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991.
尿素装置液相浓度在线自动检测软件的研究 总被引:1,自引:1,他引:1
为了改善尿素装置先进的控制和落后的人工检测物料浓度之间的矛盾,运用化工热力学原理,以及热力学模型组合求解法,研制了液相浓度实时检测软件。并开发了多种软件以适应各类尿素流程(水溶液全循环法、CO2汽提法、氨汽提法)的需要 相似文献
992.
Abstract. The simultaneous switching autoregressive (SSAR) model proposed by Kunitomo and Sato (A non-linearity in economic time series and disequilibrium econometric models. In Theory and Application of Mathematical Statistics (ed. A. Takemura). Tokyo:University of Tokyo Press (in Japanese), 1994; Asymmetry in economic time series and simultaneous switching autoregressive model. Struct. Change Econ. Dyn. , forthcoming (1994).) is a Markovian non-linear time series model. We investigate the finite sample as well as the asymptotic properties of the least squares estimator and the maximum likelihood (ML) estimator. Due to a specific simultaneity involved in the SSAR model, the least squares estimator is badly biased. However, the ML estimator under the assumption of Gaussian disturbances gives reasonable estimates. 相似文献
993.
Krzysztof Kaczmarski Dongmei Zhou Georges Guiochon 《Chemical engineering science》2003,58(11):2325-2338
The adsorption isotherm data of R- and S-1-indanol and of their racemic mixture on cellulose tribenzoate were measured by frontal analysis. These experimental data were fitted to the single-component and the modified competitive Bilangmuir isotherms. The overloaded elution profiles of bands of the pure enantiomers and of the racemic mixture were calculated for different sample sizes, using the best competitive isotherm model and the General Rate Model of chromatography coupled with the generalized Maxwell-Stefan equation that describes the surface diffusion flux. The calculated and the experimental profiles were found to be in excellent agreement in all cases. The parameters of the model of the mass transfer kinetics were derived from the band profiles obtained for the pure enantiomers. The same values of these parameters give an excellent prediction of the profiles of multicomponent bands. The new model described here allows a satisfactory interpretation of the competitive mass transfer kinetics. 相似文献
994.
A predictive model was developed for the fully developed zone of a circulating fluidized bed (CFB) riser reactor operating in the fast fluidization regime that overcomes limitations of existing models. The model accounts for the upward flow of gas and solids in the core and downward flow of the two phases in the annulus. Additionally, a numerical solution methodology for the simulation of a riser reactor employing the hydrodynamic model was devised. A simulation was performed using the fast, main Claus reaction to demonstrate the effects of backmixing in the fast fluidization regime. It was found that the molar flow rates of the reactants leaving a fast fluidized CFB riser reactor were significantly higher than those leaving an identical reactor operating in the pneumatic transport regime. 相似文献
995.
就贵州省化工企业加强质量文化建设必要性和紧迫性作用思考,通过对质量文化内涵的分析,提出我省化工企业应走“质量效益型”的道路,并指出实践中应注意的问题。 相似文献
996.
997.
The ironmaking blast furnace is regarded as one of the biggest and most complex industrial reactors, because it includes various materials like gas, lump granular materials, liquids and powders and more than 30 major reactions and phase changes in a single reaction vessel. The mathematical simulator of this process developed in this study used the multi-fluid treatment as its framework, since the motions of these materials were governed by different flow mechanisms. The rates of the interactions among the phases and the chemical reactions were evaluated based on kinetic theories. The model successfully reproduced the fields of velocity, temperature and reaction in the furnace and its validity was confirmed. The simulator was also applied to a novel operation, namely the top gas recycling combined with the carbon-composite iron-ore charging and the waste plastics injection, and the advantages in furnace efficiency and environmental load were quantitatively indicated. 相似文献
998.
本工作是在非离子凝胶的分子热力学模型基础,引入Donnan平衡项和大分子离子链的静电排斥项对凝胶自由能的贡献,建立了一个新的离子凝胶的分子热力学模型。该模型在解释离子凝胶的PH敏感性及其各种影响因素,以及预测PH溶胀曲线方面都取得了较好的效果。 相似文献
999.
Mitra Dadvar 《Chemical engineering science》2007,62(5):1466-1476
The question of whether effective diffusivities in porous materials under reactive and nonreactive conditions are equal is addressed. Previous studies had considered the problem with first-order reactions. We study the issue with two nonlinear reactions—a second-order reaction and one governed by the Michaelis-Menten kinetics. Pore network and continuum models of porous media are utilized to estimate the effective diffusivities under reactive and nonreactive conditions. We show that the two effective diffusivities are significantly different. The difference is due to the heterogeneities of the porous material, and the fluctuations that they cause in the spatially varying local concentrations and diffusivities, and can be as large as a few orders of magnitude. Theoretical analysis of diffusion and reactions in porous media is also presented that supports the results of the simulations. In particular, it is shown that the results of pore network simulations cannot be fitted to the classical continuum equation of diffusion and reaction, and that a more complex continuum equation should be used for this purpose. 相似文献
1000.
用熔剂法制备了(Nb_y.Ti_(1-y))C_r单晶体,用Debye照相法及四圆衍射仪对其晶体结构进行了研究。实验结果表明,(Nb_yTi ̄(1-y)C_x中存在类似于作化学计量化合物TiC_x及NbC_x的有序一无序转变现象,转变温度随其化学成份改变在1175~1280K范围内变化。高温型(Nb_yTi ̄(1-y))C_x的晶体结构属NaCl型结构,碳空位呈随机分布;低温型(Nb_yTi ̄(1-y))C_x的晶体中碳空位呈短程有序分布,可用V_6C_5晶体结构模型进行描述。 相似文献