明:所制备的材料为尖晶石型的ZnFe2O4纳米晶,粒径为20～45nm,磁饱和强度为32×10-3A.m2;丙氨酸成功接枝到了聚乳酸链上;铁酸锌纳米磁流体/聚乳酸复合微球的分散性较好,粒径为80～300nm,聚乳酸的包覆率为45.5%,磁饱和强度为10.6×10-3A.m2,ZnFe2O4经改性聚乳酸封装后仍然保持较好的磁饱和强度。     

退火温度对CSP生产薄规格无取向电工钢性能的影响

以CSP流程生产的35W440无取向电工钢热轧板为研究对象,研究了不同退火温度对无取向电工钢磁性能的影响规律.研究的结果表明,在实验参数的范围内,随着退火温度的升高,最终成品的晶粒尺寸增大.利用X射线测量了不同退火温度的成品板的宏观织构,结果表明,退火温度的提高有利于减弱{111}面织构,从而有利于改善产品磁性能的α纤维织构和{100}〈0vw〉有利织构组分得到了增强.因此随着退火温度的提高,成品板试样的铁损降低,磁感增加.     

第一性原理计算FeF_2的磁性、结构及电子性能(英文)

采用第一性原理方法研究FeF2的磁性、电子结构和成键机理。通过计算不同U值下的的晶格参数和磁矩,获得最佳的有效U值(Ueff)为4eV,此时计算Fe的磁矩和晶格参数c与a的比值分别3.752μB和0.704,与实验结果吻合。此外,基于GGA+U方法,利用对电子局域函数,Bader电荷和总电荷的分析来研究FeF2的电子结构和成键机理,结果表明Fe和F之间含有离子键和共价键的特征。     

电磁平板自由胀形3D数值模拟(英文)

电磁成形是一种高速率成形方法,它能够有效提高金属板材的成形极限。但是电磁成形过程复杂,涉及到磁场?结构场之间的耦合分析。数值模拟提供一种手段去解决耦合问题。然而,大多数的数值模拟都限于2D。建立3D有限元模型去分析电磁平板胀形。成形过程中考虑了板料与底模的接触和板料变形对磁场的影响。板料中心节点和半径20mm处节点的位移随着时间的变化与实验结果一致。分析了塑性应变能和塑性应变。     

钕铁硼永磁材料的生产应用及发展前景

为了探讨钕铁硼永磁材料的发展前景,发现行业存在的问题,对钕铁硼永磁材料生产和应用现状进行了分析.结果表明,钕铁硼永磁材料将进入一个崭新的发展阶段,应用前景广阔.