废催化剂中钯的回收

用硫酸溶解载体－盐酸＋氧化剂浸出－离子交换提取３１－１Ａ催化剂（含Ｐｂ０．０３１％）中的钯，可获得纯度９９．９７％Ｐｄ产品，实收率〉９７％。     

CHARAC TERIZATION OF TiAl POWDER PRODUCED BY MECHANICAL ALLOYING

The microstructure,alloying reaction and sintering behavior of the powder produced by Mechanical Al-loying(MA)for 8 h from 64 wt.-% Ti powder and 36 wt.-% Al powder were studied by scanning electronmicroscopy,optical microscopy,X-ray diffractometry,differential scanning calorimetry(DSC)and dilatometry.The mechanically alloyed powder partictes are Ti-Al composite particles.Thus,titanium aluminides can formeasily in the powder through diffusion during heat treatment.It is shown that the sintering behavior of this pow-der,different from the behaviors of TiAl alloy powder and mixed powder of 64 wt.-% Ti powder and 36 wt.-%Al powder,changes from expansion at temperatures below 1000℃ to shrinkage at temperatures above 1000℃.Homogeneously alloyed TiAl material with a density over 96% of the theoretical density can be produced fromthe mechanically alloyed powder by compaction-sintering.     

Mold-filling characteristics of AZ91 magnesium alloy in the low-pressure expendable pattern casting process

The magnesium (Mg) alloy low-pressure expendable pattern casting (EPC) process is a newly developed casting technique combining the advantages of both EPC and low-pressure casting. In this article, metal filling and the effect of the flow quantity of inert gas on the filling rate in the low-pressure EPC process are investigated. The results showed that the molten Mg alloy filled the mold cavity with a convex front laminar flow and the metal-filling rate increased significantly with increasing flow quantity when flow quantity was below a critical value. However, once the flow quantity exceeded a critical value, the filling rate increased slightly. The influence of the flow quantity of inert gas on melt-filling rate reveals that the mold fill is controlled by flow quantity for a lower filling rate, and, subsequently, controlled by the evaporation of polystyrene and the evaporation products for higher metal velocity. Meanwhile, the experimental results showed that the melt-filling rate significantly affected the flow profile, and the filling procedure for the Mg alloy in the low-pressure EPC process. A slower melt-filling rate could lead to misrun defects, whereas a higher filling rate results in folds, blisters, and porosity. The optimized filling rate with Mg alloy casting is 140 to 170 mm/s in low-pressure EPC.     

大型薄壁铝铸件表面沟槽缺陷的产生及消除

针对大型薄壁铝铸件内腔表面出现的沟槽缺陷,从差压铸造、树脂砂、铸件结构等工艺条件方面探讨了产生的机理,并通过试验和对比研究,确定排气不畅是该缺陷的首要引发因素,找到了消除该缺陷的工艺方法,提出了相关预防措施,避免了因此产生的废品损失.     

Influence of initial textures on dynamic recrystallization and textures in AZ31 magnesium alloys

1　INTRODUCTIONMagnesiumisthelightestmetallicstructurema terialwithhighspecificstrengthandthereforeiswidelyusedinautomotive ,electronicsandaerospaceindustries[1,2 ] .However ,magnesiumoftenshowsinsufficientplasticityatroomtemperatureduetoitsHCPstructurewithlessindependentsystemsofbasalslip .Toenhanceformabilityofmagnesium ,ahigherdeformingtemperatureisusuallyusedwithtwopur poses .Thefirstistoactivatenewslipsystemsbesidesbasalslip ,sothatmorethanfiveindependentslipsystemscanbeprovided ,be…     

Enabling factors toward production of nanostructured steel on an industrial scale

Utilizing the existing properties of steel, a modern technological society has been constructed. While there are over 25,000 worldwide equivalent steels based on manipulating the eutectoid transformation, there exist only a handful of commercial nanostructured steel alloys based on manipulating the more complex glass devitrification transformation. Thus, research on nanostructured steels is in its infancy, and many further developments are expected with the demonstrated promise of developing new combinations of superior properties. In this article, seven enabling metallurgical factors are presented that ultimately allow a variety of nanostructured steel products to be produced in an ever-increasing array of industrial processing techniques. Additionally, a case example of the formation of nanostructured steel are given showing how these factors can be harnessed on an industrial scale.     

High-speed milling of titanium alloys using binderless CBN tools

The performance of conventional tools is poor when used to machine titanium alloys. In this paper, a new tool material, which is binderless cubic boron nitride (BCBN), is used for high-speed milling of a widely used titanium alloy Ti–6Al–4V. The performance and the wear mechanism of the BCBN tool have been investigated when slot milling the titanium alloy in terms of cutting forces, tool life and wear mechanism. This type of tool manifests longer tool life at high cutting speeds. Observations based on the SEM and EDX suggest that adhesion of workpiece and attrition are the main wear mechanisms of the BCBN tool when used in high-speed milling of Ti–6Al–4V.     

金属及合金中钛的光度分析近况

综述了金属及合金中钛的光度测定方法新近进展情况。     

Stability of AB5-type hydrogen storage alloys

In this paper, we deduced an empirical equation for predicting the stabilities of the hydrides of AB₅-type compounds with the consideration of the effects of geometrical factor and electric factor. The theoretical curves derived from this equation are in good agreement with the test results of La_1−xCa_xNi₅, Ml_1−xCa_xNi₅ and La_1−xCe_xNi₅ compounds. With this model, we can easily interpret the phenomenon that the initial partial substitution of R by Ca in R_1−xCa_xNi₅ (R is rare earth metal) compounds cause an increase of hydrogen desorption pressure to a maximum value, whereas in the range of larger Ca content x the hydrogen desorption pressure decreases with increasing x.