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51.
基于镍基单晶合金的细观结构特征,本文建立两个微胞模型对热不协调性作了系统的模型计算和分析.微胞模型1是以一个γ和γ’为考察对象,微胞模型2是以多个γ和γ’为考察对象,详细的分析表明,这两个模型有一定的等效性,但模型2可分析边界条件更宽的情况.基于微胞模型,对两相合金的临界分切应力进行了分析,结果表明,宏观临界分切应力可用考虑热不协调性的有限元法来处理,所得结果还可推广到较大的γ’相体积分数f的情况.考察了热不协调性对回火状态时γ’形状变化的影响,初步的定量分析表明,热内应力是γ’粗化的一个主要驱动力. 相似文献
52.
SUN Liling DONG Lianke ZHANG Jishan TANG Yajun ZHANG Jinghua HU Zhuangqi Institute of Metal Research Academia Sinica Shenyang China SUN Liling Institute of Metal Research Academia Sinica Shenyang China 《金属学报(英文版)》1993,6(5):291-295
The morphology of solid/liquid interface of a directionally solidification process is describedby means of fractal analysis,and the relations among the fractal dimension of the solid/liq-uid interface,solidification rate,dendrite arm space and the phosphorus content of the test al-loys have been given.It was found that the increase of the solidification rate and the phos-phorus content of the test alloy will lead to a increase,following the regularity of exponentialfunction,in the fractal dimension of solid/liquid interface.Furthermore,by combining thefractal theory and the thermodynamic principle with the measured results,it has been provedthat the fractal dimension is not only a kind of simple geometrical parameter used in des-cribing irregular geometry,but also a state function depending the change of solidificationparameters and chemical compositions. 相似文献
53.
S. Y. Chang Y. T. Hung T. H. Chuang 《Journal of Materials Engineering and Performance》2003,12(2):123-127
Alumina ceramics were brazed to Inconel 600 and UMCo-50 superalloys at 900 °C for 10 min using an Sn10Ag4Ti active filler
metal. The brazing filler showed good wettability on alumina and superalloys. The flexural strengths were 69 and 57 MPa for
alumina/Inconel 600 and alumina/UMCo-50 joints, respectively. In both cases, the brazed specimens fractured along the Sn10Ag4Ti/superalloy
interfaces after four-point bending tests. Electron probe microanalysis (EPMA) elemental mapping revealed that the Ni of Inconel
600 and the Co of UMCo-50 dissolved into Sn10Ag4Ti filler metal, which serves to reinforce the weak Sn10Ag4Ti matrix. 相似文献
54.
Ajay K. Misra 《Oxidation of Metals》1986,25(3-4):129-161
The hot corrosion of a nickel-base superalloy, Udimet 700, has been studied in the temperature range 900–950°C. The effect of the amount of Na
2SO4 on the corrosion kinetics was determined. Large weight gains and severe corrosion were associated with two different modes of degradation: (1) formation of large, interconnected sulfides beneath the external scale, and (2) formation of a Na2MoO4-MoO3 melt. The corrosion due to formation of the Na2MoO4-MoO3 melt occurred for all the salt-coating thicknesses, whereas, large sulfides were formed only for the heavier coatings of Na2SO4. The formation of Na2MoO4-MoO3 melt required an induction period, and the length of the induction period was observed to be a function of the amount of Na2SO4 and of temperature.Work funded under NASA Grant NCC 3-43. 相似文献
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KarinGraf AnaSofiaC.M.d'Oliveira 《材料热处理学报》2004,25(5):152-156
Degradation phenomena like wear and corrosion, may have their effects accelerated as components operate at high temperature. The aim of this work is to make an indirect evaluation of the influence of high temperature exposure on wear behavior of Ni coatings. A Ni-Cr-Mo-W alloy, was deposited with Plasma Transferred Arc (PTA) process. An indirect approach based on the Ahrrenius relationship was used to evaluated long time exposures at high temperatures. To simulate longer exposures at lower temperatures, coatings were exposed to higher temperatures for the same time interval. So coatings were soaked in an air furnace at 650℃, 1000℃ and 1200℃. Metal/metal wear behavior was evaluated by pin-on-disc tests. Pins were removed from the coatings by eletrodischarge machining and rubbed against a VC31 quenched and tempered tool steel. Two sets of wear tests were run at 2m/s, for different loads (0.5, 1.0, 2.0 and 3.0Kg) and for different sliding distances (120, 720, 1080, 1440 and 1800m).Coatings characterization was done by scanning electronic microscopy and Vickers microhardness. Results showed as temperature is increased, coatings wear performance is altered,and this is associated with microstructural changes. 相似文献
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58.
IC-6高温合金及其防护性涂层的摩擦特性 总被引:4,自引:0,他引:4
采用电弧离子镀技术在IC-高温合金上沉积NiCrAlY涂层。研究了NiCrAlY涂层及IC-6高温合金在室温和600℃空气中无润滑状态下,以K17高温合金为摩擦副的摩擦特性。采用带有能谱的扫描电镜(SEM/EDX)分析IC-6高温合金和NiCrAlY涂层磨损表面的形貌和成分。实验结果表明,室温条件下摩擦时,一些碎屑从K17合金上脱落下来,在IC-6合金及NiCrAlY涂层表面上形成磨粒,随着摩擦时间延长,磨损表面元素发生氧化。试样在环境温度在600℃摩擦时,NiCrAlY涂层的表面比较快的形成氧化膜,减少金属-金属间的直接接触。环境温度升高后,摩擦表面温度也随之升高,氧化物的粘滞性增强,600℃时,合金和涂层摩擦系数都有不同程度的减小。 相似文献
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60.
为应用d-电子合金设计理论(或新相分计算法(New PHACOMP))设计发展新型抗热腐蚀单晶高温合金,首先对高Cr抗热腐蚀IN738LC系列合金Ni—16Cr—9.5Al—4.0Ti-8.0Co—0.55Nb—0.06Zr—0.05B—0.47C-Ta—W—Mo(at-%)的相稳定性进行了综合评价得出抑制σ相析出的稳定性临界条件为Mdt<0.991或Mdγ<0.93同时证明这两个临界电子参数具有等价性,可以用Mdt代替Mdγ简化合金设计过程.这一结果可适用于其它高Cr系列抗热腐蚀镍基合金的d-电子合金设计 相似文献