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21.
Adem Sreedhar I. Neelakanta Reddy Qui Thanh Hoai Ta Gitae Namgung Eunbin Cho Jin-Seo Noh 《Ceramics International》2019,45(6):6985-6993
In this paper, novel morphology correlation between silver nanowires (AgNWs) and cobalt (Co)-doped ZnO (Co-ZnO) flake-like thin films (nanowire/flake-like) has been proposed for enhanced photoelectrochemical (PEC) water splitting activity. Here in, high-quality AgNWs/Co-ZnO heterostructures enabled superior visible light water splitting activity compared to the pure ZnO and AgNWs/ZnO. To address the strategic effect of AgNWs coupling and transition metal (Co-2?at%) doping into the ZnO host lattice, we have carried out the X-ray diffraction, field emission scanning microscopy, X-ray photoelectron spectroscopy, UV–Vis transmittance, water contact angle and PEC analyses. In this way, PEC water splitting activity was mainly examined by linear sweep voltammetry (I-V), amperometric I-t and photoconversion efficiency (η) studies. The experimental results provide clear evidence of morphology correlation between AgNWs and Co-ZnO flake-like structures for strong visible light absorption. Specifically, AgNWs/Co-ZnO composites exhibited significant enhancement in the photocurrent density (7.0?×?10?4 A/cm2) than AgNWs/ZnO (3.2?×?10?4 A/cm2) and pure ZnO (1.5?×?10?6 A/cm2). As a result, detailed AgNWs/Co-ZnO geometry has great potential for photoconversion efficiency (0.73%). In a word, the merits of controllable AgNWs/Co-ZnO heterostructure are proposed to improve the visible light harvesting and charge carrier generation for energy conversion devices. 相似文献
22.
Koji Morita Byung-Nam Kim Hidehiro Yoshida Keijiro Hiraga Yoshio Sakka 《Journal of the European Ceramic Society》2018,38(6):2588-2595
Carbon contamination from the carbon paper/dies during spark-plasma-sintering (SPS) processing was examined in the MgAl2O4 spinel. The carbon contamination sensitively changes with the heating rate during the SPS processing. At the high heating rate of 100 °C/min, the carbon contamination having organized structures occurred over almost the entire area from the surface to deep inside the SPSed spinel disk. In contrast, at the slow heating rate of 10 °C/min, the carbon contamination having disordered structures occurred only around the surface area. The carbon phases transform into high pressure CO/CO2 gases by post-annealing in air and lead to pore formation along the grain junctions. The pore formation significantly occurs at the high heating rate due to the large amount of the contaminant carbon phases. This suggests that if once the carbon contamination was formed in the materials, it is very difficult to remove the carbon phases from the materials. 相似文献
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3D laser ultramicroscopy (3D LUM) is intended specially for determining the concentration and size distribution of submicron inclusions in the bulk samples of high-purity materials for visible and IR fiber optics. In this work the 3D LUM technique is shown to be able to identify the nature of individual inclusions detected. The measurement of the light scattered by an inclusion at a varied probe beam wavelength and polarization and at a varied scattered light collection angle makes it possible to determine the inclusion refractive index. The 3D LUM possibilities are illustrated by the example of studying the inclusion nature in the As2S3 glass samples prepared by the direct synthesis from elements in a quartz container at elevated temperatures. 相似文献
25.
无源光网络(Passive Optical Network,PON)作为当今接入网的主要技术解决方案,具有带宽使用效率高、传输距离远、抗干扰能力强等特点.通过研究PON技术的发展动态,本文首先归纳了各种PON技术的产生背景和应用特点,整理出各技术间的连接关系及主要标准;其次介绍了PON技术的帧结构,并对带宽、波长、传输模式等PON技术的主要参数进行了汇总;然后将国内外研究热点进行划分,围绕媒体访问控制协议、帧结构、动态带宽分配算法、节能机制等关键技术,阐述了其研究现状及在PON中的重要作用;最后对PON技术的发展趋势进行了展望. 相似文献
26.
《International Journal of Hydrogen Energy》2020,45(32):16169-16182
Copper indium disulfide (CuInS2) thin films as an absorption layer for solar cell and photocatalytic degradation of organic pollutants, were successfully electrodeposited on the FTO coated glass substrate using the simple and inexpensive electrodeposition method and a sulfurization process. The effects of the Cu/In molar ratio, annealing temperature and kind of Cu2+ precursor (Cu(salen) and Cu(acac)2 as novel Cu2+ precursors) on the structural and morphological properties of samples were examined. The XRD diffraction patterns and energy dispersive spectroscopy measurements exhibit that high-quality film with superior crystalline structure was formed in the presence of Cu(salen) as Cu2+ precursor. Also, we found that a suitable heat treatment temperature could suppress the CuS phases and form well-crystallized CIS. As we know, this is the first reported efficiency for any CuInS2 superstrate solar cell to date that fabricated using Cu(salen) as Cu2+ precursor. In addition, the photocatalytic degradation of organic dye in the presence of as-synthesized CuInS2 thin films was studied. The as-prepared semiconductor photocatalysts have a good reusability; it can be successfully reused for 5 times recycling photoactivity tests. 相似文献
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28.
CAI Xiang bao 《中国邮电高校学报(英文版)》2003,10(2)
1 IntroductionMaterialswithPhotonicBandGaps (PBG’s)havebeenwidelystudiedboththeoreticallyandex perimentallyinthepastfew years[1~ 4] .Theexis tenceofgaps,which prohibitthepropagationofelectromagnetic (EM )wavesinacertainrangeoffrequencies,canhavesignificantimpactsbothinsci enceandtechnology .Manypracticalapplicationsofthesestructureshavebeensuggestedanddemon strated ,suchasPhotonicCrystal (PC)microcavi ties[5] ,infraredPC[6] ,PClens[7] ,suppressingspontaneousemission ,manipulatinglight… 相似文献
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This letter presents a new polarizer which has a simple comb structure inside a circular waveguide. The electrical performance of the proposed comb polarizer is optimized by a circular waveguide radius and by the physical parameters of the comb plates. This polarizer is suitable for providing good performance in millimeter‐band application because of its simple structure and low fabrication cost. In our experiments the dual‐band comb polarizer designed in band 1(K) and band 2(Ka) showed good electrical performance without any tuning elements. 相似文献