Microstructure and Mechanical Properties of NiTi Shape Memory Alloys by In Situ Laser Directed Energy DepositionEI北大核心CSCD

以Ni粉与Ti粉为原料,采用激光定向能量沉积(LDED)技术制备NiTi形状记忆合金。利用XRD、物相拟合、SEM、EDS和DSC等测试方法,对NiTi合金的显微组织、物相含量和物相转变进行分析,随后采用压缩圆柱样品进行形状记忆效应测试,并评估其形状记忆效应。激光能量密度较低时,NiTi合金中产生大量Ni_(4)Ti_(3)相沉淀,随着激光能量密度增加,Ni_(4)Ti_(3)相消失。激光能量密度为20.0 J/mm^(2)时,NiTi合金具有2878 MPa的压缩断裂强度与34.9%的压缩失效应变,且样品在循环20 cyc后具有88.2%形状记忆恢复率。     

奥氏体不锈钢1Cr18Ni9Ti的钻削试验研究

奥氏体不锈钢1Cr18Ni9Ti属较难加工材料,特别是较小孔钻削。为了得到钻头直径与钻削参数对钻削力和钻削温度的影响规律,故用高速钢标准钻头对1Cr18Ni9Ti与45钢进行了钻削对比试验,并用多元线性回归模型建立了钻削力和钻削温度的经验公式。结果表明:1Cr18Ni9Ti的扭矩和轴向力比45钢大,钻削参数对钻削力影响规律与45钢相同,即钻头直径对钻削力的影响最大,进给量次之,钻削速度最小;1Cr18Ni9Ti的钻削温度比45钢约高1.4倍,钻削速度对钻削温度影响最大,进给量次之,钻头直径最小。     

梯度孔隙率与大孔隙尺寸NiTi形状记忆合金的制备及其相变和超弹性行为

利用低温分解型造孔剂与梯级热等静压烧结和常规烧结的匹配工艺成功制备出了梯度孔隙率与大孔隙尺寸多孔NiTi形状记忆合金.多孔合金的孔隙率为30%-61%,孔隙平均尺寸可根据不同预处理工艺在50-500 μm之间变化,且具有较高的开孔率(最高可达85%).所制备的径向梯度孔隙率多孔NiTi合金具有良好的力学性能,线性超弹性应变大于4%;热分析和XRD分析表明,所制备的多孔合金呈现明显的马氏体转变和逆转变特征,相变特征温度随孔隙率的提高而降低.     

Equal channel angular extrusion of NiTi shape memory alloy tube

As a new attempt, equal channel angular extrusion (ECAE) of nickel–titanium shape memory alloy (NiTi SMA) tube was investigated by means of process experiment, finite element method (FEM) and microscopy. NiTi SMA tube with the steel core in it was inserted into the steel can during ECAE of NiTi SMA tube. Based on rigid-viscoplastic FEM, multiple coupled boundary conditions and multiple constitutive models were used for finite element simulation of ECAE of NiTi SMA tube, where the effective stress field, the effective strain field and the velocity field were obtained. Finite element simulation results are in good accordance with the experimental ones. Finite element simulation results reveal that the velocity field shows the minimum value in the corner of NiTi SMA tube, where severe shear deformation occurs. Microstructural observation results reveal that severe plastic deformation leads to a certain grain orientation as well as occurrence of substructures in the grain interior and dynamic recovery occurs during ECAE of NiTi SMA tube. ECAE of NiTi SMA tube provides a new approach to manufacturing ultrafine-grained NiTi SMA tube.     

NiTi 形状记忆合金环向预应力混凝土结构强化现象的研究

采用 NYL-80 型压力试验机进行抗压试验,用YJ-26型静态电阻应变仪测量各级荷载下对应的横竖向应变,同时观察和记录试件的破坏现象,研究了NiTi形状记忆合金环向预应力混凝土结构的强化现象.结果表明SMA环向预应力混凝土柱与同等条件的普通混凝土柱相比,其极限荷载和抗裂性能都有较大的提高.     

Comparative study on microstructure and homogeneity of NiTi shape memory alloy produced by copper boat induction melting and conventional vacuum arc melting

A comparative study was carried out on the microstructures of NiTi shape memory alloy produced by two techniques of copper boat induction melting and vacuum arc melting. The as-solidified and homogenized specimens were characterized by optical microscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM) equipped with EDS, and differential scanning calorimetry (DSC). The results showed that the microstructure formed in the copper boat method was free of segregation (Ti or Ni-rich precipitates) with a low scatter (<5 K) in phase transition temperatures within the ingot at different positions. Unlike the multi-stage vacuum arc remelting process, a homogeneous microstructure was achieved only after one melting procedure.     

Effect of Nitrogen Ion Implantation on the Structure and Corrosion Resistance of Equiatomic NiTi Shape Memory Alloy

To protect the surface of NiTi from corrosion, an ion implantation method was proposed. In the present work, a surface oxidized sample was implanted with nitrogen at energy of 100 keV. The corrosion resistarwe property was examined by the anodic polarization method in a simulated body fluid （SBF） at a temperature of 37 ℃ and contrasted to non-implanted NiTi samples. The composition and structure of the implanted layers were investigated by XPS. The experimental results from the electrochemical measurements provide an evidence that the nitrogen ion-implantation increases the corrosion resistance of NiTi shape memory alloy.