Preparation and characterization of Ni/Co bimetallic nano-clusters

Ni/Co bimetallic nano-cluters have been prepared from the aqueous solution by reducing their corresponding metal salts under suitable conditions. The experimental conditions including the type and concentration of protective agent, feeding order and the pH of the solution that influence the average particle size have been studied in detail. Transmission electron microscopy (TEM) indicates that the shape of those bimetallic nano-cluster particles is spheroid. The alloy structure has been shown by X-ray powder diffraction (XRD). The X-ray photoelectron spectroscopic (XPS) data have confirmed that the nickel and cobalt in the bimetallic nano-clusters are in the zero-valence state.     

The AC losses measurement and analysis of superconducting NbTi CICC for HT-TU superconducting Tokamak

Superconducting TF and PF coils have been measured in SULTAN test facility. Segregated copper strands are included in four NbTi CICC and this is a technical innovation. Two AC losses measurement methods, calorimetric and electromagnetic methods, have been used in the experiments, and a broad frequency range (from 0.05 Hz to 6 Hz) is covered in sample test. The purpose of this experiment was to investigate AC losses of TF and PF CICC conductor including segregated copper and to check the design of PF and TF CICC coated with different resistive barriers (Pb-30Sn-2Sb and Ni plating on NbTi strands).     

燃气轮机叶片材料0Cr17Ni4Cu4Nb砂带磨削性能研究

理论分析了在切除过程中磨粒与材料表面的交互作用机理,进行了砂带磨削燃气轮机叶片材料0Cr17Ni4Cu4Nb的试验研究,系统分析了各磨削工艺参数对材料切除率的影响规律,该研究对生产实践具有理论指导意义.     

Ag/LaNixCo1-xO3触点材料的制备及电接触性能研究

本文运用溶胶-凝胶燃烧法合成了双钙钛矿型LaNixCo1-xO3(LNCO)纳米材料,利用粉末冶金和热挤压技术制备了相应的Ag/LNCO触点材料及元件样品。重点考察了不同Ni、Co含量对Ag/LNCO触点材料微观结构、物相组成、物理性能、力学性能及电寿命服役能力的影响,对其电弧侵蚀失效行为进行了研究,并与SnO2粉体增强Ag基触点材料进行对比。结果表明:溶胶凝胶法合成的LNCO纳米颗粒粒径为20-30 nm,经粉末冶金工艺制备的Ag/LaNi0.5Co0.5O3触点材料电学性能和电寿命都优于Ag/SnO2触点材料,其电阻率低至2.10 μΩ?cm,电寿命性能达到51287次。表明Ag/LaNi0.5Co0.5O3触点材料性能较佳,是一种可以取代Ag/CdO的新型触点材料。     

变电站不锈钢金属膨胀节泄漏原因分析

从化学成分、断口电镜扫描、X射线能谱和金相试验等方面,分析了沧州供电公司某变电站电流互感器不锈钢膨胀节泄漏的原因,认为泄漏是不锈钢膨胀节外表面点状电化学腐蚀所致,而该膨胀节表面状态的不连续性,周围潮湿的空气介质及空气介质中富含S、Cl等元素,是造成膨胀节外表面点状电化学腐蚀的主要原因。     

氨浸工艺从废旧锂电池中选择性回收有价金属

研究了碳酸氢铵-还原剂体系选择性浸出废旧三元锂电池中锂、镍、钴的过程。考察了浸出温度、碳酸氢铵浓度、还原剂的种类和浓度、固液比及浸出时间等对有价金属浸出率的影响,并通过XRD、SEM-EDS和FT-IR等表征方法对选择性浸出机理进行了初步探明。结果表明：在浸出温度80 ℃、浸出时间2.5 h、碳酸氢铵浓度2.5 mol/L、固液比50 g/L、还原剂亚硫酸钠浓度0.6 mol/L的条件下,锂、镍、钴的浸出率分别为96.86%、96.36%、93.43%,而锰几乎不被浸出。碳酸氢铵-亚硫酸钠还原浸出体系可以实现从废旧三元锂电池材料中高效、选择性回收锂、镍和钴。     

C/纳米[Ni0.96Co0.04(OH)2-C]混合超级电容器

以纳米Ni0.96Co0.04(OH)2-C复合材料[Ni0.96Co0.04(OH)2(90%)+FJC(10%)]为正极,活性炭为负极,KOH水溶液为电解液组成混合超级电容器.其工作电压为0.75～1.5 V;适合的充电方法是恒流恒压充电;具有快速充电、高倍率放电和循环性良好的特点.8min可充满80%容量,2 200W/kg(以正、负极活性物总质量计算)放电时,比能量达23.2Wh/kg.