Structures and phase transformations of odd-numbered asymmetric main-chain liquid crystalline polyesters

Two new asymmetric odd-numbered main-chain liquid crystalline (LC) polyesters (BPE-Cn) were synthesized through the condensation polymerization of A-B type asymmetric α,ω-carboxylic acid-hydroxyl terminated monomers with odd-numbers of methylene units in the spacers (BPCA-Cn-PmOH, where n=7 and 9). The phase behaviors and structures of these odd-numbered BPE-Cn samples were characterized using the combined techniques of differential scanning calorimetry (DSC), wide angle X-ray diffraction (WAXD), selected area electron diffraction (SAED) and polarized light microscopy (PLM). One-dimensional (1D) powder WAXD results at different temperatures combined with DSC results revealed that during cooling these two polyesters enter a low-ordered LC phase before developing a crystalline phase at lower temperatures. Based on 2D WAXD of oriented fiber patterns, the low ordered LC phase of odd-numbered BPE-Cn was identified to be a smectic A (SmA) phase, which was constructed by each chemical repeating unit along the fiber drawn direction. The crystalline structures were determined to be monoclinic unit cells (K_M). However, BPE-C7 possessed a γ=87°, while BPE-C9 had a β=100°. These crystalline structure identifications were also confirmed by SAED from single crystals. Two-chain packing models of the K_M phases with four chemical repeating units were proposed on the basis of the experimental diffraction patterns. The different structures were attributed to the interplay between the mesogenic group ordering propensity and the chain constraints dictated by the methylene spacer and the meta-linkage at the end of mesogen. In the ordered phases of these two odd-numbered BPE-Cn polyesters, aromatic mesogenic groups are more or less parallel to each other along the chain with small angles of deviation from the c-axis of the crystal lattice, different from those large zigzag conformation structures in even-numbered BPE-Cn crystals. Crystallographic calculations of these two unit cell structures indicated that the neighboring chains in the crystals are translated along the c-axis (in the case of BPE-C9) or twisted away from the b-axis (in the case of BPE-C7) in order to incorporate both of the bend attributed to the odd-numbered methylene spacers and of the configurational meta-linkage at the end of mesogens. The simulated diffractions based on these calculations qualitatively agreed with the experimental observations. The phase identifications were also supported by the observed texture changes in PLM.     

Semiconductor-to-metallic phase transition of VO<Subscript>2</Subscript> by laser excitation

VO₂ thin films deposited on MgO and fused silica glass substrates were prepared by the pulsed laser deposition (PLD) technique, which shows phase transition (PT) from the monoclinic semiconductor phase to a metallic tetragonal rutile structure at temperatures over 68°C. The observed PT is reversible, showing a typical hysteresis. The PT can also be induced through optical pumping by laser excitation. In this case, it was found that the optically induced PT is ultrafast and passive, but not thermally initiated. In order to understand the PT mechanism, a study of transient holography using degenerate-four-wavemixing (DFWM) measurement was conducted. A Nd:YAG pulsed laser with pulse duration of 30 psec operating at 532 nm was employed as the coherent light source. This showed that the observed transient holography in VO₂ thin film is associated with the excited state dynamical process, which essentially causes the structural change, or so-called optically induced PT. The observed extremely large polarizability is believed to relate to the large offset in the potential well minimum between the ground state and excited state. Through an unidentified intermediate state, the transient lattice distortion triggered the structural change.     

Prototype calculations of B2 miscibility gaps in ternary b.c.c. systems with strong ordering tendencies

Prototype calculations in ternary ordering systems based on the b.c.c. lattice have been carried out with the Cluster Variation Method (CVM) in the irregular tetrahedron approximation including tetrahedron interactions. The systems under investigations were characterized by strong ordering tendencies (i.e. with large, negative first neighbour interactions in all binary sub-systems) which resulted in the opening of a miscibility gap inside the B2 single-phase field. This miscibility gap is shown to be produced by frustration of the B2 cluster by a calculation using a hypothetical system with identical first neighbour interactions in the three binary sub-systems. This phase diagram presents as a key feature a central three-phase miscibility gap, which transforms into an ordinary two-phase miscibility gap involving two B2 phases after the symmetry of the interactions is broken. The results are discussed in connection with the experimental Fe–Ti–Rh phase diagram.     

On the unstable propagation of a phase transition in a solid

To explore a possible mechanism of deep earthquakes, this paper analyzes the unstable propagation of a stress-induced phase transition which is initiated in a homogeneous stress field. This Stephen problem is formulated as an initial-value problem for the phase boundary, and the driving force of the boundary is computed by using the solution of the boundary-value problem for a partially transformed material. The propagation of the phase transition under uniform pressure is numerically simulated. It is shown that (1) under lower pressure, the transition is terminated at a certain size, but it can propagate unstably when an initially transformed region is sufficiently large; and (2) when the pressure attains a critical value, the propagation becomes unstable, and goes in a particular direction depending on the initial shape. These results confirm the possibility of the unstable propagation of phase transition, and provide a theoretical basis for the hypothesis that the phase transition of a mantle material can trigger a deep earthquake.     

宝钢三期工程新技术概述

宝钢三期工程项目初步设计工作已全面完成并通过审查，现已进入施工图设计与现场施工准备工作阶段。本文介绍了三期工程的建设规模与产品方案，简介了三期工程的建设水平与特点，三期工程主体项目中新技术应用状况与其建设进度，提供了宝钢三期工程项目的概貌。     

Two- and three-dimensional equilibrium morphology of a misfitting particle and the Gibbs–Thomson effect

The equilibrium shapes of misfitting precipitates in elastically anisotropic systems are obtained in both two and three dimensions, and the corresponding Gibbs–Thomson equation is derived as a function of the characteristic ratio between elastic and interfacial energies, L′. The effect of elastic inhomogeneity is investigated systematically. For soft or moderately hard particles, the stable equilibrium shape bifurcates from a fourfold symmetric shape to a twofold symmetric one in 2D and from a cubic symmetric shape to a plate-like one in 3D. For a very hard particle, the shape bifurcation is not observed in 2D for the range of L′ investigated, but both plate-like and rod-like shapes are found in 3D. The computed Gibbs–Thomson equation is well approximated by a piecewise linear function of L′. Predictions are made for coarsening of many-particle systems based on an established mean-field theory. The results predict that the elastic stress has no effect on coarsening kinetics where most particles are highly symmetric (fourfold in 2D and cubic in 3D), and the exponent remains 1/3 but the rate constant increases if stress is sufficient to induce symmetry-breaking bifurcation on most particles.     

Prediction of Austenitization and Homogenization of Q235 Plain Carbon Steel during Reheating Process

In this paper,the austenitization and homogenization process of Q235 plain carbon steel during reheating is predicted using a two-dimensional model which has been developed for the prediction of diffusive phase transformation(e,g.αto γ).The diffusion equations are solved within each phase(αand γ) and an explicit finite volume technique formulated for a regular hexagonal grid are used.The discrete interface is represented by special volume elements α/γ,an volume element α undergoes a transition to an interface state before it becomes γ.The procedure allows us to handle the displacement of theinterface while respecting the flux condition at the interface.The simulated microstructure shows the dissolution of ferrite particles in the austenite matrix is presented at different stages of the phase transflrmation.Specifically,the influence of the microstructure scale and the hwating rate on the phase transformation kinetics has been investigated.The experimental results agree well with the simulated ones.     

A NEW ONE—DIMENSIONAL CHAOTIC MAP WITH INFINITE COLLAPSES

This letter presents a new one-dimensional chaotic map with infinite collapses. Theoretical analyses show that the map has complicated dynamical behavior and ideal distribution. The map can be applied in chaotic spreading spectrum communication and chaotic cipher.     

一种通用可编程数字频率合成器的设计

讨论了锁相式频率合成器的基本原理，设计了一种通用可编程锁相式频率合成器，介绍了其编程置型格式，提出了一种可提高程控分频器工作频率的电路设计方法，并给出了其模拟波形。该电路的最高合成频率为１００ＭＨｚ最小频率间隔为１００Ｈｚ，在工程上具有广泛的应用前景。     

高斯光束强度共轭的数值模拟

本文从傍轴波动方程出发,在线性化假设下,导出了任意振幅分布的发射场相位与接收场振幅分布之间的解析关系式,并对高斯光束进行了数值模拟。模拟结果表明,衍射场强度与要求场强度之间符合较好。最后对数值模拟结果进行了讨论。